9-(4-butylphenyl)carbazole-3-carbaldehyde | 1357350-86-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-(4-butylphenyl)carbazole-3-carbaldehyde
• CAS: 1357350-86-7
• 化学式: C₂₃H₂₁NO
• 分子量: 327.426
• InChiKey: DLBAQMQDOXTVFR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.94
• 重原子数：
  25.0
• 可旋转键数：
  5.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  22.0
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  9-(4-butylphenyl)carbazole-3-carbaldehyde 在 sodium sulfate 、 三乙胺 、 potassium hydroxide 作用下， 以 甲醇 、 丁酮 为溶剂， 反应 25.0h， 生成 1,3-bis{4-[9-(4-butylphenyl)carbazole-3-methylene-1-phenylhydrazino](3-hydroxy)thiabutyl}benzene
  参考文献：
  名称：

  9-Phenylcarbazole–Based Hydrazone Twin Compounds as P-Type Organic Semiconductors

  摘要：

  Hole transporting glass-forming low-molar-mass hydrazones containing 9-phenylcarbazole moiety were synthesized and characterized by NMR-, infrared- and mass spectrometries. The thermal, optical and photoelectrical properties of the synthesized compounds are reported. Compounds containing 1,3-benzendithiol linking bridge were isolated as amorphous materials therefore differential scanning calorimetry experiments revealed glass transitions approximately at 60 degrees C. The ionization potentials of the synthesized compounds were measured by electron photoemission technique in air range from 5.23eV to 5.4eV. Hole drift mobilities in the films of the solid solutions of some of the synthesized hydrazones in bisphenol Z polycarbonate measured by the time-of-flight technique exceed 10-5cm2V-1s-1 at high electric fields.

  DOI：

  10.1080/15421406.2011.538605
• 作为产物：
  描述：

  9-(4-butylphenyl)-9H-carbazole 、 N,N-二甲基甲酰胺 在 三氯氧磷 作用下， 以78%的产率得到9-(4-butylphenyl)carbazole-3-carbaldehyde
  参考文献：
  名称：

  9-Phenylcarbazole–Based Hydrazone Twin Compounds as P-Type Organic Semiconductors

  摘要：

  Hole transporting glass-forming low-molar-mass hydrazones containing 9-phenylcarbazole moiety were synthesized and characterized by NMR-, infrared- and mass spectrometries. The thermal, optical and photoelectrical properties of the synthesized compounds are reported. Compounds containing 1,3-benzendithiol linking bridge were isolated as amorphous materials therefore differential scanning calorimetry experiments revealed glass transitions approximately at 60 degrees C. The ionization potentials of the synthesized compounds were measured by electron photoemission technique in air range from 5.23eV to 5.4eV. Hole drift mobilities in the films of the solid solutions of some of the synthesized hydrazones in bisphenol Z polycarbonate measured by the time-of-flight technique exceed 10-5cm2V-1s-1 at high electric fields.

  DOI：

  10.1080/15421406.2011.538605