5-(9H-carbazol-9-yl)pentanoyl chloride | 1582808-76-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 5-(9H-carbazol-9-yl)pentanoyl chloride
• CAS: 1582808-76-1
• 化学式: C₁₇H₁₆ClNO
• 分子量: 285.773
• InChiKey: OLYIIUIECQWBMW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.73
• 重原子数：
  20.0
• 可旋转键数：
  5.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  22.0
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  氨基丙基庚基-笼形聚倍半硅氧烷 、 5-(9H-carbazol-9-yl)pentanoyl chloride 以 四氢呋喃 为溶剂， 反应 12.0h， 以82%的产率得到5-(9H-carbazol-9-yl)-N-(3-(3,5,7,9,11,13,15-heptaisobutyl-2,4,6,8,10,12,14,16,17,18,19,20-dodecaoxa-1,3,5,7,9,11,13,15-octasilapentacyclo[9.5.1.1^3,9.1^5,15.1^7,13]icosan-1-yl)propyl)pentanamide
  参考文献：
  名称：

  Influence of polyhedral oligomeric silsesquioxanes (POSS) on blue light-emitting materials for OLED

  摘要：

  By using Heck polycondensation, we have synthesized carbazole-based alt-copolymers tethered with polyhedral oligomeric silsesquioxanes (POSS), which had well-defined architectures, similar polymerization degrees and the different contents of POSS. The effect of POSS content and the length of the side chain containing FOSS on the electroluminescence properties of these polymers were investigated. POSS particles in these alt-copolymers showed excellent dispersity and prevented the interchain aggregation of polymers in film state well. Besides, POSS benefited charge balance by increasing the electron current density, which led to a higher luminance and current efficiency, as well as purer blue light-emitting. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2013.11.082
• 作为产物：
  描述：

  5-(9H-carbazol-9-yl)pentanoic acid 在 草酰氯 作用下， 以 苯 为溶剂， 反应 6.0h， 以80%的产率得到5-(9H-carbazol-9-yl)pentanoyl chloride
  参考文献：
  名称：

  Influence of polyhedral oligomeric silsesquioxanes (POSS) on blue light-emitting materials for OLED

  摘要：

  By using Heck polycondensation, we have synthesized carbazole-based alt-copolymers tethered with polyhedral oligomeric silsesquioxanes (POSS), which had well-defined architectures, similar polymerization degrees and the different contents of POSS. The effect of POSS content and the length of the side chain containing FOSS on the electroluminescence properties of these polymers were investigated. POSS particles in these alt-copolymers showed excellent dispersity and prevented the interchain aggregation of polymers in film state well. Besides, POSS benefited charge balance by increasing the electron current density, which led to a higher luminance and current efficiency, as well as purer blue light-emitting. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2013.11.082