2-methyl-1,3-propanediol dipropenoate | 86168-86-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-methyl-1,3-propanediol dipropenoate
• 英文别名: 2-methylpropane-1,3-diyldipropenoate；2-methyl-1,3-propanediol diacrylate；2-methylpropane-1,3-diyl diacrylate；1,3-isobutanediol diacrylate；(2-methyl-3-prop-2-enoyloxypropyl) prop-2-enoate
• CAS: 86168-86-7
• 化学式: C₁₀H₁₄O₄
• 分子量: 198.219
• InChiKey: LBDSQNRQXIKAGX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  14
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-甲基-1,3-丙二醇 、 丙烯酸甲酯（MA） 在 Novozyme 435 作用下， 以 2-methyl-2-butanol 为溶剂， 反应 24.0h， 生成 2-methyl-3-hydroxypropyl acrylate 、 2-methyl-1,3-propanediol dipropenoate
  参考文献：
  名称：

  自由基和氮氧化物介导的通过脂肪酶催化的酰基转移反应制备的羟基官能丙烯酸酯的聚合

  摘要：

  丙烯酸3-羟基丙酯，丙烯酸4-羟基丁酯，丙烯酸2-甲基-3-羟基丙酯，丙烯酸2-羟基丙基，丙烯酸新戊二醇酯，丙烯酸甘油酯和丙烯酸二羟基己酯是通过南极假丝酵母催化的丙烯酸甲酯与二醇和三醇的酰基转移反应制得的在通过过滤除去酶并通过蒸馏除去丙烯酸甲酯之后，将单体通过自由基聚合（FRP）与偶氮二异丁腈作为引发剂进行聚合，并使用Blocbuilder™烷氧基胺引发剂和SG-1游离硝基氧化物进行氮氧化物介导聚合（NMP）。产生羟基官能的聚（丙烯酸酯）。NMP动力学进行了详细讨论。另外，比较了通过FRP和NMP获得的聚合物，并且结果与由酰基转移反应产生的初始单体混合物中存在的双丙烯酸酯的量有关。©2010 Wiley Periodicals，Inc. J Polym Sci A部分：Polym Chem 48：2610–2621，2010

  DOI：

  10.1002/pola.24041

文献信息

• Diurethane (meth)acrylate-silane compositions and articles including the same
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US10011735B2

  公开（公告）日：2018-07-03

  Diurethane (meth)acrylate-silane precursor compounds prepared by reacting a primary or secondary aminosilane with a cyclic carbonate to yield a hydroxylalkylene-carbamoylalkylene-alkoxysilanes (referred to as a “hydroxylcarbamoylsilane”), which is reacted with a (meth)acrylated material having isocyanate functionality, either neat or in solvent, and optionally with a catalyst, such as a tin compound. Also described are articles including a substrate, a base (co)polymer layer on a major surface of the substrate, an oxide layer on the base (co)polymer layer; and a protective (co)polymer layer on the oxide layer, the protective (co)polymer layer including the reaction product of at least one diurethane (meth)acrylate-silane precursor compound. The substrate may be a (co)polymer film or an electronic device such as an organic light emitting device, electrophoretic light emitting device, liquid crystal display, thin film transistor, or combination thereof. Methods of making the diurethane (meth)acrylate-silane and their use in composite films and electronic devices are described.

  通过使伯氨基或仲氨基硅烷与环状碳酸酯反应生成羟基烷基-氨基甲酰基烷基-烷氧基硅烷（简称为 "羟基氨基甲酰基硅烷"），再与具有异氰酸酯官能团的（甲基）丙烯酸酯化材料反应制备的聚氨酯（甲基）丙烯酸酯-硅烷前体化合物，反应物可以是纯的，也可以在溶剂中进行，还可以选择使用催化剂，如锡化合物。还描述了包括基底、基底主要表面上的基底（共）聚合物层、基底（共）聚合物层上的氧化物层和氧化物层上的保护（共）聚合物层的物品，保护（共）聚合物层包括至少一种二氨基甲酸酯（甲基）丙烯酸酯-硅烷前体化合物的反应产物。基底可以是（共）聚合物薄膜或电子设备，如有机发光设备、电泳发光设备、液晶显示器、薄膜晶体管或其组合。本文介绍了制造（甲基）丙烯酸酯-硅烷的方法及其在复合薄膜和电子设备中的应用。
• Urea (multi)-(meth)acrylate (multi)-silane compositions and articles including the same
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US10774236B2

  公开（公告）日：2020-09-15

  Urea (multi)-(meth)acrylate (multi)-silane precursor compounds, synthesized by reaction of (meth)acrylated materials having isocyanate functionality with aminosilane compounds, either neat or in a solvent, and optionally with a catalyst, such as a tin compound, to accelerate the reaction. Also described are articles including a substrate, a base (co)polymer layer on a major surface of the substrate, an oxide layer on the base (co)polymer layer; and a protective (co)polymer layer on the oxide layer, the protective (co)polymer layer including the reaction product of at least one urea (multi)-(meth)acrylate (multi)-silane precursor compound synthesized by reaction of (meth)acrylated materials having isocyanate functionality with aminosilane compounds. The substrate may be a (co)polymer film or an electronic device such as an organic light emitting device, electrophoretic light emitting device, liquid crystal display, thin film transistor, or combination thereof. Methods of making the urea (multi)-(meth)acrylate (multi)-silanes and their use in composite films and electronic devices are described.

  尿素（多元）-（甲基）丙烯酸酯（多元）-硅烷前体化合物，由具有异氰酸酯官能度的（甲基）丙烯酸酯材料与氨基硅烷化合物反应合成，可单独或在溶剂中进行，也可选择使用催化剂（如锡化合物）加速反应。还描述了包括基底、基底主要表面上的基底（共）聚合物层、基底（共）聚合物层上的氧化物层；以及氧化物层上的保护（共）聚合物层，保护（共）聚合物层包括通过具有异氰酸酯官能度的（甲基）丙烯酸酯材料与氨基硅烷化合物反应合成的至少一种脲（多元）-（甲基）丙烯酸酯（多元）-硅烷前体化合物的反应产物。基底可以是（共）聚合物薄膜或电子装置，如有机发光装置、电泳发光装置、液晶显示器、薄膜晶体管或其组合。本文介绍了脲基（多元）-（甲基）丙烯酸酯（多元）-硅烷的制造方法及其在复合薄膜和电子设备中的应用。
• Hydroxy functional acrylate and methacrylate monomers prepared via lipase—catalyzed transacylation reactions
  作者：Dragos Popescu、Richard Hoogenboom、Helmut Keul、Martin Moeller

  DOI：10.1016/j.molcatb.2009.09.008

  日期：2010.1

  Candida antarctica lipase B (CAL-B, Novozyme 435) catalyzes the transacylation of methyl acrylate and methyl methacrylate with diols and triols in 2-methyl-2-butanol at 50 degrees C. Under the experimental conditions, up to 70 mol% of the acyl donor methyl acrylate was converted. Methyl methacrylate is the less efficient acyl donor (up to 60 mol%) due to the higher sterical hindrance in the enzymatic transacylation. Under the reaction conditions high yields of the mono-acylated products are obtained, which contain minor amounts of bis(meth)acrylates. In addition it was observed that Novozyme 435 catalyzes regioselectively the acylation of the primary hydroxyl groups. In comparison with the chemical catalyzed route no selectivity was observed for unsubstituted diols. For substituted diols more mono-acylated product was formed in the lipase-catalyzed reaction than in the chemical catalyzed reaction. (C) 2009 Elsevier B.V. All rights reserved.
• Lithographic printing plate precursor
  申请人：FUJIFILM Corporation

  公开号：EP1096314B1

  公开（公告）日：2011-10-19
• PHOTOSENSITIVE POLYIMIDES
  申请人：CHOU MENG-YEN

  公开号：US20090181324A1

  公开（公告）日：2009-07-16

  The present invention relates to an isocyanate-modified photosensitive polyimide. The photosensitive polyimide of the invention possesses excellent heat resistance, chemistry resistance, and flexibility, and can be used as a liquid photo resist or dry film resist, or used in a solder resist, coverlay film, or printed wiring board.