N-{[2-(2,6-Diethylanilino)phenyl]methylene}-N-(2,6-diethylphenyl)amine

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-{[2-(2,6-Diethylanilino)phenyl]methylene}-N-(2,6-diethylphenyl)amine
• 英文别名: N-[2-[(2,6-diethylphenyl)iminomethyl]phenyl]-2,6-diethylaniline
• 化学式: C₂₇H₃₂N₂
• 分子量: 384.564
• InChiKey: KEPBTFHPYYRUBH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  29
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  24.4
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-{[2-(2,6-Diethylanilino)phenyl]methylene}-N-(2,6-diethylphenyl)amine 、 copper dichloride 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 1.0h， 以74.6%的产率得到
  参考文献：
  名称：

  Cu(II) complexes with anilido-imine ligands: Synthesis, characterization and catalysis on reverse atom transfer radical polymerization of styrene

  摘要：

  Several copper(II) complexes bearing bidentate anilido-imine ligands [(Ar ' N=CHC6H4-NAr)Cu](2)(mu-Cl)(2) (Ar = Ar ' = 2,6-Me2C6H3 (1a); Ar = Ar ' = 2,6-Et2C6H3 (1b); Ar = 3,5-(CF3)(2)C6H3, Ar ' = 2,6-(Pr2C6H3)-Pr-1 (1d); Ar = p-OMeC6H4, Ar ' = 2,6-(Pr2C6H3)-Pr-i (le)), (Ar ' N=CHC6H4-NAr)CuCI (Ar = Ar ' = 2,6-(Pr2C6H3)-Pr-i (1c)), and that bearing tridentate quinolinyl anilido-imine ligand (2,6-(i)pr(2)C(6)H(3)N=CHC6H4-NAr)CuCI (Ar = 8-quinolinyl (1f)) were synthesized via reactions of the corresponding ligands with (BuLi)-Bu-n and subsequent in-situ addition of CuCl2. The X-ray diffraction analysis revealed that la and ld are dinuclear, while 1f with N,N,N-tridentate ligand is in monomeric form. In the presence of 2,2 '-azobisisobutyronitrile (AIBN), these well-defined complexes showed moderate to high activities in reverse ATRP of styrene. High conversions up to 86.5% were obtained and polymers with controllable molecular weight and relatively narrow polydispersity were produced. (C) 2017 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2017.01.018
• 作为产物：
  描述：

  o-C6H4F(CH=NC6H3Et2-2,6) 、 邻苯二胺 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 16.0h， 生成 N-{[2-(2,6-Diethylanilino)phenyl]methylene}-N-(2,6-diethylphenyl)amine 、 5H-dibenzo[b,e][1,4]diazepine
  参考文献：
  名称：

  Synthesis of Ti, Zr, and Hf complexes with a new tetra-azane ligand by one-pot HCl-elimination and their properties as catalysts for production of UHMWPE

  摘要：

  HCl-消除反应的第一个例子是将含有氨基配体附着到锆和铪上。

  DOI：

  10.1039/c5nj02151k

文献信息

• 胺亚胺镁配合物及其制备方法和应用
  申请人：济南大学

  公开号：CN109438486B

  公开（公告）日：2021-02-19

  本发明公开了一种胺亚胺镁配合物及其制备方法和应用，其具有式Ⅰ所述的结构式，其中，R为氢、甲基、乙基或异丙基。本发明胺亚胺镁配合物催化剂由二正丁基镁、苄醇和配体A一锅法反应而得，制备方法简单，成本低，反应后处理简单，产品收率高。该化合物结构变化多样，金属中心镁与配体的N，N原子配位，可作为环内酯开环聚合反应的催化剂，其催化活性高、立体选择性好、不需要助催化剂、反应速率快，聚合反应操作简单，得到的聚合产物分子量分布窄、分子量可控、产率高，可以广泛用于环内酯开环聚合，是一种十分理想的催化剂。
• Iron(II) complexes bearing anilido-imine ligands: Synthesis and catalysis on ATRP of methyl methacrylate
  作者：Zhiqiang Hao、Yuxi Han、Wei Gao、Lan Xin、Ying Mu

  DOI：10.1016/j.poly.2014.08.003

  日期：2014.11

  Reactions of the ortho-C6H4(NHAr)-(CH=NAr) with (BuLi)-Bu-n and subsequent addition of FeCl2 afford the anilido-aldimine Fe(II) complexes [(ArN=CHC6H4-NAr)Fe](2)(mu-Cl)(2) (Ar = 2,6-Me2C6H3 (1a); Ar = 2,6-Et2C6H3 (1b)), and (ArN=CHC6H4-NAr)Fe(mu-Cl)(2)Li(THF)(2) (Ar = 2,6-(Pr2C6H3)-Pr-i (1c)). Similarly, reactions of the 2-(ArNC(H))C6H4-HNC6H6N with nBuLi and FeCl2 give the N,N,N-tridentate iron complexes [2-(ArNC(H))C6H4-NC6H6N]Fe}(2)(mu-Cl)(2) (Ar = 2,6-Me2C6H3 (2a), 2,6-Et2C6H3 (2b), and 2,6-(Pr2C6H3)-Pr-i (2c)). The X-ray diffraction analysis reveals that 1a and 1b are dimeric complexes and 1c is hetero-binuclear complex. Fe(II) atoms in these complexes are all in a distorted tetrahedral geometry. Complex 2c was confirmed to be a dimeric complex with the iron atom in a trigonal bipyramidal geometry. Complexes 1a-1c show moderate activities in ATRP of MMA in the presence of benzyl chloride (BnCI). While complexes 2a-2c are inert under the same condition. (C) 2014 Elsevier Ltd. All rights reserved.
• Synthesis of Ti, Zr, and Hf complexes with a new tetra-azane ligand by one-pot HCl-elimination and their properties as catalysts for production of UHMWPE
  作者：Xiangdong Ji、Wei Yao、Xuyang Luo、Wei Gao、Ying Mu

  DOI：10.1039/c5nj02151k

  日期：——

  The first example for the HCl-elimination reaction being applied in the attachment of an amido-containing ligand to Zr and Hf.

  HCl-消除反应的第一个例子是将含有氨基配体附着到锆和铪上。
• Cu(II) complexes with anilido-imine ligands: Synthesis, characterization and catalysis on reverse atom transfer radical polymerization of styrene
  作者：Zhiqiang Hao、Anjie Ma、Bin Xu、Wei Gao、Ying Mu

  DOI：10.1016/j.poly.2017.01.018

  日期：2017.4

  Several copper(II) complexes bearing bidentate anilido-imine ligands [(Ar ' N=CHC6H4-NAr)Cu](2)(mu-Cl)(2) (Ar = Ar ' = 2,6-Me2C6H3 (1a); Ar = Ar ' = 2,6-Et2C6H3 (1b); Ar = 3,5-(CF3)(2)C6H3, Ar ' = 2,6-(Pr2C6H3)-Pr-1 (1d); Ar = p-OMeC6H4, Ar ' = 2,6-(Pr2C6H3)-Pr-i (le)), (Ar ' N=CHC6H4-NAr)CuCI (Ar = Ar ' = 2,6-(Pr2C6H3)-Pr-i (1c)), and that bearing tridentate quinolinyl anilido-imine ligand (2,6-(i)pr(2)C(6)H(3)N=CHC6H4-NAr)CuCI (Ar = 8-quinolinyl (1f)) were synthesized via reactions of the corresponding ligands with (BuLi)-Bu-n and subsequent in-situ addition of CuCl2. The X-ray diffraction analysis revealed that la and ld are dinuclear, while 1f with N,N,N-tridentate ligand is in monomeric form. In the presence of 2,2 '-azobisisobutyronitrile (AIBN), these well-defined complexes showed moderate to high activities in reverse ATRP of styrene. High conversions up to 86.5% were obtained and polymers with controllable molecular weight and relatively narrow polydispersity were produced. (C) 2017 Elsevier Ltd. All rights reserved.