methyl 11-methyl octadecanoate | 74484-77-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: methyl 11-methyl octadecanoate
• 英文别名: 10-Methyloctadecansaeuremethylester；11-methyl-octadecanoic acid methyl ester；11-Methyl-octadecansaeure-methylester；Octadecanoic acid, 11-methyl-, methyl ester；methyl 11-methyloctadecanoate
• CAS: 74484-77-8
• 化学式: C₂₀H₄₀O₂
• 分子量: 312.536
• InChiKey: OHEUQJSREGQWEP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.8
• 重原子数：
  22
• 可旋转键数：
  17
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.95
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  methyl 11-methyl octadecanoate 在 氢氧化钾 、 氯化亚砜 作用下， 生成 11-methyl-octadecanoic acid amide
  参考文献：
  名称：

  BRANCHED-CHAIN FATTY ACIDS. XIII. PREPARATION OF BRANCHED AND NORMAL ACIDS FOR USE IN THE STUDY OF MELTING POINTS OF BINARY MIXTURES. COMPLETION OF THE METHYLOCTADECANOIC ACID SERIES

  摘要：

  DOI：

  10.1021/jo01147a023
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 氢氧化钾 、 一水合肼 、 二乙二醇 作用下， 生成 methyl 11-methyl octadecanoate
  参考文献：
  名称：

  BRANCHED-CHAIN FATTY ACIDS. XIII. PREPARATION OF BRANCHED AND NORMAL ACIDS FOR USE IN THE STUDY OF MELTING POINTS OF BINARY MIXTURES. COMPLETION OF THE METHYLOCTADECANOIC ACID SERIES

  摘要：

  DOI：

  10.1021/jo01147a023

文献信息

• Enzymes for producing non-straight-chain fatty acids
  申请人：WISCONSIN ALUMNI RESEARCH FOUNDATION

  公开号：US10273511B2

  公开（公告）日：2019-04-30

  Enzymes for producing non-straight-chain fatty acids, microorganisms comprising the enzymes, and in vivo and in vitro uses of the enzymes. Provided are enzymes capable of producing various non-straight-chain fatty acids, including branched-chain fatty acids, cyclic fatty acids, and furan-containing fatty acids. The enzymes include RSP2144, RSP1091, and RSP1090 from Rhodobacter sphaeroides and homologs thereof. The enzymes can be purified to produce non-straight-chain fatty acids in vitro or expressed in microorganisms to produce non-straight-chain fatty acids in vivo. The microorganisms can be fine-tuned to produce a specific type of non-straight-chain fatty acid by expressing, overexpressing, or deleting the enzymes in various combinations.

  用于生产非直链脂肪酸的酶，包含这些酶的微生物，以及这些酶在体内和体外的用途。所提供的酶能够生产各种非直链脂肪酸，包括支链脂肪酸、环脂肪酸和含呋喃脂肪酸。这些酶包括Rhodobacter sphaeroides的RSP2144、RSP1091和RSP1090及其同源物。这些酶可以纯化，在体外产生非直链脂肪酸，或在微生物中表达，在体内产生非直链脂肪酸。可以通过表达、过表达或删除酶的各种组合，对微生物进行微调，以生产特定类型的非直链脂肪酸。
• ENZYMES FOR PRODUCING NON-STRAIGHT-CHAIN FATTY ACIDS
  申请人：WISCONSIN ALUMNI RESEARCH FOUNDATION

  公开号：US20150376659A1

  公开（公告）日：2015-12-31

  Enzymes for producing non-straight-chain fatty acids, microorganisms comprising the enzymes, and in vivo and in vitro uses of the enzymes. Provided are enzymes capable of producing various non-straight-chain fatty acids, including branched-chain fatty acids, cyclic fatty acids, and furan-containing fatty acids. The enzymes include RSP2144, RSP1091, and RSP1090 from Rhodobacter sphaeroides and homologs thereof. The enzymes can be purified to produce non-straight-chain fatty acids in vitro or expressed in microorganisms to produce non-straight-chain fatty acids in vivo. The microorganisms can be fine-tuned to produce a specific type of non-straight-chain fatty acid by expressing, overexpressing, or deleting the enzymes in various combinations.
• BRANCHED-CHAIN FATTY ACIDS. XIII. PREPARATION OF BRANCHED AND NORMAL ACIDS FOR USE IN THE STUDY OF MELTING POINTS OF BINARY MIXTURES. COMPLETION OF THE METHYLOCTADECANOIC ACID SERIES
  作者：JAMES CASON、W. ROBERT WINANS

  DOI：10.1021/jo01147a023

  日期：1950.1