cyclododecyl acrylate | 10543-67-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: cyclododecyl acrylate
• 英文别名: Cyclododecylacrylat；cyclododecyl prop-2-enoate
• CAS: 10543-67-6
• 化学式: C₁₅H₂₆O₂
• 分子量: 238.37
• InChiKey: OLYPZOMHOKXSGU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  碘苯 、 cyclododecyl acrylate 在 montmorilloniteethylsilyldiphenylphosphine palladium(II) chloride 三正丁胺 作用下， 反应 8.0h， 以92%的产率得到Cyclododecyl Cinnamate
  参考文献：
  名称：

  A highly active and stereoselective montmorillonite catalyst for arylation of conjugated alkenes

  摘要：

  A highly active and stereoscelective heterogenised homogeneous catalyst montmorillo niteethylsilyldiphenylphosphinepalladium (II) chloride complex (Pd/P is 1:1) for arylation of conjugated alkenes is reported.

  DOI：

  10.1016/s0040-4020(01)88131-x
• 作为产物：
  描述：

  环十二醇 、 丙烯酰氯 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 4.42h， 以73%的产率得到cyclododecyl acrylate
  参考文献：
  名称：

  光诱导ATRP的大环侧链单体：合成和性质与长链线性异构体。

  摘要：

  据报道，传统上具有挑战性的疏水性单体（月桂基C 12，硬脂基C 18和二十二烷基C 22丙烯酸酯）和新型环状异构体（C 12，C 16和C 17）发生光诱导的原子转移自由基聚合。通过明智地选择市场上可买到的溶剂和催化体系，可以高度控制分散性的聚合物（Đ≈1.1）和端基保真度是在很宽的分子量范围内获得的。这种控制水平可提供独特的疏水性材料（无规，嵌段和均聚物）的访问权，这些特性由于烃侧链的异构形式（大环与线性）而具有明显的性能差异。

  DOI：

  10.1021/acs.macromol.8b01509

文献信息

• Novel polymers, compositions comprising them, processes therefor, and use thereof
  申请人：Luukas Timo

  公开号：US20050244364A1

  公开（公告）日：2005-11-03

  The present disclosure relates to novel block polymers comprising at least one monomer with an optical effect, and to cosmetic compositions comprising them, for example nail varnish compositions, foundation compositions, and anti-ageing compositions. The present disclosure also relates to cosmetic treatment processes using the compositions disclosed herein, and to the use of these polymers as tensioning agents.

  本公开涉及包含至少一种具有光学效果的单体的新型嵌段聚合物，以及包含它们的化妆品组合物，例如指甲油组合物、粉底组合物和抗衰老组合物。本公开还涉及使用此处披露的组合物的化妆品处理过程，以及将这些聚合物用作紧致剂的用途。
• Novel polymers, compositions comprising them, processes therefor and use thereof
  申请人：Luukas Timo

  公开号：US20050220732A1

  公开（公告）日：2005-10-06

  Disclosed herein are novel block polymers comprising at least one monomer with an optical effect, and cosmetic compositions comprising the polymers, such as nail varnish compositions, foundation compositions, and anti-ageing compositions. Also disclosed herein are a cosmetic treatment process comprising applying to a keratin material the cosmetic composition as disclosed herein, and the use of these polymers as tensioning agents.

  本文揭示了包含至少一种具有光学效应的单体的新型块聚合物，以及包含这些聚合物的化妆品组合物，如指甲油组合物、粉底组合物和抗衰老组合物。本文还揭示了一种化妆品处理过程，包括将本文所述的化妆品组合物应用于角蛋白材料，并将这些聚合物用作紧肤剂。
• LIGHT ABSORPTIVE COMPOUND, POLYMER COMPOSITION CONTAINING THE COMPOUND, POLYMER FILM, AND CURED LAYER
  申请人：Sumitomo Chemical Company, Limited

  公开号：US20170183304A1

  公开（公告）日：2017-06-29

  The object of the present invention is to provide a light absorptive compound which is capable of selectively absorbing light around a wavelength of 400 nm, and is excellent in solubility in various solvents and/or affinity with hydrophobic substances. Also, the object of the present invention is to provide an optical film containing such a light absorptive compound, and a cured layer. A compound represented by the following formula (I):

  本发明的目的是提供一种能够选择性吸收波长约为400纳米附近光线的光吸收化合物，具有在各种溶剂中良好的溶解性和/或与疏水性物质的亲和性。此外，本发明的目的是提供一种含有这种光吸收化合物的光学膜和固化层。由以下式（I）表示的化合物：
• Novel block polymers, compositions comprising them, and processes for making up and/or treating therewith
  申请人：Luukas Timo

  公开号：US20050220729A1

  公开（公告）日：2005-10-06

  The present disclosure relates to novel block polymers comprising at least one monomer with an optical effect, and to cosmetic compositions comprising them, such as nail varnish compositions, foundation compositions and anti-ageing compositions. The present disclosure also relates to a cosmetic treatment process using the composition disclosed herein.

  本公开涉及包含至少一种具有光学效应的单体的新型嵌段聚合物，以及包括它们的化妆品组合物，如指甲油组合物、粉底组合物和抗衰老组合物。本公开还涉及使用此处披露的组合物的化妆品处理方法。
• Novel block polymers, compositions comprising them, and processes for treating kerating materials therewith
  申请人：Luukas Timo

  公开号：US20050271616A1

  公开（公告）日：2005-12-08

  The present disclosure relates to novel block polymers comprising at least one monomer with an optical effect of formula (I), and to cosmetic compositions comprising them, such as nail varnish compositions, foundation compositions and anti-ageing compositions. The present disclosure also relates to a cosmetic treatment process comprising the application of the composition to keratin materials.

  本公开涉及一种新型块状聚合物，其包含至少一种具有式(I)光学效应的单体，并涉及包含它们的化妆品组合物，例如指甲油组合物、粉底组合物和抗衰老组合物。本公开还涉及一种化妆品处理过程，包括将组合物应用于角蛋白材料。