2-Amino-4-octadecyl-phenol | 117597-70-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-Amino-4-octadecyl-phenol
• 英文别名: 2-Amino-4-octadecylphenol
• CAS: 117597-70-3
• 化学式: C₂₄H₄₃NO
• 分子量: 361.612
• InChiKey: OCDFZRIOTQBMDV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.3
• 重原子数：
  26
• 可旋转键数：
  17
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  46.2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-Amino-4-octadecyl-phenol 、 甘油 在 硫酸 作用下， 生成 5-octadecyl-quinolin-8-ol
  参考文献：
  名称：

  杀菌活性和化学成分。第四部分 5 - n-烷基-8-羟基喹啉的合成

  摘要：

  DOI：

  10.1039/jr9550004391
• 作为产物：
  描述：

  4-十八烷基苯酚 在 四氢呋喃 、 硝酸 、 镍 、 溶剂黄146 作用下， 生成 2-Amino-4-octadecyl-phenol
  参考文献：
  名称：

  杀菌活性和化学成分。第四部分 5 - n-烷基-8-羟基喹啉的合成

  摘要：

  DOI：

  10.1039/jr9550004391

文献信息

• 2,6-Di-tertiary butyl phenyl pentaerythritol spiro bis-phosphites enhancing the stability to heat and light of synthetic resins, stabilizer compositions comprising phenolic antioxidants and such phosphites, and synthetic resin compositions containing the same
  申请人：ADEKA ARGUS CHEMICAL CO., Ltd.

  公开号：EP0038876A1

  公开（公告）日：1981-11-04

  2,6-Di-tertiary butyl phenyl pentaerythritol spiro bis-phosphites are provided having the structure: wherein: R is alkyl having from one to six carbon atoms; R is methyl or ethyl; R2 is selected from the group consisting of alkyl having from one up to about eighteen carbon atoms; cycloalkyl having from three up to about twelve carbon atoms; and alkaryl and aryl having from six to about thirty carbon atoms; such groups substituted with from one to about four oxy ether-0- and/or carboxylic ester-COO-groups; the residue of a polyhydric alcohol having from two to about eighteen carbon atoms, and from two to about ten hydroxyl groups; and the residue of a polyphenol having from six to about eighteen carbon atoms and from two to about ten phenolic hydroxyl groups. Stabilizer compositions are provided comprising a phenolic antioxidant and such phosphites as well as synthetic resin compositions having an enhanced resistance to deterioration by heat and/or light due to the presence of such a phosphite and/or stabilizer composition.

  2,6-二叔丁基苯基季戊四醇螺双磷酸盐具有以下结构： 其中 R 是具有 1 至 6 个碳原子的烷基； R 是甲基或乙基 R2 选自具有 1 至约 18 个碳原子的烷基；具有 3 至约 12 个碳原子的环烷基；具有 6 至约 30 个碳原子的烷芳基和芳基；这些基团被 1 至约 4 个氧醚-0-和/或羧酸酯-COO-基团取代；具有 2 至约 18 个碳原子和 2 至约 10 个羟基的多元醇的残余物；以及具有 6 至约 18 个碳原子和 2 至约 10 个酚类羟基的多元酚的残余物。 稳定剂组合物包括酚类抗氧化剂和此类亚磷酸酯以及合成树脂组合物，由于此类亚磷酸酯和/或稳定剂组合物的存在，合成树脂组合物的耐热和/或耐光性得到增强。
• Copolymer light stabilizers having at least one 2,2,6,6-tetraalkyl piperidyl group and synthetic resin compositions containing the same
  申请人：ADEKA ARGUS CHEMICAL CO., Ltd.

  公开号：EP0069871A2

  公开（公告）日：1983-01-19

  Copolymer light stabilizers are provided having at least one 2,2,6,6-tetraalkyl piperidyl group in the molecule and a molecular weight within the range from about 1000 to about 20,000, that are copolymers of a maleic or fumaric acid ester containing a 2,2,6,6-tetraalkyl piperidyl group in the alcohol group of the formula: wherein R2 is alkyl or R1; Re is lower alkyl or hydroxyalkyl; R3 is hydrogen alkaryl or alkyl, hydroxyalkyl or eopx- yalkyl; R4 is hydrogen or methyl; R5 is alkylene; Y is >CH2, >C=0, >CH-OH or R7 is alkylene; and at least one monomer selected from the group consisting of aliphatic carboxylic acid vinyl ester having from two to eight carbon atoms; alkyl vinyl ethers having from one to eighteen carbon atoms; triallyl isocyanurate; pinene; and tricyclo- (5.2.1.02.6)-decene-3; and synthetic resin compositions having improved light stability comprising per 100 parts by weight of resin from 0.001 to 5 parts by weight of the polymeric light stabilizer.

  共聚光稳定剂分子中至少有一个 2，2，6，6-四烷基哌啶基，分子量在约 1000 至约 20000 之间，是马来酸酯或富马酸酯的共聚物，其醇基中含有 2，2，6，6-四烷基哌啶基： 其中 R2 是烷基或 R1； Re是低级烷基或羟基烷基 R3 是氢烷基芳基或烷基、羟基烷基或异丙基烷基； R4 是氢或甲基 R5 是亚烷基； Y 是 >CH2、>C=0、>CH-OH 或 R7 是亚烷基； 和至少一种选自以下组别的单体：具有 2 至 8 个碳原子的脂肪族羧酸乙烯酯；具有 1 至 18 个碳原子的烷基乙烯基醚；异氰尿酸三烯丙基酯；蒎烯；和三环-(5.2.1.02.6)-癸烯-3；以及具有更高光稳定性的合成树脂组合物，其中每 100 份树脂重量包含 0.001 至 5 份聚合物光稳定剂。
• Polymeric light stabilizers having at least one 2,2,6,6-tetraalkyl piperidyl group and synthetic resin compositions containing the same
  申请人：ADEKA ARGUS CHEMICAL CO., Ltd.

  公开号：EP0065655A1

  公开（公告）日：1982-12-01

  Polymeric light stabilizers are provided having at least one 2,2,6,6-tetraalkyl piperidyl group in the molecule and a molecular weight within the range from about 1000 to about 20,000, that are polymers of an unsaturated carboxylic acid ester selected from the group consisting of unsaturated cycloaliphatic mono-, di-, and tri-carboxylic acid esters having from seven to about thirty carbon atoms; unsaturated branched-chain aliphatic di- and tri-carboxylic acid esters having from four to about thirty carbon atoms; sorbic acid ester, 3,8-nonadienyl acid ester, oleic acid ester, linolenic acid ester and ricinoleic acid ester; or copolymers of at least one thereof with another copolymerizable unsaturated monomer; and synthetic resin compositions having improved light stability comprising per 100 parts by weight of resin from 0.001 to 10 parts by weight of the polymeric light stabilizer.

  聚合物光稳定剂分子中至少有一个 2,2,6,6-四烷基哌啶基团，分子量在约 1000 至约 20,000 范围内，是不饱和羧酸酯的聚合物，该不饱和羧酸酯选自具有 7 至约 30 个碳原子的不饱和环脂族一元、二元和三元羧酸酯；具有 4 至约 30 个碳原子的不饱和支链脂肪族二元和三元羧酸酯；山梨酸酯；3,8-壬二烯酸酯；具有四个至三十个碳原子的不饱和支链脂肪族二羧酸酯和三羧酸酯；山梨酸酯、3,8-壬二烯酸酯、油酸酯、亚麻酸酯和蓖麻油酸酯；或其中至少一种与另一种可共聚的不饱和单体的共聚物；以及具有更好光稳定性的合成树脂组合物，每 100 份树脂（重量）中包含 0.001 至 10 份(重量)的聚合光稳定剂。
• Bis-phenol phosphates as clarifiers for polyolefin resins
  申请人：ADEKA ARGUS CHEMICAL CO., Ltd.

  公开号：EP0068326A2

  公开（公告）日：1983-01-05

  Bis-phenol phosphates, phosphonates and phosphinates are provided, represented by the formula:wherein: R is selected from the group consisting of a carbon-to-carbon bond; thio sulfur-S-; and alkylidene in which R3 and R. are selected from the group consisting of hydrogen, alkyl having from one to about eighteen carbon atoms, and cycloalkyl, including cycloalkylidene in which R3 and R. are taken together as part of a cycloalkylene ring, having from three to about twelve carbon atoms; R, and R2 are each selected from the group consisting of hydrogen, alkyl having from one to about eighteen carbon atoms; and cycloalkyl having from three to about twelve carbon atoms; M is a metal atom which can be monovalent or polyvalent; and n is the valence of the metal atom M, ranging from one to about four; useful to improve clarity of polyolefin resin compositions in an amount within the range from 0.005 to 5 parts by weight per 100 parts of resin.

  提供的双酚膦酸盐、膦酸盐和膦酸盐由式表示： 其中 R 选自碳-碳键、硫代硫-S-和亚烷基组成的组 其中 R3 和 R.选自由氢、具有 1 至约 18 个碳原子的烷基和环烷基组成的组，其中环烷基包括 R3 和 R.作为具有 3 至约 12 个碳原子的环亚烷基环的一部分； R 和 R2 各自选自由氢、具有 1 至约 18 个碳原子的烷基、具有 1 至约 18 个碳原子的环烷基和具有 1 至约 18 个碳原子的环烷基组成的组； 和具有 3 至 12 个碳原子的环烷基； M 是金属原子，可以是一价或多价金属原子；n 是金属原子 M 的价数，从 1 到 4 不等；用于提高聚烯烃树脂组合物的透明度，用量范围为每 100 份树脂 0.005 到 5 份（按重量计）。
• Synthetic resin compositions containing 2,2,6,6-tetramethyl piperidyl ethers
  申请人：ADEKA ARGUS CHEMICAL CO., Ltd.

  公开号：EP0073386A1

  公开（公告）日：1983-03-09

  Synthetic resin compositions of improved resistance to deterioration by heat and light are provided containing a 2,2,6,6-tetramethyl piperidyl ether having the formula: wherein: R, is selected from the group consisting of X is selected from the group consisting of methylene -CH2, carbonyl C=O, > CH-O-R, and Y is oxy - where Z is alkylene or thioalkylene having from two to about ten carbon atoms; or phenylene having from six to about ten carbon atoms; and n is a number from 1 to 50; R2 and R3; or R2 and R4 can be taken together to form and when n is 1 and Y is -O-, R2 and R3 or R2 and R4 can be connected together as a C-C linkage to form a cyclic ring, or The other symbols have the meanings given in the description.

  本发明提供的合成树脂组合物具有更好的耐热和耐光变质性能，其中含有一种 2,2,6,6-四甲基哌啶基醚，其化学式为 其中R，选自由下列物质组成的组 X 选自亚甲基-CH2、羰基 C=O、>CH-O-R 所组成的组，以及 Y 是氧 其中 Z 是具有 2 至约 10 个碳原子的亚烷基或硫代亚烷基；或具有 6 至约 10 个碳原子的亚苯基；且 n 是 1 至 50 的数字；R2 和 R3；或 R2 和 R4 可共同组成 当 n 为 1 且 Y 为-O-时，R2 和 R3 或 R2 和 R4 可作为 C-C 连接连接在一起，形成一个环，或 其他符号的含义见说明。