meso-tetra(4-pyridyl)porphynatomanganese(III) acetate | 64000-04-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: meso-tetra(4-pyridyl)porphynatomanganese(III) acetate
• 英文别名: (acetato)[5,10,15,20-tetra(pyridin-4-yl)porphinato]-manganese(III)；meso-tetra(4-pyridyl)porphyrinatemanganese(III) acetate；(TPiP)MnOAc；[Mn((III))TPyP]OAc
• CAS: 64000-04-0；1008516-50-4
• 化学式: C₂H₃O₂*C₄₀H₂₄MnN₈
• 分子量: 730.667
• InChiKey: KGYUIVMAPQYUJD-NGRCPIEASA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ru₃(μ₃-O)(-CH₃COO)₆(pyridine)₂(CH₃OH)](PF₆) 、 meso-tetra(4-pyridyl)porphynatomanganese(III) acetate 以 further solvent(s) 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  (5,10,15,20-Tetra(4-pyridil)porphinato)manganese(III) acetate modified by four μ3-oxo-triruthenium acetate clusters: synthesis, characterization, electrochemical behavior and catalytic activity

  摘要：

  A novel supermolecule constituted by four mu(3)-oxo-triruthenium acetate clusters coordinated to manganese(III)-meso -tetra(4-pyridil)porphyrin acetate ([MnTPyP]CH3COO) has been synthesized. Characterization has been performed by UV-Vis and H-1 NMR spectroscopy. The electrochemical behavior (cyclic voltammetry and spectroelectrochemistry) in N,N'-dimethylformamide has been analyzed in terms of five redox processes: three related to peripheral clusters (Ru-IV,Ru-III,Ru-III/Ru-III,Ru-III,Ru-III/Ru-III,Ru-II,Ru-II) and two centered on the Mn-porphyrin core ((MnP)-P-III/(MnP)-P-II/(MnP2-)-P-II). A direct comparison has been performed between MnTCP and MnTPyP as catalysts for the cyclooctene and cyclohexane oxidation reactions. The improved selectivity exhibited by the supramolecular catalyst for cyclohexane oxidation has been ascribed to electronic effects on the oxomanganese(V) porphyrin species induced by the four peripheral clusters, in the formal (RuRuRuIII)-Ru-IV-Ru-III oxidation state. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00138-9
• 作为产物：
  描述：

  5,10,15,20-tetra(4-pyridyl)-21H,23H-porphine 、 manganese(II) acetate 以 溶剂黄146 为溶剂， 生成 meso-tetra(4-pyridyl)porphynatomanganese(III) acetate
  参考文献：
  名称：

  Novel manganese (III) porphyrin containing peripheral “[RuCl(dppb)(X-bipy)]+” cations [dppb=1,4-bis(diphenylphosphino)butane and X=–CH3, –OMe, –Cl]. X-ray structure of the cis-[RuCl(dppb)(bipy)(4-Mepy)]PF6 complex

  摘要：

  New tetraruthenated manganese (III) porphyrins were synthesized and characterized (P-31 NMR, cyclic voltammetry, UV-Vis). This new system presents four units of cationic ''[RuCl(dppb)(X-bipy)](+)''. The electrochemical and catalytic properties of the central manganese (III) show dependence on the characteristics of the peripheral ruthenium complexes as evidenced by the Mn-(III)/Mn-(II) reduction potential.The catalytic oxidation reactions of olefins, cyclohexene and cyclohexane, were carried out in the presence of tetrapyridyl manganese (III) porphyrins containing cationic ruthenium complex and using iodosylbenzene as oxygen donor. The performance of these new tetraruthenated porphyrins systems were evaluated and compared with the manganese porphyrin. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.08.021
• 作为试剂：
  描述：

  正癸烯 在 meso-tetra(4-pyridyl)porphynatomanganese(III) acetate 、 氧气 、 异丁醛 作用下， 以 乙腈 为溶剂， 反应 8.0h， 生成 1,2-二甲基丁炔酯
  参考文献：
  名称：

  锰卟啉和中孔SBA-15在烯烃与氧的对映选择性环氧化中的协同作用

  摘要：

  摘要能够以高对映选择性和高活性催化烯烃的非均质，低成本过渡金属配合物的合理设计一直是合成化学家的一个挑战性目标。在这项研究中，手性离子对策略用于合成仿生有效的锰-四吡啶基卟啉（H2TPyP）催化剂，用于烯烃与O2的不对称环氧化。在血红素型环境中，复杂的Mn-TPyP与中孔SBA-15共价连接，其抗衡离子被1-酒石酸根阴离子（SBA15- [Mn（TPyP）TA]）取代。还制备了Mn-TPyP的手性和非手性均质类似物。与相同手性催化剂在均相溶液中起作用时（TOF 97 h-1）相比，SBA-15纳米反应器中所含的锰卟啉具有增强的活性（TOF = 652 h-1）和对映体过量（ee 93％）。和ee 83％）用O2 /异丁醛氧化1-癸烯。高比表面积，均匀尺寸的孔道和催化剂的位点隔离的活性中心可有助于高活性和对映选择性。SBA15- [Mn（TPyP）TA]在结构上稳定，可以回收再利用。在五个循环后，苯乙烯氧化的总周转数为47

  DOI：

  10.1016/j.ica.2017.10.037

文献信息

• Enhanced enantioselective oxidation of olefins catalyzed by Mn-porphyrin immobilized on graphene oxide
  作者：Kayhaneh Berijani、Afsaneh Farokhi、Hassan Hosseini-Monfared、Christoph Janiak

  DOI：10.1016/j.tet.2018.03.027

  日期：2018.5

  Raman and thermogravimetric analysis (TGA). The graphene-supported Mn-porphyrin showed higher activity for the enantioselective epoxidation of unfunctionalized olefins with molecular oxygen in the presence of isobutyraldehyde. It could be recovered easily and reused in asymmetric oxidation of styrene precursor in a five-step sequence without any considerable loss of its catalytic activity and selectivity

  通过共价连接H 2的Mn（III）配合物制备了一种有效的对映选择性非均相催化剂GO- [Mn（TPyP）tart]。TPyP通过丙基键连接至氧化石墨烯（GO）纳米片，并使用手性酒石酸抗衡离子。该催化剂的特征在于傅立叶变换红外（FT-IR），漫反射紫外可见（DR UV-Vis）光谱，粉末X射线衍射（XRD），扫描电子显微镜（SEM），拉曼和热重分析（TGA） 。在异丁醛存在下，石墨烯负载的锰卟啉对未官能化烯烃与分子氧的对映选择性环氧化反应显示出更高的活性。它可以很容易地回收，并可以五步顺序重新用于苯乙烯前体的不对称氧化，而不会显着降低其催化活性和选择性。获得的光学环氧化物选择性为86％至100％。
• Chirally-Modified Graphite Oxide as Chirality Inducing Support for Asymmetric Epoxidation of Olefins with Grafted Manganese Porphyrin
  作者：Elahe Ahadi、Hassan Hosseini-Monfared、Carsten Schlüsener、Christoph Janiak、Afsaneh Farokhi

  DOI：10.1007/s10562-019-02933-1

  日期：2020.3

  -tartrate (GO * ) and used as asymmetric support for a covalently-linked manganese porphyrine complex [Mn(TPyP)OAc]. The thereby obtained heterogeneous catalyst, GO * -[Mn(TPyP)OAc], showed excellent performance and ee-values of 92–99% for the asymmetric epoxidation of prochiral olefins with O 2 as oxidant and isobutyraldehyde as co-reductant in acetonitrile; linear terminal olefins with 54–76% conversion

  摘要 通过对映纯 l-酒石酸盐 (GO * ) 的氧化石墨 (GO) 功能化制备手性诱导剂，并将其用作共价连接的锰卟啉配合物 [Mn(TPyP)OAc] 的不对称载体。由此获得的多相催化剂GO*-[Mn(TPyP)OAc]在乙腈中以O 2 为氧化剂、异丁醛为共还原剂的前手性烯烃不对称环氧化反应中表现出优异的性能和92-99%的ee值；具有 54-76% 转化率和芳族烯烃定量转化率的线性末端烯烃。GO * -[Mn(TPyP)OAc] 催化剂具有高活性、可回收性，同时使用手性池中的手性诱导剂制备既简单又便宜。通过扫描电镜（SEM）、透射电镜（TEM）、BET分析等对催化剂的结构进行了阐明，FT-IR、拉曼和光致发光光谱方法。图形摘要用对映纯基团官能化的氧化石墨被用作手性诱导剂和Mn-卟啉复合物的不对称载体。由此获得的多相催化剂是用于前手性烯烃环氧化的优异的对映选择性催化剂。
• Kinetics and mechanistic studies on the formation and reactivity of high valent MnO porphyrin species: mono-<i>ortho</i> or <i>para</i>-substituted porphyrins <i>versus</i> a di-<i>ortho</i>-substituted one
  作者：Rahele Nasrollahi、Saeed Zakavi

  DOI：10.1039/c7nj04233g

  日期：——

  intermediates of the para-substituted porphyrins were significantly degraded under reaction conditions, the corresponding species of the ortho substituted porphyrins showed high oxidative stability up to 20 min. Interestingly, the high valent Mn(O) of the mono-ortho-substituted meso-tetra(phenyl)porphyrins were as stable as that of meso-tetra(2,6-dichlorophenyl)porphyrin. The presence of imidazole (ImH)

  高锰价V（O）（λ最大≈407纳米）和Mn IV（O）（λ最大≈421纳米）的一系列的物种富电子和缺电子的内消旋-四（芳基）卟啉（=芳基苯基，2-氯苯基，2-硝基苯基，2-甲基苯基，2-溴苯基，2,6-二氯苯基（4-甲氧基苯基，4-甲基苯基，4-氯苯基和4-吡啶基）是通过相应的锰卟啉与在较低温度（273 K）下的二氯甲烷中的丙酮 虽然对位取代卟啉的高价Mn（O）中间体在反应条件下显着降解，但邻位的相应物种取代的卟啉显示出长达20分钟的高氧化稳定性。有趣的是，单邻取代的内消旋-四（苯基）卟啉的高价Mn（O）与内消旋-四（2,6-二氯苯基）卟啉的高价Mn（O）一样稳定。发现咪唑（ImH）的存在在高价Mn（O）物种的形成和反应性中起关键作用。研究了高价Mn V（O）卟啉中间体氧化烯烃的动力学和机理，并在拟一级条件下评价了二级速率常数。而且，Mn IV（O）物种的反应性与相应的Mn V相当。（O）
• Synthesis and Antimicrobial Activity of a Pyridine Complex of (Acetato)[5,10,15,20-tetrakis(N-methylpyridin- 4-yl)porphinato]manganese(III) Tetratosylate
  作者：E. N. Ovchenkova、N. G. Bichan、A. V. Lyubimtsev、E. V. Garasko、T. N. Lomova

  DOI：10.1134/s1070363218080170

  日期：2018.8

  Aiming at preparation of new biologically active donoracceptor complexes, a water-soluble manganese(III) complex with 5,10,15,20-tetrakis(N-methylpyridin-4-yl)porphine tetratosylate was synthesized and its reaction with pyridine was studied by spectrophotometry using the molar ratio method. In water a 1: 1 donoracceptor complex with pyridine is formed. The chemical structure of the compounds was established by spectral methods. (Acetato)[5,10,15,20-tetrakis(N-methylpyridin-4-yl)porphinato]manganese(III) tetratosylate and especially its donoracceptor complex with pyridine showed an antifungal activity against Candida albicans.
• Micellar aggregates of platinum(II) complexes containing porphyrins
  作者：Luigi Monsú Scolaro、Caterina Donato、Mariangela Castriciano、Andrea Romeo、Raffaello Romeo

  DOI：10.1016/s0020-1693(99)00617-9

  日期：2000.4