Δ(3)-Cyclohexen-aldehyd | 109716-56-5

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 英文名称: Δ(3)-Cyclohexen-aldehyd
• 英文别名: (S)-3-cyclohexene-1-carbaldehyde；(1S)-cyclohex-3-ene-1-carbaldehyde
• CAS: 109716-56-5
• 化学式: C₇H₁₀O
• mdl: MFCD00001572
• 分子量: 110.156
• InChiKey: DCFDVJPDXYGCOK-SSDOTTSWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  8
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1,3-丁二烯 、 丙烯醛 在 [bis[3,5-bis(trifluoromethyl)phenyl]-[(2S)-pyrrolidin-1-ium-2-yl]methoxy]trimethylsilane perchlorate 作用下， 以 水 、 乙腈 为溶剂， 反应 48.0h， 生成 (R)-1-C-(1-Cyclohexen-5-yl)carbaldehyde 、 Δ(3)-Cyclohexen-aldehyd
  参考文献：
  名称：

  二芳基脯氨醇甲硅烷基醚盐在水的存在下催化的α，β-不饱和醛的不对称Diels-Alder反应。

  摘要：

  DOI：

  10.1002/anie.200801408

文献信息

• INHIBITORS OF BETA-SECRETASE
  申请人：Vitae Pharmaceuticals, Inc.

  公开号：EP2324032B1

  公开（公告）日：2014-10-01
• FRAGRANCE AND FLAVOR MATERIALS
  申请人：Takasago International Corporation

  公开号：EP3802475A1

  公开（公告）日：2021-04-14
• USE OF VOLATILE COMPOUNDS TO MODULATE THE PERCEPTION OF FLORAL MUGUET
  申请人：Firmenich SA

  公开号：EP3853328A2

  公开（公告）日：2021-07-28
• [EN] USE OF VOLATILE COMPOUNDS TO MODULATE THE PERCEPTION OF FLORAL MUGUET<br/>[FR] UTILISATION DE COMPOSÉS VOLATILS POUR MODULER LA PERCEPTION DU MUGUET FLORAL
  申请人：FIRMENICH & CIE

  公开号：WO2020127325A2

  公开（公告）日：2020-06-25

  The various aspects presented herein relate to the perfumery industry. More particularly, the various aspects presented herein relate to compositions and/or ingredients that increase a subject's perception of floral muguet compounds, methods for intensifying a subject's perception of floral muguet compounds, as well as to the perfumed articles or perfuming compositions comprising as an active ingredient, at least one compound selected from octanal; (E)-dec-2-enal, 2-phenylpropanal; (E)-but-2-enal; 3-methylbenzaldehyde; 3-(1,3- benzodioxol-5-yl)-2-methylpropanal; (+-)-3-(4-methyl-3-penten-1-yl)-3-cyclohexene-1-carbaldehyde, (+-)-4-(4-methyl-3-penten-1-yl)-3-cyclohexene-1-carbaldehyde, and mixtures thereof; heptanal, 4-Propan-2-ylbenzaldehyde; (3R)-3,7-dimethyloct-6-enal; (+)-(3S)-3- [(1R)-4-methyl-3-cyclohexen-1-yl]butanal, (+)-(3R)-3-[(1R)-4-methyl-3-cyclohexen-1- yl]butanal, and mixtures thereof; hexanal; 2,6-dimethylhept-5-enal; benzaldehyde; 2-methyl- 3-(4-methylphenyl)propanal; 3,5,6-trimethyl-3-cyclohexene-1-carbaldehyde, 2,4,6-trimethyl- 3-cyclohexene-1-carbaldehyde, and mixtures thereof; 4-ethylbenzaldehyde; 6-methoxy-2,6- dimethylheptanal; (E)-non-2-enal; and combinations thereof.
• Asymmetric Diels-Alder Reactions of α,β-Unsaturated Aldehydes Catalyzed by a Diarylprolinol Silyl Ether Salt in the Presence of Water
  作者：Yujiro Hayashi、Sampak Samanta、Hiroaki Gotoh、Hayato Ishikawa

  DOI：10.1002/anie.200801408

  日期：2008.8.18