2-氯-5-正癸基嘧啶 | 170434-06-7

• 物质功能分类: 医药中间体 - 杂环化合物 - 嘧啶类化合物
• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 中文名称: 2-氯-5-正癸基嘧啶
• 中文别名: 2-氯-5-N-癸基嘧啶
• 英文名称: 2-chloro-5-decylpyrimidine
• 英文别名: 2-chloro-5-n-decylpyrimidine
• CAS: 170434-06-7
• 化学式: C₁₄H₂₃ClN₂
• 分子量: 254.803
• InChiKey: LJRSECCCAXFYFU-UHFFFAOYSA-N

物化性质

• 沸点：
  368.8±11.0 °C(Predicted)
• 密度：
  1.008±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  17
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 安全说明：
  S26
• 危险类别码：
  R36/37/38
• 海关编码：
  2933599090

反应信息

• 作为反应物：
  描述：

  2-氯-5-正癸基嘧啶 、 3-联苯硼酸 在 四(三苯基膦)钯 potassium carbonate 作用下， 以 乙二醇二甲醚 、 水 为溶剂， 反应 14.0h， 生成 5-Decyl-2-(3-phenylphenyl)pyrimidine
  参考文献：
  名称：

  IRIDIUM COMPLEX AND LIGHT EMITTING MATERIAL FORMED FROM SAME

  摘要：

  公开号：

  EP2471800B1

文献信息

• Optically active compound, liquid crystal composition containing the
  申请人：Canon Kabushiki Kaisha

  公开号：US05849217A1

  公开（公告）日：1998-12-15

  An optically active compound represented by the formula R.sub.1 --A.sub.1 --A.sub.2 --X.sub.1 --A.sub.3 --(CH.sub.2).sub.p --L--A.sub.4 --R.sub.2, in which R.sub.1 is F, CN or straight chain, branched or cyclic alkyl and R.sub.2 is H, F, CH or straight chain or branched alkyl; A.sub.3 is 1,4-phenylene, pyridine-2,5-diyl, pyrimidine-2,5-diyl, pyrazine-2,5-diyl, pyridazine-3,6-diyl, 1,4-cyclohexylene, 1,3-dioxane-2,5-diyl, 1,3-ditiane-2,5-diyl, thiophene-2,5-diyl, thiazole-2,5-diyl, thiaziazole-2,5-diyl, benzoxazole-2,5-diyl, benzoxazole-2,6-diyl, benzothiazole-2,5-diyl, benzothiazole-2,6-diyl, benzofuran-2,5-diyl, benzofuran-2,6-diyl, quinoxaline-2,6-diyl, quinoline-2,6-diyl, 2,6-naphthylene, indane-2,5-diyl, 2-alkylindane-2,5-diyl, indanone-2,6-diyl, 2-alkylindane-2,6-diyl, coumarane-2,5-diyl and 2-alkylcoumarane-2,5-diyl; A.sub.1, A.sub.2 and A.sub.4 are single bond or A.sub.3 ; X.sub.1 ' is a single bond, --COO--, --OCO--, --CH.sub.2 O--, --OCH.sub.2 --, --CH.sub.2 CH.sub.2 --, --CH.dbd.CH-- or --C.tbd.C--; p is an integer from 2 to 20; and L is optically active.

  化学式R.sub.1 --A.sub.1 --A.sub.2 --X.sub.1 --A.sub.3 --(CH.sub.2).sub.p --L--A.sub.4 --R.sub.2代表的一种光学活性化合物，其中R.sub.1为F、CN或直链、支链或环烷基，R.sub.2为H、F、CH或直链或支链烷基；A.sub.3为1,4-苯撑基、吡啶-2,5-二基、嘧啶-2,5-二基、吡嗪-2,5-二基、吡啶嗪-3,6-二基、1,4-环己撑基、1,3-二氧杂环戊烷-2,5-二基、1,3-二硫杂环戊烷-2,5-二基、噻吩-2,5-二基、噻唑-2,5-二基、噻二唑-2,5-二基、苯并噁唑-2,5-二基、苯并噁唑-2,6-二基、苯并噻唑-2,5-二基、苯并噻唑-2,6-二基、苯并呋喃-2,5-二基、苯并呋喃-2,6-二基、喹啉-2,6-二基、喹啉-2,6-二基、2,6-萘撑基、茚-2,5-二基、2-烷基茚-2,5-二基、茚酮-2,6-二基、2-烷基茚-2,6-二基、香豆素-2,5-二基和2-烷基香豆素-2,5-二基；A.sub.1、A.sub.2和A.sub.4为单键或A.sub.3；X.sub.1 '为单键、--COO--、--OCO--、--CH.sub.2 O--、--OCH.sub.2--、--CH.sub.2 CH.sub.2--、--CH.dbd.CH--或--C.tbd.C--；p为2到20的整数；L为光学活性。
• Mesomorphic compound, liquid crystal composition, liquid crystal device,
  申请人：Canon Kabushiki Kaisha

  公开号：US05733476A1

  公开（公告）日：1998-03-31

  A mesomorphic compound of the formula (I) having a coumaran skeleton is suitable as a component for a liquid crystal composition providing improved response characteristics. A liquid crystal device is constituted by disposing the liquid crystal composition between a pair of electrode plates. The liquid crystal device is used as a display panel constituting a display apparatus providing good display characteristics.

  具有香豆素骨架的介向化合物(I)适用于液晶组分，提供改善的响应特性。液晶器件通过在一对电极板之间放置液晶组分来构成。液晶器件用作显示面板，构成具有良好显示特性的显示设备。
• Mesomorphic compounds, liquid crystal composition, liquid crystal device, display apparatus and display method
  申请人：CANON KABUSHIKI KAISHA

  公开号：EP0611815A1

  公开（公告）日：1994-08-24

  A mesomorphic compound of the formula (I) according to Claim 1 characterized by having a coumaran skeleton is suitable as a component for a liquid crystal composition providing improved response characteristics. A liquid crystal device is constituted by disposing the liquid crystal composition between a pair of electrode plates. The liquid crystal device is used as a display panel constituting a display apparatus providing good display characteristics.

  根据权利要求1所述的式(I)的介形化合物，其特征在于具有香豆素骨架，适合作为液晶组合物的组分，提供更好的响应特性。将液晶组合物置于一对电极板之间可构成液晶装置。该液晶装置用作构成显示装置的显示面板，具有良好的显示特性。
• METAL COMPLEX COMPOSITION AND COMPLEX POLYMER
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2471889A1

  公开（公告）日：2012-07-04

  A metal complex composition comprising a metal complex including a structure represented by the following formula (1) and a charge transport material, wherein in the formula (1), Ra represents an alkyl group having 2 to 30 carbon atoms, and R1, R2, R3 and R4 each independently represent a hydrogen atom, an alkyl group having 1 to 30 carbon atoms that may have a substituent, or the like, provided that adjacent groups among R1, R2, R3 and R4 may be bonded to each other to form a ring structure.

  一种金属络合物组合物，由包括下式（1）所代表结构的金属络合物和电荷传输材料组成、 式（1）中，Ra 代表具有 2 至 30 个碳原子的烷基，R1、R2、R3 和 R4 各自独立地代表氢原子、具有 1 至 30 个碳原子且可能具有取代基的烷基或类似基团，条件是 R1、R2、R3 和 R4 中的相邻基团可以相互键合以形成环状结构。
• COMPOSITION CONTAINING POLYMER COMPOUND AND LIGHT-EMITTING ELEMENT USING SAME
  申请人：Sumitomo Chemical Company Limited

  公开号：EP2594607A1

  公开（公告）日：2013-05-22

  It is an object of the present invention to provide a composition using a polymer compound, which is useful for manufacturing a blue phosphorescent light-emitting device excellent in luminous efficiency. The present invention provides a composition including: a polymer compound substantially consisting of a constitutional unit selected from a constitutional unit represented by Formula (1)-1 below, a constitutional unit represented by Formula (1)-2 below, a constitutional unit represented by Formula (2)-1 below, a constitutional unit represented by Formula (2)-2 below, and a constitutional unit derived from a phosphorescent light-emitting compound having a light-emitting spectrum peak at smaller than 480 nm and the polymer compound containing at least both of the constitutional unit represented by Formula (1)-1 and the constitutional unit represented by Formula (1)-2; and a phosphorescent light-emitting compound having a light-emitting spectrum peak at smaller than 480 nm.

  本发明的目的是提供一种使用聚合物化合物的组合物，该组合物可用于制造发光效率极佳的蓝色磷光发光器件。本发明提供了一种组合物，包括一种聚合物化合物，该聚合物化合物实质上由一个构型单元组成，该构型单元选自如下式（1）-1 所代表的构型单元、如下式（1）-2 所代表的构型单元、如下式（2）-1 所代表的构型单元、如下式（2）-2 所代表的构型单元，以及一个源自磷光发光化合物的构型单元，该磷光发光化合物的发光光谱峰值小于 480 纳米，且该聚合物化合物至少同时含有如下式（1）-1 所代表的构型单元和如下式（1）-2 所代表的构型单元；以及发光光谱峰值小于 480 纳米的磷光发光化合物。