(+/-)-Heptadeca-1,6t,8t,10t-tetraen-4-in-3-ol | 13894-57-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (+/-)-Heptadeca-1,6t,8t,10t-tetraen-4-in-3-ol
• 英文别名: (6E,8E,10E)-heptadeca-1,6,8,10-tetraen-4-yn-3-ol；heptadeca-1,6t,8t,10t-tetraen-4-yn-3-ol
• CAS: 13894-57-0
• 化学式: C₁₇H₂₄O
• 分子量: 244.377
• InChiKey: AXKPLCWMEYNSKC-OFYUHDMGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  18
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.41
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (+/-)-Heptadeca-1,6t,8t,10t-tetraen-4-in-3-ol 在 manganese(IV) oxide 作用下， 以 四氢呋喃 为溶剂， 以94%的产率得到(6E,8E,10E)-heptadeca-1,6,8,10-tetraen-4-yn-3-one
  参考文献：
  名称：

  Pd-catalyzed regio and stereocontrolled mono and bis-coupling reactions of 1-bromo-6-chlorohexa-1,3,5-triene: synthesis of a naturally occurring tetraenynone

  摘要：

  The synthesis of new 1,6-dihalogenohexatrienes is described. The chemoselectivity of pallado-catalyzed cross-coupling reaction is Studied and a short synthesis, by Negishi and Sonogashira reactions, of a natural product is described. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2009.01.037
• 作为产物：
  描述：

  *Non-2-en-1-yl-triphenyl-phosphonium-bromid 生成 (+/-)-Heptadeca-1,6t,8t,10t-tetraen-4-in-3-ol
  参考文献：
  名称：

  Bohlmann,F. et al., Chemische Berichte, 1966, vol. 99, p. 3552 - 3558

  摘要：

  DOI：

文献信息

• Pd-catalyzed regio and stereocontrolled mono and bis-coupling reactions of 1-bromo-6-chlorohexa-1,3,5-triene: synthesis of a naturally occurring tetraenynone
  作者：Wissam Bentoumi、Jérôme Helhaik、Gérard Plé、Yvan Ramondenc

  DOI：10.1016/j.tet.2009.01.037

  日期：2009.3

  The synthesis of new 1,6-dihalogenohexatrienes is described. The chemoselectivity of pallado-catalyzed cross-coupling reaction is Studied and a short synthesis, by Negishi and Sonogashira reactions, of a natural product is described. (C) 2009 Elsevier Ltd. All rights reserved.
• Bohlmann,F. et al., Chemische Berichte, 1966, vol. 99, p. 3552 - 3558
  作者：Bohlmann,F. et al.

  DOI：——

  日期：——