Vasil'ev, A. A.; Poddubnaya, S. S.; Cherkaev, G. V., Journal of Organic Chemistry USSR (English Translation), 1987, vol. 23, # 8, p. 1457 - 1460
作者:Vasil'ev, A. A.、Poddubnaya, S. S.、Cherkaev, G. V.、Cherkaev, V. G.
DOI:——
日期:——
Copper-Catalyzed γ-Selective and Stereospecific Allylic Alkylation of Ketene Silyl Acetals
作者:Dong Li、Hirohisa Ohmiya、Masaya Sawamura
DOI:10.1021/ja111645q
日期:2011.4.20
Copper-catalyzed allylic alkylation of ketene silyl acetals proceeded with excellent γ-E-selectivity. Efficient α-to-γ chirality transfer with anti-selectivity occurred in the reaction of enantioenriched secondary allylic phosphates, affording enantioenriched β-branched γ,δ-unsaturated esters. Excellent functional group compatibility was observed.