反式-1-苯基巯基丁烯-(1) | 21106-26-3

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 中文名称: 反式-1-苯基巯基丁烯-(1)
• 英文名称: trans-1-Phenylmercaptobuten-(1)
• 英文别名: (E) 1-Phenylthio-1-butene；[(E)-but-1-enyl]sulfanylbenzene
• CAS: 21106-26-3
• 化学式: C₁₀H₁₂S
• 分子量: 164.271
• InChiKey: PXAUEKOLGHSMRX-YCRREMRBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  反式-1-苯基巯基丁烯-(1) 在 potassium tert-butylate 作用下， 以 二甲基亚砜 为溶剂， 生成 (E)-but-2-en-1-yl phenyl sulfide
  参考文献：
  名称：

  Kimmelma, Reijo, Acta chemica Scandinavica. Series B: Organic chemistry and biochemistry, 1988, vol. 42, # 8, p. 550 - 555

  摘要：

  DOI：
• 作为产物：
  描述：

  (E)-but-2-en-1-yl phenyl sulfide 在 potassium tert-butylate 作用下， 以 二甲基亚砜 为溶剂， 生成 反式-1-苯基巯基丁烯-(1)
  参考文献：
  名称：

  Kimmelma, Reijo, Acta chemica Scandinavica. Series B: Organic chemistry and biochemistry, 1988, vol. 42, # 8, p. 550 - 555

  摘要：

  DOI：

文献信息

• Decarbonylation of thiol esters to give sulfides promoted by transition metal complexes
  作者：Kohtaro Osakada、Takakazu Yamamoto、Akio Yamamoto

  DOI：10.1016/s0040-4039(01)91363-2

  日期：1987.1

  Thiol esters are converted into sulfides through decarbonylation promoted by catalytic amounts of Pd(0) compounds or stoichiometric amounts of Rh(I) compounds.

  硫醇酯通过催化量的Pd（0）化合物或化学计量的Rh（I）化合物促进的脱羰作用转化为硫化物。
• METHOD FOR PRODUCING OLEFIN
  申请人：ASAHI GLASS COMPANY,LIMITED

  公开号：US20170291862A1

  公开（公告）日：2017-10-12

  A method for producing at least one olefin compound selected from the group consisting of a compound of formula (51), a compound of formula (52), a compound of formula (53), and a compound of formula (54), the method including reacting an olefin compound of formula (21) with a olefin compound of formula (31) in the presence of at least one metal catalyst selected from the group consisting of a compound of formula (11), a compound of formula (12), a compound of formula (13), a compound of formula (14), and a compound of formula (15).

  一种生产至少一种从化合物组中选择的烯烃化合物的方法，所述化合物组包括式(51)、式(52)、式(53)和式(54)的化合物，该方法包括在至少一种金属催化剂的存在下，将式(21)的烯烃化合物与式(31)的烯烃化合物反应，所述至少一种金属催化剂选择自式(11)、式(12)、式(13)、式(14)和式(15)的化合物组。
• METHOD FOR PRODUCING OLEFIN CONTAINING CHLORINE AND FLUORINE
  申请人：ASAHI GLASS COMPANY, LIMITED

  公开号：US20170291863A1

  公开（公告）日：2017-10-12

  A method for producing at least one olefin compound selected from the group consisting of a compound of formula (51) and a compound of formula (52), the method including reacting an olefin compound of formula (21) with a olefin compound of formula (31) in the presence of at least one metal catalyst selected from the group consisting of a compound of formula (11), a compound of formula (12), a compound of formula (13), a compound of formula (14), and a compound of formula (15).

  一种用于生产至少一种烯烃化合物的方法，所述烯烃化合物选自公式（51）和公式（52）所示的化合物组，所述方法包括在至少选择自公式（11）、公式（12）、公式（13）、公式（14）和公式（15）所示的化合物组中选择至少一种金属催化剂的存在下，将公式（21）所示的烯烃化合物与公式（31）所示的烯烃化合物反应。
• Method for producing olefin containing chlorine and fluorine
  申请人：AGC Inc.

  公开号：US10358400B2

  公开（公告）日：2019-07-23

  A method for producing at least one olefin compound selected from the group consisting of a compound of formula (51) and a compound of formula (52), the method including reacting an olefin compound of formula (21) with a olefin compound of formula (31) in the presence of at least one metal catalyst selected from the group consisting of a compound of formula (11), a compound of formula (12), a compound of formula (13), a compound of formula (14), and a compound of formula (15).

  一种生产至少一种选自式（51）化合物和式（52）化合物的烯烃化合物的方法，该方法包括在至少一种选自式（11）化合物、式（12）化合物、式（13）化合物、式（14）化合物和式（15）化合物的金属催化剂存在下，使式（21）烯烃化合物与式（31）烯烃化合物反应。
• Method for producing olefin
  申请人：AGC Inc.

  公开号：US10407365B2

  公开（公告）日：2019-09-10

  A method for producing at least one olefin compound selected from the group consisting of a compound of formula (51), a compound of formula (52), a compound of formula (53), and a compound of formula (54), the method including reacting an olefin compound of formula (21) with a olefin compound of formula (31) in the presence of at least one metal catalyst selected from the group consisting of a compound of formula (11), a compound of formula (12), a compound of formula (13), a compound of formula (14), and a compound of formula (15).

  一种生产至少一种选自由式(51)化合物、式(52)化合物、式(53)化合物和式(54)化合物组成的组的烯烃化合物的方法、该方法包括在至少一种选自由式（11）化合物、式（12）化合物、式（13）化合物、式（14）化合物和式（15）化合物组成的组的金属催化剂存在下，使式（21）烯烃化合物与式（31）烯烃化合物反应。