5-Methoxy-1-azapentacyclo[10.6.1.02,7.08,19.013,18]nonadeca-2(7),3,5,8,10,12(19),13,15,17-nonaene | 1309072-73-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 5-Methoxy-1-azapentacyclo[10.6.1.02,7.08,19.013,18]nonadeca-2(7),3,5,8,10,12(19),13,15,17-nonaene
• CAS: 1309072-73-8
• 化学式: C₁₉H₁₃NO
• 分子量: 271.318
• InChiKey: UWWOWGQDMCQIKU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  21
• 可旋转键数：
  1
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  13.6
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-溴-1-碘-4-甲氧基苯 在 copper(l) iodide 、 Et₃NBnCl 、 palladium diacetate 、 potassium carbonate 、 三苯基膦 作用下， 以 N,N-二甲基乙酰胺 为溶剂， 反应 54.0h， 生成 5-Methoxy-1-azapentacyclo[10.6.1.02,7.08,19.013,18]nonadeca-2(7),3,5,8,10,12(19),13,15,17-nonaene
  参考文献：
  名称：

  通过钯催化的分子内环化反应轻松合成吲哚[3,2,1- jk ]咔唑

  摘要：

  描述了一种新的高效合成吲哚[3,2,1- jk ]咔唑的方法，该方法通过钯催化的N-（2-溴芳基）咔唑的环化反应来实现。该反应涉及分子内CC键的形成，以及咔唑环上CX键和CH键的断裂。引入具有给电子基团或吸电子基团的N-芳基核上的取代基，并评估了用于环化的不同反应因子。

  DOI：

  10.1016/j.tetlet.2012.07.093

文献信息

• ORGANIC ELECTROLUMINESCENCE ELEMENT AND ELECTRONIC APPARATUS
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20210005826A1

  公开（公告）日：2021-01-07

  An organic electroluminescence device comprising a cathode, an anode and an organic layer disposed between the cathode and the anode, wherein the organic layer comprises a fluorescent emitting layer and the fluorescent emitting layer comprises a first compound, a second compound having a hole mobility larger than that of the first compound, and a dopant material showing a fluorescent spectrum with a half width of 30 nm or less; and an organic electroluminescence device comprising a cathode, an anode and an organic layer disposed between the cathode and the anode, wherein the organic layer comprises a fluorescent emitting layer and the fluorescent emitting layer comprises a first compound, a third compound having an affinity larger than that of the first compound, and a dopant material showing a fluorescent spectrum with a half width of 30 nm or less and the content of the third compound in the fluorescent emitting layer is less than that of the first compound in the fluorescent emitting layer are excellent in their performance.

  一种有机电致发光装置，包括阴极、阳极以及设置在阴极和阳极之间的有机层，其中所述有机层包括荧光发射层，且所述荧光发射层包括第一化合物、第二化合物和掺杂材料，所述第二化合物的空穴迁移率大于所述第一化合物，且所述掺杂材料显示的荧光光谱半宽为30纳米或更小；以及一种有机电致发光装置，包括阴极、阳极以及设置在阴极和阳极之间的有机层，其中所述有机层包括荧光发射层，且所述荧光发射层包括第一化合物、第三化合物和掺杂材料，所述第三化合物与所述第一化合物的亲和力更大，且所述掺杂材料显示的荧光光谱半宽为30纳米或更小，且所述第三化合物在荧光发射层中的含量小于所述第一化合物在荧光发射层中的含量，这些装置的性能都十分出色。
• ORGANIC ELECTROLUMINESCENT ELEMENT AND ELECTRONIC DEVICE
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20210005825A1

  公开（公告）日：2021-01-07

  An organic electroluminescence device comprising a cathode, an anode and an organic layer disposed between the cathode and the anode, wherein the organic layer comprises a fluorescent emitting layer and the fluorescent emitting layer comprises at least one first compound selected from the compounds represented by formulae (19), (21), (22), and (23), a second compound selected from the compounds represented by formula (3a), and a dopant material selected from the compounds represented by formulae (D1) and (D2) is excellent in its performance.

  一个有机电致发光装置，包括阴极、阳极和位于阴极与阳极之间的有机层，其中所述有机层包括荧光发射层，且所述荧光发射层包括至少一种由公式（19）、（21）、（22）和（23）所表示的化合物中选择的第一化合物，一种由公式（3a）所表示的化合物中选择的第二化合物，以及一种由公式（D1）和（D2）所表示的化合物中选择的掺杂材料，其性能卓越。
• Strained Dehydrogenative Ring Closure of Phenylcarbazoles
  作者：Alexander W. Jones、Marie-Laure Louillat-Habermeyer、Frederic W. Patureau

  DOI：10.1002/adsc.201401136

  日期：2015.3.23

  and strained dehydrogenative ring closure, for example, in phenylcarbazoles? Since the works of Buchwald and Fagnou, palladium‐catalysed ring‐closing dehydrogenative reactions are legion, but will not operate when the strain at the reductive elimination stage becomes too large. We propose here a “muscled up” super‐oxidative palldium‐catalysed CH activation method for the ring closure of strained phenylcarbazoles

  强制在苯咔唑类化合物中进行刚性且紧张的脱氢环关闭，需要采取什么措施？由于Buchwald和Fagnou的工作，钯催化的闭环脱氢反应是一团大事，但是当还原消除阶段的应变变得太大时，钯将不起作用。在这里，我们提出了“肌肉了”超氧化palldium催化Ç  ^ h活化紧张phenylcarbazoles的闭环方法。
• ORGANIC ELECTROLUMINESCENCE ELEMENT AND ELECTRONIC DEVICE
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20200052225A1

  公开（公告）日：2020-02-13

  Organic EL devices having excellent performance and electronic devices comprising the organic EL devices are provided. The organic EL device comprises a cathode, an anode, and an organic layer disposed between the cathode and the anode, wherein the organic layer comprises one or more layers that comprise a fluorescent emitting layer and the fluorescent emitting layer comprises a first compound represented by formula (P) and a second compound that is not the same as the first compound. The electronic device comprises the organic EL device. wherein, π1, π2, Z, R B , R C , m, and n are as defined in the description.