1-hexa-2t,4t-dienyloxy-2-methacryloyloxy-ethane | 108595-19-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 1-hexa-2t,4t-dienyloxy-2-methacryloyloxy-ethane
• 英文别名: 1-Hexa-2t,4t-dienyloxy-2-methacryloyloxy-aethan；2-methacryloyloxyethyl sorbate；2-(2-methylprop-2-enoyloxy)ethyl (2E,4E)-hexa-2,4-dienoate
• CAS: 108595-19-3
• 化学式: C₁₂H₁₆O₄
• 分子量: 224.257
• InChiKey: NLTIJJMRGGHOTL-YTXTXJHMSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  16
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  甲基丙烯酸甲酯 在 吡啶 、 乙醚 、 对甲苯磺酸 作用下， 生成 1-hexa-2t,4t-dienyloxy-2-methacryloyloxy-ethane
  参考文献：
  名称：

  Sigwalt, Bulletin de la Societe Chimique de France, 1959, p. 64

  摘要：

  DOI：

文献信息

• Degradable polymer and process for production thereof
  申请人：Matsumoto Akikazu

  公开号：US20090069448A1

  公开（公告）日：2009-03-12

  In one embodiment of the present invention, a degradable polymer having a peroxide bond therein is disclosed. The degradable polymer can be utilized in the fields of medicals or medical materials, can be applied to a DDS or gene delivery system, and can be used as a novel polymeric material or environmentally-friendly material. A polyperoxide, which is an alternating copolymer, has in a side chain thereof, a functional group (which is a substituent comprising a therapeutic molecule), a water-soluble substituent, or a biodegradable substituent.

  在本发明的一个实施例中，揭示了具有过氧化物键的可降解聚合物。这种可降解聚合物可以应用于医学领域或医疗材料领域，可以用于DDS或基因传递系统，并可用作新型聚合材料或环保材料。一种聚过氧化物，即交替共聚物，在其侧链中具有一个功能基团（该基团包括治疗分子）、水溶性基团或可生物降解基团。
• DEGRADABLE POLYMER AND PROCESS FOR PRODUCTION THEREOF
  申请人：Japan Science and Technology Agency

  公开号：EP1897898A1

  公开（公告）日：2008-03-12

  Disclosed is a degradable polymer having a peroxide bond therein. The degradable polymer can be utilized in the fields of medicals or medical materials, can be applied to a DDS or gene delivery system, and can be used as a novel polymeric material or environmentally-friendly material. A polyperoxide (114), which is an alternating copolymer, has in a side chain thereof, a functional group (112) (which is a substituent comprising a therapeutic molecule), a water-soluble substituent, or a biodegradable substituent.

  本发明公开了一种具有过氧化物键的可降解聚合物。这种可降解聚合物可用于医疗或医用材料领域，可应用于 DDS 或基因递送系统，还可用作新型聚合物材料或环保材料。聚过氧化物（114）是一种交替共聚物，在其侧链中有一个官能团（112）（这是一个包含治疗分子的取代基）、一个水溶性取代基或一个可生物降解的取代基。
• Champetier et al., Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1958, vol. 246, p. 769
  作者：Champetier et al.

  DOI：——

  日期：——
• POLYMERIZABLE MONOMER, POLYMER COMPOUND, BIOLOGICAL ELECTRODE COMPOSITION, BIOLOGICAL ELECTRODE, AND METHOD FOR PRODUCING BIOLOGICAL ELECTRODE
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20180197653A1

  公开（公告）日：2018-07-12

  The present invention provides: a biological electrode composition formable a living body contact layer for a biological electrode which is excellent in conductivity and biocompatibility, as well as light in the weight thereof and producible at a low cost, and in addition, which does not cause a significant decrease in the conductivity thereof regardless of under a water-wet condition and a dry condition; a polymer compound which can be suitably used for the biological electrode composition; a polymerizable monomer suitable as a raw material of the polymer compound; a biological electrode having a living body contact layer formed of the biological electrode composition; and a method for producing the same; and wherein, the polymerizable monomer is represented by the following general formula (1).
• BIO-ELECTRODE COMPOSITION, BIO-ELECTRODE, AND METHOD FOR MANUFACTURING BIO-ELECTRODE
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20180168470A1

  公开（公告）日：2018-06-21

  The present invention provides a bio-electrode composition including a polymer compound having both an ionic repeating unit A and a (meth)acrylate repeating unit B, wherein the ionic repeating unit A is a repeating unit selected from the group consisting of sodium salt, potassium salt, and ammonium salt having either or both partial structures shown by the following general formulae (1-1) and (1-2), and the (meth)acrylate repeating unit B is a repeating unit shown by the following general formula (2). This can form a living body contact layer for a bio-electrode with excellent electric conductivity, biocompatibility, and light weight, which can be manufactured at low cost and does not cause large lowering of the electric conductivity even when it is wetted with water or dried.