[庚-2-基(苯基)磷酰基]苯 | 63103-37-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: [庚-2-基(苯基)磷酰基]苯
• 英文名称: (1-Methylhexyl)diphenylphosphinoxid
• 英文别名: (Heptan-2-yl)(oxo)diphenyl-lambda~5~-phosphane；[heptan-2-yl(phenyl)phosphoryl]benzene
• CAS: 63103-37-7
• 化学式: C₁₉H₂₅OP
• 分子量: 300.381
• InChiKey: IIXVKZBXONMBPA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  21
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  [庚-2-基(苯基)磷酰基]苯 在 对甲苯磺酸 作用下， 以 苯 为溶剂， 生成 (E)-2-Diphenylphosphinoyl-3-methyloct-3-en
  参考文献：
  名称：

  Davidson,A.H. et al., Journal of the Chemical Society. Perkin transactions I, 1977, p. 550 - 565

  摘要：

  DOI：
• 作为产物：
  描述：

  heptan-2-yldiphenylphosphane 在 双氧水 作用下， 生成 [庚-2-基(苯基)磷酰基]苯
  参考文献：
  名称：

  Cerium-Hydride Secondary Building Units in a Porous Metal–Organic Framework for Catalytic Hydroboration and Hydrophosphination

  摘要：

  We report the stepwise, quantitative transformation of Ce-6(IV)(mu(3)-O)(4)(mu(3)-OH)(4)(OH)(6)(OH2)(6) nodes in a new Ce-BTC (BTC = trimesic acid) metal-organic framework (MOF) into the first Ce-6(III)(mu(3)-O)(4)(mu(3)-OLi)(4)(H)(6)(THF)(6)Li-6 metal-hydride nodes that effectively catalyze hydroboration and hydrophosphination reactions. CeH-BTC displays low steric hindrance and electron density compared to homogeneous organolanthanide catalysts, which likely accounts for the unique 1,4-regioselectivity for the hydroboration of pyridine derivatives. MOF nodes can thus be directly transformed into novel single-site solid catalysts without homogeneous counterparts for sustainable chemical synthesis.

  DOI：

  10.1021/jacs.6b10055

文献信息

• Addition of diphenylphosphine oxide to arenesulfonylhydrazones: novel adducts from tosylhydrazones and a new synthesis of alkyldiphenylphosphine oxides from trisylhydrazones
  作者：Steven H. Bertz、Gary Dabbagh

  DOI：10.1021/ja00409a063

  日期：1981.9
• BERTZ S. H.; DABBAGH G., J. AMER. CHEM. SOC., 1981, 103, NO 19, 5932-5934
  作者：BERTZ S. H.、 DABBAGH G.

  DOI：——

  日期：——
• Davidson,A.H. et al., Journal of the Chemical Society. Perkin transactions I, 1977, p. 550 - 565
  作者：Davidson,A.H. et al.

  DOI：——

  日期：——
• Cerium-Hydride Secondary Building Units in a Porous Metal–Organic Framework for Catalytic Hydroboration and Hydrophosphination
  作者：Pengfei Ji、Takahiro Sawano、Zekai Lin、Ania Urban、Dean Boures、Wenbin Lin

  DOI：10.1021/jacs.6b10055

  日期：2016.11.16

  We report the stepwise, quantitative transformation of Ce-6(IV)(mu(3)-O)(4)(mu(3)-OH)(4)(OH)(6)(OH2)(6) nodes in a new Ce-BTC (BTC = trimesic acid) metal-organic framework (MOF) into the first Ce-6(III)(mu(3)-O)(4)(mu(3)-OLi)(4)(H)(6)(THF)(6)Li-6 metal-hydride nodes that effectively catalyze hydroboration and hydrophosphination reactions. CeH-BTC displays low steric hindrance and electron density compared to homogeneous organolanthanide catalysts, which likely accounts for the unique 1,4-regioselectivity for the hydroboration of pyridine derivatives. MOF nodes can thus be directly transformed into novel single-site solid catalysts without homogeneous counterparts for sustainable chemical synthesis.