1,4-二[(4-丁苯基)氨基]-5,8-二羟基蒽醌 | 28198-05-2

• 物质功能分类: 染料及颜料 - 染料 - 溶剂染料
• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 中文名称: 1,4-二[(4-丁苯基)氨基]-5,8-二羟基蒽醌
• 中文别名: 溶剂绿28；1,4-双[(4-丁苯基)氨基]-5,8-二羟基蒽醌；溶剂绿 28
• 英文名称: 1,4-dihydroxy-5,8-di(p-butylanilino)anthraquinone
• 英文别名: 1,4-bis[(4-butylphenyl)amino]-5,8-dihydroxyanthraquinone；1,4-bis[(4-butylphenyl)amino]-5,8-dihydroxy-9,10-anthracenedione；9,10-Anthracenedione, 1,4-bis[(4-butylphenyl)amino]-5,8-dihydroxy-；1,4-bis(4-butylanilino)-5,8-dihydroxyanthracene-9,10-dione
• CAS: 28198-05-2
• 化学式: C₃₄H₃₄N₂O₄
• 分子量: 534.655
• InChiKey: KTEFLEFPDDQMCB-UHFFFAOYSA-N

物化性质

• 沸点：
  716.9±60.0 °C(Predicted)
• 密度：
  1.273
• LogP：
  12.23 at 25℃

计算性质

• 辛醇/水分配系数(LogP)：
  10.1
• 重原子数：
  40
• 可旋转键数：
  10
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  98.7
• 氢给体数：
  4
• 氢受体数：
  6

安全信息

• 海关编码：
  2922509090

制备方法与用途

油溶绿G是一种艳绿色素，广泛应用于塑料、油墨、涂料以及纤维的着色。

生产方法如下：可以以1,4-二氯基-5,8-二醌和4-正丁基苯胺为原料，将两者缩合即可得到产物。经过过滤、干燥后即得成品。另一种方法是以1,4,5,8-四羟基蒽醌和4-正丁基苯胺为原料，首先将1,4,5,8-四羟基蒽醌还原为其隐色体，再与4-正丁基苯胺缩合，随后氧化得到最终产物。同样经过过滤、干燥后即得成品。

反应信息

• 作为反应物：
  描述：

  1,4-二[(4-丁苯基)氨基]-5,8-二羟基蒽醌 在 sodium hydroxide 、 potassium acetate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 10.0h， 生成 1,4-dihydroxy-5,8-bis(N-acetyl-p-butylanilino)anthraquinone
  参考文献：
  名称：

  Popov, S. I.; Volosenko, V. P., Journal of Organic Chemistry USSR (English Translation), 1983, vol. 19, # 4, p. 745 - 750

  摘要：

  DOI：

文献信息

• Standard samples and methods of instrumental measurement of ASTM color of petroleum products using said samples
  申请人：NIPPON PETROLEUM REFINING COMPANY, Ltd.

  公开号：EP0481519A1

  公开（公告）日：1992-04-22

  A standard sample for use in an instrumental measurement of ASTM color of a petroleum product with a photoelectric colorimeter, which comprises a mixed solution 3-methyl-I-phenyl-4-(phenylazo)-pyrazol-5-ol, 1-(phenylazo)-2-naphthalenol, 1-[[4-[(dimethylphenyl)azo]dimethylphenyl]azo]-2-naphthalenol, 1,5(or 1,8)-bis[(4-methylphenyl)amino]-9,10-anthracenedione, 1-hydroxy-4-[(4-methylphenyl)amino]-9,10-anthracenedione, 1,4-bis-(butylamino)-9,10-anthracenedione and 1,4-bis[(4-butylphenyl)amino]-5,8-dihydroxy-9,10-anthracenedione each as a colorant, 1-phenyl-1-xylylethane as a solvent for said colorants and dodecane as a diluent, and a method of instrumental measurement of ASTM color with the standard sample.

  一种标准样品，用于用光电比色计对石油产品的 ASTM 颜色进行仪器测量，其中包括 3-甲基-I-苯基-4-(苯基偶氮)-吡唑-5-醇混合溶液、1-(苯基偶氮)-2-萘酚、1-[[4-[(二甲基苯基)偶氮]二甲基苯基]偶氮]-2-萘酚、1,5(或 1,8)-双[(4-甲基苯基)氨基]-9,10-蒽二酮、1-羟基-4-[(4-甲基苯基)氨基]-9,10-蒽二酮、1,4-双(丁氨基)-9,10-蒽二酮和 1,4-双[(4-丁基苯基)氨基]-5,8-二羟基-9,10-蒽二酮各自作为着色剂、1-苯基-1-羟乙基乙烷作为上述着色剂的溶剂，十二烷作为稀释剂，以及用标准样品对 ASTM 颜色进行仪器测量的方法。
• POLYMERIZABLE COMPOSITION FOR OPTICAL MATERIAL, AND OPTICAL MATERIAL AND PLASTIC LENS OBTAINED FROM SAME
  申请人：Mitsui Chemicals, Inc.

  公开号：EP3381951A1

  公开（公告）日：2018-10-03

  A polymerizable composition for an optical material of the present invention includes a compound (A) represented by General Formula (1) including two or more allyloxycarbonyl groups; an ultraviolet absorbing agent (B) represented by General Formula (i) ; at least one kind of radical polymerization initiator (C) selected from the group consisting of a peroxyketal-based radical polymerization initiator, a peroxymonocarbonate-based radical polymerization initiator, and a peroxyester-based radical polymerization initiator; at least one kind of dye (D) selected from an anthraquinone-based dye, a perinone-based dye, a monoazo-based dye, a diazo-based dye, and a phthalocyanine-based dye.

  本发明光学材料的可聚合组合物包括通式(1)代表的化合物(A)，其中包括两个或两个以上的烯丙氧羰基；通式(i)代表的紫外线吸收剂(B)；至少一种自由基聚合引发剂 (C)，选自过氧酮基自由基聚合引发剂、过氧一碳酸酯基自由基聚合引发剂和过氧酯基自由基聚合引发剂组成的组； 至少一种染料 (D)，选自蒽醌基染料、过醌基染料、单偶氮基染料、重氮基染料和酞菁基染料。
• POLYMERIZABLE COMPOSITION FOR OPTICAL MATERIAL, AND MOLDED ARTICLE
  申请人：Mitsui Chemicals, Inc.

  公开号：EP3722840A1

  公开（公告）日：2020-10-14

  The polymerizable composition for an optical material of the present invention includes an allyl carbonate compound (A) including two or more allyloxycarbonyl groups which is represented by General Formula (1); a (meth)acrylate compound (B) including two or more (meth)acryl groups which is represented by General Formula (2); at least one kind of compound (C), selected from compounds represented by General Formulas (3) to (6) and dyes described below; and a polymerization initiator (D) including at least a radical polymerization initiator (D1) and a radical polymerization initiator (D2), in which, in 100% by weight in a total of the compound (A) and the compound (B), the compound (A) is included in an amount of more than 0% by weight and 30% by weight or less and the compound (B) is included in an amount of 70% by weight or more and less than 100% by weight, the radical polymerization initiator (D1) has a radical residual ratio after 5 hours at 50°C of 20% or more and less than 100% and a radical residual ratio after 5 hours at 70°C of 0% or more and less than 30%, and the radical polymerization initiator (D2) has a radical residual ratio after 5 hours at 70°C of 30% or more and less than 98%.

  本发明光学材料的可聚合组合物包括通式(1)表示的包括两个或两个以上烯丙氧羰基的碳酸烯丙酯化合物(A)；通式(2)表示的包括两个或两个以上(甲基)丙烯酰基的(甲基)丙烯酸酯化合物(B)；至少一种化合物(C)，选自通式(3)至(6)表示的化合物和下述染料；和聚合引发剂 (D)，至少包括自由基聚合引发剂 (D1) 和自由基聚合引发剂 (D2)，其中化合物 (A) 和化合物 (B) 的总重量为 100%，化合物 (A) 的含量大于 0%（以重量计）且小于 30%（以重量计），化合物 (B) 的含量大于 70%（以重量计）且小于 100%（以重量计）、自由基聚合引发剂（D1）在 50°C 下 5 小时后的自由基残留率为 20%或以上且小于 100%，在 70°C 下 5 小时后的自由基残留率为 0%或以上且小于 30%，自由基聚合引发剂（D2）在 70°C 下 5 小时后的自由基残留率为 30%或以上且小于 98%。
• Polymerizable composition for optical material and optical material and plastic lens obtained from same composition
  申请人：Mitsui Chemicals, Inc.

  公开号：US10723862B2

  公开（公告）日：2020-07-28

  A polymerizable composition for an optical material of the present invention includes a compound (A) represented by General Formula (1) including two or more allyloxycarbonyl groups; an ultraviolet absorbing agent (B) represented by General Formula (i); at least one kind of radical polymerization initiator (C) selected from the group consisting of a peroxyketal-based radical polymerization initiator, a peroxymonocarbonate-based radical polymerization initiator, and a peroxyester-based radical polymerization initiator; at least one kind of dye (D) selected from an anthraquinone-based dye, a perinone-based dye, a monoazo-based dye, a diazo-based dye, and a phthalocyanine-based dye.

  本发明光学材料的可聚合组合物包括通式(1)代表的化合物(A)，其中包括两个或两个以上的烯丙氧羰基；通式(i)代表的紫外线吸收剂(B)；至少一种自由基聚合引发剂 (C)，选自过氧酮基自由基聚合引发剂、过氧一碳酸酯基自由基聚合引发剂和过氧酯基自由基聚合引发剂组成的组； 至少一种染料 (D)，选自蒽醌基染料、过醌基染料、单偶氮基染料、重氮基染料和酞菁基染料。
• Transparently coated polycarbonate component, its production and use
  申请人：Covestro Deutschland AG

  公开号：US11027312B2

  公开（公告）日：2021-06-08

  The present invention relates to a multilayer construction containing a support or frame composed of a nontransparent polymer as layer c) and a transparent layer b) based on a thermoplastic polymer having a solar transmittance TDS of more than 20%, determined in accordance with ISO 13837:2008 at a layer thickness of 4 mm, and a siloxane-based protective layer a) which is applied to layer c) and layer b), wherein the siloxane layer a) is selectively postcured in selected regions by means of ultrashort-wave UV radiation, and to a method for selective surface treatment.

  本发明涉及一种多层结构，包含一个支撑或框架，该支撑或框架由作为层 c) 的非透明聚合物和透明层 b) 组成，透明层 b) 基于热塑性聚合物，根据 ISO 13837：在层厚度为 4 毫米时，根据 ISO 13837：2008 测定，在层 c) 和层 b) 上涂敷硅氧烷保护层 a)，其中硅氧烷保护层 a)通过超短波紫外线辐射在选定区域进行选择性后固化，以及一种选择性表面处理方法。