2-[[2-[[2-[[2-[[2-[[2-[[2-[[2-(Oxan-2-yloxymethyl)phenyl]methyl]phenyl]methyl]phenyl]methyl]phenyl]methyl]phenyl]methyl]phenyl]methyl]phenyl]methoxy]oxane | 1027527-66-7

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 2-[[2-[[2-[[2-[[2-[[2-[[2-[[2-(Oxan-2-yloxymethyl)phenyl]methyl]phenyl]methyl]phenyl]methyl]phenyl]methyl]phenyl]methyl]phenyl]methyl]phenyl]methoxy]oxane
• CAS: 1027527-66-7
• 化学式: C₆₀H₆₂O₄
• 分子量: 847.15
• InChiKey: KBNBZZYRSXQCME-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.5
• 重原子数：
  64
• 可旋转键数：
  18
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-[[2-[[2-[[2-[[2-[[2-[[2-[[2-(Oxan-2-yloxymethyl)phenyl]methyl]phenyl]methyl]phenyl]methyl]phenyl]methyl]phenyl]methyl]phenyl]methyl]phenyl]methoxy]oxane 在 Celite 、 对甲苯磺酸 、 pyridinium chlorochromate 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 反应 2.0h， 生成 1,2-Bis<2-<2-(2-formylbenzyl)benzyl>benzyl>benzene
  参考文献：
  名称：

  Orthocyclophanes. 3. Ketonands, Novel Ketonic Crowns of Polyoxo[1n]orthocyclophane Constitution

  摘要：

  Synthetic studies of a new family of novel ketonic macrocycles are reported. Exhaustive oxidation of all of the methylenes in odd-numbered [1(n)]orthocyclophanes ([1(n)]OCPs) resulted in the polyoxo derivatives of a cyclopolyorthobenzoyl or polyoxo[1(n)]orthocyclophane constitution. This new class of ketonic crowns is referred to as [1(n)]orthocyclophanepolyones and includes [1(5)] orthocyclophane-pentaone, [1(7)]orthocyclophaneheptaone, and [1(9)]orthocyclophanenonaone. We suggest the generic name ''ketonands'' for these ketonic crowns. Structures of ketonands were confirmed by spectral and X-ray crystallographic analyses.

  DOI：

  10.1021/jo00083a033
• 作为产物：
  描述：

  2-(tetrahydropyranyloxy)methylbromobenzene 在 copper(l) iodide 、 氢溴酸 、 对甲苯磺酸 、 magnesium 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 反应 35.0h， 生成 2-[[2-[[2-[[2-[[2-[[2-[[2-[[2-(Oxan-2-yloxymethyl)phenyl]methyl]phenyl]methyl]phenyl]methyl]phenyl]methyl]phenyl]methyl]phenyl]methyl]phenyl]methoxy]oxane
  参考文献：
  名称：

  Lee, Woo Young; Sim, Wonbo; Kim, Hyo-Joong, Journal of the Chemical Society. Perkin transactions I, 1993, # 6, p. 719 - 730

  摘要：

  DOI：

文献信息

• Lee, Woo Young; Sim, Wonbo; Kim, Hyo-Joong, Journal of the Chemical Society. Perkin transactions I, 1993, # 6, p. 719 - 730
  作者：Lee, Woo Young、Sim, Wonbo、Kim, Hyo-Joong、Yoon, Sung-Hwa

  DOI：——

  日期：——
• Orthocyclophanes. 3. Ketonands, Novel Ketonic Crowns of Polyoxo[1n]orthocyclophane Constitution
  作者：Woo Young Lee、Chang Hee Park、Hyo-Joong Kim、Sangsoo Kim

  DOI：10.1021/jo00083a033

  日期：1994.2

  Synthetic studies of a new family of novel ketonic macrocycles are reported. Exhaustive oxidation of all of the methylenes in odd-numbered [1(n)]orthocyclophanes ([1(n)]OCPs) resulted in the polyoxo derivatives of a cyclopolyorthobenzoyl or polyoxo[1(n)]orthocyclophane constitution. This new class of ketonic crowns is referred to as [1(n)]orthocyclophanepolyones and includes [1(5)] orthocyclophane-pentaone, [1(7)]orthocyclophaneheptaone, and [1(9)]orthocyclophanenonaone. We suggest the generic name ''ketonands'' for these ketonic crowns. Structures of ketonands were confirmed by spectral and X-ray crystallographic analyses.