9-(bis(4-(allyloxy)phenyl)methylene)-9H-fluorene | 1353580-61-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 9-(bis(4-(allyloxy)phenyl)methylene)-9H-fluorene
• 英文别名: 9-[Bis(4-prop-2-enoxyphenyl)methylidene]fluorene；9-[bis(4-prop-2-enoxyphenyl)methylidene]fluorene
• CAS: 1353580-61-6
• 化学式: C₃₂H₂₆O₂
• 分子量: 442.557
• InChiKey: ZXGSRTWIVWVGJJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.3
• 重原子数：
  34
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  9-芴酮 在 四(三苯基膦)钯 、 potassium acetate 、 亚磷酸三乙酯 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 17.0h， 生成 9-(bis(4-(allyloxy)phenyl)methylene)-9H-fluorene
  参考文献：
  名称：

  Palladium catalyzed atom-economic synthesis of functionalized 9-(diarylmethylene)-9H-fluorenes using triarylbismuths in one-pot bis-coupling process

  摘要：

  An efficient palladium catalyzed atom-economic synthesis of functionalized 9-(diarylmethylene)-9H-fluorenes has been accomplished in one-pot bis-coupling process using triarylbismuths as organometallic reagents. These bis-couplings in 1 hour short reaction time afforded various 9-(diarylmethylene)-9H-fluorenes in good to high yields. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.10.156

文献信息

• Palladium catalyzed atom-economic synthesis of functionalized 9-(diarylmethylene)-9H-fluorenes using triarylbismuths in one-pot bis-coupling process
  作者：Maddali L.N. Rao、Priyabrata Dasgupta

  DOI：10.1016/j.tetlet.2011.10.156

  日期：2012.1

  An efficient palladium catalyzed atom-economic synthesis of functionalized 9-(diarylmethylene)-9H-fluorenes has been accomplished in one-pot bis-coupling process using triarylbismuths as organometallic reagents. These bis-couplings in 1 hour short reaction time afforded various 9-(diarylmethylene)-9H-fluorenes in good to high yields. (C) 2011 Elsevier Ltd. All rights reserved.