9-(3'-(4,6-diphenyl-1,3,5-triazin-2-yl)-[1,1'-biphenyl]-4-yl)-9H-carbazole | 864377-32-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-(3'-(4,6-diphenyl-1,3,5-triazin-2-yl)-[1,1'-biphenyl]-4-yl)-9H-carbazole
• 英文别名: 9-[4-[3-(4,6-Diphenyl-1,3,5-triazin-2-yl)phenyl]phenyl]carbazole
• CAS: 864377-32-2
• 化学式: C₃₉H₂₆N₄
• 分子量: 550.662
• InChiKey: BGWDXNDKWMMEAO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.7
• 重原子数：
  43
• 可旋转键数：
  5
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  43.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  4-(9H-咔唑-9-基)苯硼酸 、 2-(3-溴苯基)-4,6-二苯基-1,3,5-三嗪 在 palladium diacetate 、 potassium carbonate 、 2-二环己基磷-2,4,6-三异丙基联苯 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 6.0h， 以72%的产率得到9-(3'-(4,6-diphenyl-1,3,5-triazin-2-yl)-[1,1'-biphenyl]-4-yl)-9H-carbazole
  参考文献：
  名称：

  热稳定的双极性主体材料，用于高效磷光绿色和蓝色有机发光二极管

  摘要：

  通过改变三嗪和咔唑部分的取代位置，报道了两种双极性主体材料H1（N-连接的咔唑）和H2（C-3-连接的咔唑）。它们的结构和物理性质得到充分表征。热分析表明，H1和H2都具有很高的热稳定性。H1和H2的三重态能级分别确定为2.64和2.7 eV。以H1和H2为主体材料的绿色和蓝色OLED均被制造，以研究其在PHOLED中的性能。基于H1的绿色PHOLED在最大电流效率，最大功率效率和最大亮度分别为51.7 cd / A，37.8 lm / W和132800 cd / m 2的情况下表现出最佳性能，而基于H2的蓝色PHOLED在最大电流下显示出最佳性能效率，最大功率效率和最大亮度分别为21.6 cd / A，17.2 lm / W和16640 cd / m 2。OLED器件的特性测量表明H1和H2是有希望的实际应用宿主材料。通过比较4,4'-双（咔唑-9-基）联苯（CBP）和N，N-二咔唑基-3

  DOI：

  10.1016/j.dyepig.2017.05.004

文献信息

• ORGANIC OPTOELECTRONIC DEVICE AND DISPLAY DEVICE
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US20200144508A1

  公开（公告）日：2020-05-07

  An organic optoelectronic device and a display device including the organic optoelectronic device, the organic optoelectronic device including an anode and a cathode facing each other, a light emitting layer between the anode and the cathode, a hole transport layer between the anode and the light emitting layer, and a hole transport auxiliary layer between the light emitting layer and the hole transport layer, wherein the light emitting layer includes a first compound represented by Chemical Formula 1 and a second compound represented by Chemical Formula 2, and the hole transport auxiliary layer includes a third compound represented by Chemical Formula 3,

  一种有机光电器件和包括该有机光电器件的显示器件，该有机光电器件包括彼此面对的阳极和阴极，位于阳极和阴极之间的发光层，位于阳极和发光层之间的空穴传输层，以及位于发光层和空穴传输层之间的空穴传输辅助层，其中发光层包括化学式1表示的第一化合物和化学式2表示的第二化合物，空穴传输辅助层包括化学式3表示的第三化合物。
• COMPOUND FOR ORGANIC OPTOELECTRONIC DEVICE, COMPOSITION FOR ORGANIC OPTOELECTRONIC DEVICE, ORGANIC OPTOELECTRONIC DEVICE, AND DISPLAY DEVICE
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US20210184128A1

  公开（公告）日：2021-06-17

  The present invention is related to a first compound for an organic optoelectronic device represented by Chemical Formula 1, a composition for an organic optoelectronic device including the same, an organic optoelectronic device, and a display device. In Chemical Formula 1, definitions of each substituent are the same as defined in the specification.

  本发明涉及一种有机光电器件的第一化合物，其化学式表示为化学式1，包括该化合物的有机光电器件的组合物，有机光电器件以及显示装置。 在化学式1中，每个取代基的定义与规范中定义的相同。
• MATERIAL FOR ORGANIC ELECTROLUMINESCENCE DEVICE AND ORGANIC ELECTROLUMINESCENCE DEVICE UTILIZING THE SAME
  申请人：Iwakuma Toshihiro

  公开号：US20090017330A1

  公开（公告）日：2009-01-15

  A material for organic electroluminescence devices of the invention which is for use in combination with at least one phosphorescent metal complex has a specific heterocyclic structure. The material for organic electroluminescence devices is used as a host material or a hole transporting material. An organic electroluminescence device having an anode, a cathode and an organic thin film layer having one or more layers which is interposed between the anode and cathode, in which at least one layer of the organic thin film layer contains the material for organic electroluminescence devices, has a high emitting efficiency, causes little pixel defects, is excellent in heat resistance, and shows a long lifetime.

  该发明的有机电致发光器件材料，用于与至少一种磷光金属配合使用，具有特定的杂环结构。该有机电致发光器件材料用作主体材料或空穴传输材料。具有阳极、阴极和有机薄膜层的有机电致发光器件，该有机薄膜层具有至少一层，位于阳极和阴极之间，其中有机薄膜层的至少一层含有该有机电致发光器件材料，具有高发光效率，几乎没有像素缺陷，具有优异的耐热性，并显示出长寿命。
• MATERIAL FOR ORGANIC ELECTROLUMINESCENT ELEMENT AND ORGANIC ELECTROLUMINESCENT ELEMENT EMPLOYING THE SAME
  申请人：Iwakuma Toshihiro

  公开号：US20090030202A1

  公开（公告）日：2009-01-29

  A material for organic electroluminescence devices for use as a host material in combination with at least one phosphorescent metal complex, which comprises a compound having a specific heterocyclic structure, is described. Also described is an organic electroluminescence device having an anode, a cathode and an organic thin film layer having one or more layers. The organic thin film layer is interposed between the anode and cathode and has a light emitting layer containing a host material in combination with at least one phosphorescent metal complex. At least one layer of the organic thin film layer contains the material for organic electroluminescence devices. The material for organic electroluminescence devices provides an organic electroluminescence device which has a high emitting efficiency, causes little pixel defects, is excellent in heat resistance, and show a long lifetime.

  本文描述了一种用于有机电致发光器件的材料，可与至少一种磷光金属配合使用作为主体材料，其包含具有特定杂环结构的化合物。还描述了一种有机电致发光器件，其具有阳极、阴极和具有一个或多个层的有机薄膜层。有机薄膜层位于阳极和阴极之间，并具有包含主体材料与至少一种磷光金属配合的发光层。有机薄膜层的至少一层含有用于有机电致发光器件的材料。该材料为有机电致发光器件提供了高发光效率，几乎不会产生像素缺陷，具有优异的耐热性，并展现长寿命。
• ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP1923929A1

  公开（公告）日：2008-05-21

  An organic electroluminescent device (1) including an anode (2), a cathode (6), and at least a first layer (3), a second layer (4), and a third layer (5) provided between the anode (2) and the cathode (6) in that order from the anode side. At least one of the first to third layers (3), (4), and (5) includes a phosphorescent compound. At least one of the first to third layers (3), (4), and (5) is an emitting layer. At least three compounds respectively forming the first layer (3), the second layer (4), and the third layer (5) other than the phosphorescent compound are compounds of the following formula (1). wherein R1 to R7 each represent a hydrogen atom or a substituent, provided that adjacent substituents may form a ring.

  一种有机电致发光器件 (1)，包括阳极 (2)、阴极 (6)，以及至少一个第一层 (3)、一个第二层 (4) 和一个第三层 (5)，从阳极侧依次设置在阳极 (2) 和阴极 (6) 之间。第一至第三层（3）、（4）和（5）中至少有一层包括磷光化合物。第一至第三层（3）、（4）和（5）中至少有一层是发光层。除磷光化合物外，分别形成第一层（3）、第二层（4）和第三层（5）的至少三种化合物是下式（1）的化合物。 其中 R1 至 R7 各代表一个氢原子或一个取代基，但相邻取代基可形成一个环。