Co(nitrilotriacetate)(1-) | 18976-16-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Co(nitrilotriacetate)(1-)
• 英文别名: Co(II)(nitrilotriacetate)；[Co(nitrilotriacetate)(3-))](1-)
• CAS: 18976-16-4
• 化学式: C₆H₆NO₆*Co
• 分子量: 247.11
• InChiKey: KBRVZMLUGBMYEF-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -5.46
• 重原子数：
  14.0
• 可旋转键数：
  6.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  123.63
• 氢给体数：
  0.0
• 氢受体数：
  7.0

反应信息

• 作为反应物：
  描述：

  酮羧酸 、 Co(nitrilotriacetate)(1-) 以 水 为溶剂， 生成
  参考文献：
  名称：

  Magnetic field effects in rates of reactions between radicals and transition metal coordination complexes of cobalt(II) and manganese(II): probes for spin polarization

  摘要：

  The effect of magnetic fields on the rates of reactions of Cl-2-, Br-2-, and CO3H with Co(II) and Mn(II) complexes was investigated as a function of the field intensity between 0 and 7 T. The Delta g mechanism and suppression of HFC-induced transitions in radical-ion pairs account for effects observed at less than 0.3 T on reactions with high-spin Co(II) complexes. In the reaction between Co(Me(6)-[14]dieneN(4))(2+) and Cl-2-, MFE on the rate are mostly related to the suppression of HFC-induced transitions in the radical-ion pairs. In a number of these processes the reaction rate constant increases with field and the sense of MFE in reactions of the CO3H radical appears inverted with respect to reactions of Cl-2- and Br-2-. A mechanism that accounts for such differences is discussed.

  DOI：

  10.1021/j100148a014
• 作为产物：
  描述：

  nitrilotriacetate 、 cobalt(II) nitrate 以 硝酸 为溶剂， 生成 Co(nitrilotriacetate)(1-)
  参考文献：
  名称：

  Pandey; Pandey, Journal of the Indian Chemical Society, 1999, vol. 76, # 1, p. 38 - 40

  摘要：

  DOI：

文献信息

• Mentasti, Edoardo, Journal of the Chemical Society, Dalton Transactions, 1982, p. 721 - 726
  作者：Mentasti, Edoardo

  DOI：——

  日期：——