四亚甲基双(三苯基溴化磷) | 15546-42-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 四亚甲基双(三苯基溴化磷)
• 中文别名: 四亚甲基双(三苯基溴化磷
• 英文名称: Tetramethylenebis(triphenylphosphonium bromide)
• 英文别名: triphenyl(4-triphenylphosphaniumylbutyl)phosphanium;dibromide
• CAS: 15546-42-6
• 化学式: C40H38Br2P2
• 分子量: 740.5
• InChiKey: WTFXVDWCEPLDDY-UHFFFAOYSA-L

物化性质

• 熔点：
  292-293°C
• 稳定性/保质期：
  在常温常压下保持稳定，应避免与氧化物接触。

计算性质

• 辛醇/水分配系数(LogP)：
  1.76
• 重原子数：
  44
• 可旋转键数：
  11
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 危险品标志：
  Xi
• 危险类别码：
  R36/37/38
• 安全说明：
  S26,S36

反应信息

• 作为反应物：
  描述：

  钾 、 2-氰基-3-氧代丙酸乙酯 、 四亚甲基双(三苯基溴化磷) 生成 3-Oxo-2-cyanopropanoic acid ethyl ester tetramethylenebis(triphenylphosphonium) salt
  参考文献：
  名称：

  PHOTOTHERMOGRAPHIC MATERIALS CONTAINING CO-DEVELOPERS WITH PHOSPHONIUM CATION

  摘要：

  在光热相纸材料中加入三酚还原剂（显影剂）和含有膦鎵阳离子的取代烯烃协同显影剂的组合，可以改善所得图像的色调。

  公开号：

  US20080145788A1

文献信息

• Flavor and fragrance compositions
  申请人：Emura Makoto

  公开号：US20060160719A1

  公开（公告）日：2006-07-20

  The present invention provides a flavor and fragrance composition which comprises, as the active ingredient, an optically active (1S)-8-mercaptomenthone having an S-form/R-form mixing ratio for the configuration at the 4-position in the range of from 65:35 to 95:5 by weight, wherein the flavor and fragrance composition is for use in food and beverage, fragrances and cosmetics, pharmaceuticals or oral compositions and the like; a product which is scented with the flavor and fragrance composition; and a method for enhancing or modulating odor of the flavor and fragrance composition by adding the optically active (1S)-8-mercaptomenthone.

  本发明提供了一种风味和香料组合物，其包括作为活性成分的光学活性(1S)-8-巯基薄荷酮，在重量上4位构型的S形/R形混合比为65:35至95:5的范围内，其中，该风味和香料组合物适用于食品和饮料、香料和化妆品、药品或口腔组合物等；一种用该风味和香料组合物调香的产品；以及通过添加光学活性(1S)-8-巯基薄荷酮来增强或调节该风味和香料组合物气味的方法。
• Method for producing squalene
  申请人：——

  公开号：US20040015033A1

  公开（公告）日：2004-01-22

  A process for making squalene involving: (a) providing a hydrocarbon-containing intermediate product derived from a vegetable oil; (b) providing an extractant; and (c) extracting squalene-containing starting material from the hydrocarbon-containing intermediate product to form a squalene-containing raffinate phase and an extract phase.

  制备角鲨烯的过程包括：(a)提供从植物油中得到的含碳氢化合物中间产物；(b)提供一种萃取剂；(c)从含碳氢化合物中间产物中提取含有角鲨烯的起始材料，形成含有角鲨烯的粗品相和萃取相。
• Carboxylic acids and derivatives thereof and pharmaceutical compositions containing them
  申请人：——

  公开号：US20020049345A1

  公开（公告）日：2002-04-25

  The invention relates to carboxylic acids and derivatives thereof and pharmaceutical compound containing them. The active compounds are represented by the formula compound represented by formula I, wherin R 1 -R 4 each independently represents an unsubstituted or substituted hydrocarbyl or heterocyclyl radical, Q represents a diradical consisting of a linear chain of 11 to 18 carbon atoms, one or more of which may be replaced by heteroatoms, said chain being optionally substituted by inert substituents and one or more of said carbon or heteroatom chain members optionally forming part of a ring structure, and where one or both of de carboxyl groups can be substituted by an in vitro hydrolyzable physiologically acceptable substituent; with the proviso that: compounds wherein R 1 -R 4 each represents CH 3 and Q represents a linear chain of 14 carbons, are excluded; and compounds wherein Q represents a linear chain of carbon atoms one of which is replaced by oxygen or sulfur, are excluded. 1

  本发明涉及羧酸及其衍生物和含有它们的药物化合物。活性化合物由式I表示，其中R1-R4各自独立地表示未取代或取代的烃基或杂环基，Q表示由11到18个碳原子的线性链组成的双原子基团，其中可以有一个或多个被杂原子取代，该链可以被惰性取代基取代，并且该碳或杂原子链的一个或多个成员可以选择地构成环结构，其中一个或两个羧基可以被体外水解的生理可接受的取代基取代；但是具有以下特征：其中R1-R4表示CH3且Q表示14个碳原子的线性链的化合物被排除；以及Q表示碳原子链的一个原子被氧或硫替换的化合物被排除。
• PHOTOTHERMOGRAPHIC MATERIALS CONTAINING CO-DEVELOPERS WITH PHOSPHONIUM CATION
  申请人：Simpson Sharon M.

  公开号：US20080145788A1

  公开（公告）日：2008-06-19

  Incorporating a combination of a trisphenol reducing agent (developer) and a substituted olefinic co-developer having a phosphonium cation in photothermographic materials improves image tone in resulting images.

  在光热相纸材料中加入三酚还原剂（显影剂）和含有膦鎵阳离子的取代烯烃协同显影剂的组合，可以改善所得图像的色调。
• PHOTOCHROMIC AND ELECTROCHROMIC COMPOUNDS AND SYNTHESIS AND USE THEREOF
  申请人：Branda Neil R.

  公开号：US20100190868A1

  公开（公告）日：2010-07-29

  Novel photochromic and electrochromic hexadiene compounds are described. The compounds are reversibly convertible between ring-open and ring-closed isomeric forms as indicated in structures I(o) and I(c) below. (See formula in original abstract of application) The conversion between the different isomeric forms may be induced by light or electricity. In one embodiment the compounds may include a charge transfer moiety including electron donor and acceptor groups. The electron donor and acceptor are linearly conjugated in the ring-open form to enable electron transfer but are electrically insulated in the ring-closed form. Methods for synthesizing the compounds from photochemically and/or electrically inert precursors are also described. For example, the photoresponsive compounds may be synthesized by reacting diene precursors with dienophiles in a condensation reaction. The compounds may be utilized in reactivity-gated photochromic or electrochromic applications. In one embodiment of the invention, compounds of the invention may be used in a method to selectively release a releasable agent, such as a small molecule. According to this method, a photochemically inert precursor compound is reacted with the releasable agent to form a carrier compound comprising a switching moiety, the switching moiety being reversibly convertible between a thermally unstable form and a thermally stable form. The switching moiety may be selectively converted between the first and second forms to cause controlled release of the releasable agent from the carrier compound.

  本文描述了新型的光致变色和电致变色六烯基化合物。这些化合物可以在开环和闭环异构形式之间可逆转化，如下所示的结构I（o）和I（c）。 （请参见申请书原摘要中的公式）不同异构形式之间的转化可以通过光或电引发。在一种实施例中，这些化合物可以包括一个电荷转移基团，包括电子给体和受体基团。在开环形式中，电子给体和受体是线性共轭的，以实现电子转移，但在闭环形式中是电绝缘的。本文还描述了从光化学和/或电化学惰性前体合成这些化合物的方法。例如，可以通过将二烯前体与二烯酰亲合剂在缩合反应中反应来合成光响应化合物。这些化合物可以用于反应门控的光致变色或电致变色应用中。在本发明的一种实施例中，本发明的化合物可以用于选择性释放可释放剂（例如小分子）的方法。根据这种方法，将光化学惰性前体化合物与可释放剂反应以形成载体化合物，其中载体化合物包含可转换为热不稳定形式和热稳定形式的开关基团。可以选择性地在第一和第二形式之间转换开关基团，以从载体化合物中控制释放可释放剂。