1-butylcarbazole | 111960-26-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 1-butylcarbazole
• 英文别名: 1-Butyl-9H-carbazole
• CAS: 111960-26-0
• 化学式: C₁₆H₁₇N
• 分子量: 223.318
• InChiKey: ZQWJZVCRQDBHBQ-UHFFFAOYSA-N

物化性质

• 熔点：
  56-57 °C(Solv: ethanol (64-17-5))
• 沸点：
  398.9±11.0 °C(Predicted)
• 密度：
  1.106±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  15.8
• 氢给体数：
  1
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1-碘丁烷 、 9-(1-pyrrolidinomethyl)carbazole 在 叔丁基锂 作用下， 生成 1-butylcarbazole
  参考文献：
  名称：

  Improved syntheses of substituted carbazoles and benzocarbazoles via lithiation of the (dialkylamino)methyl (aminal) derivatives

  摘要：

  DOI：

  10.1021/jo00239a020

文献信息

• [EN] METHODS AND COMPOUNDS FOR PHOTO LEWIS ACID GENERATION AND USES THEREOF<br/>[FR] PROCÉDÉS ET COMPOSÉS POUR LA PHOTOGÉNÉRATION D'ACIDES DE LEWIS ET LEURS UTILISATIONS
  申请人：UTI LIMITED PARTNERSHIP

  公开号：WO2013142956A1

  公开（公告）日：2013-10-03

  There are disclosed masked Lewis acids into compounds in which the Lewis acid can be released by exposure of the compound to light, especially ultraviolet light. These compounds can be represented by the following formula (I): ([(AEX(3-n))(n+1)Yn](n+1)-)m(Qm+)(n+1) (I). wherein briefly, E represents boron or aluminium, X is an aryl group and Y is -Ar'EAX,. These compounds are used as catalyst for hydrosilylation reaction, crosslinking of polymers, or ester deprotection reactions as photo Lewis acid generator (PhLAG).

  披露了遮蔽的路易斯酸进入化合物中，通过将化合物暴露于光，特别是紫外光，可以释放路易斯酸。这些化合物可以用以下公式（I）表示：（[(AEX(3-n))(n+1)Yn](n+1)-)m(Qm+)(n+1) (I)。其中，简要地说，E代表硼或铝，X是一个芳基团，Y是-Ar'EAX。这些化合物作为催化剂用于氢硅化反应、聚合物的交联或作为光路易斯酸发生器（PhLAG）的酯去保护反应。
• [EN] PHOTOINITIATORS FOR UV-LED CURABLE COMPOSITIONS AND INKS<br/>[FR] PHOTOINITIATEURS POUR COMPOSITIONS DURCISSABLES PAR DEL UV ET ENCRES
  申请人：AGFA GEVAERT

  公开号：WO2011069947A1

  公开（公告）日：2011-06-16

  A specific type of carbazole photoinitiator is capable of providing radiation curable compositions that are curable by UV LEDs and do not exhibit an unstable yellowing behaviour in an image upon storage like ITX.

  一种特定类型的咔唑光引发剂能够提供通过紫外LED固化的辐射固化组合物，并且不像ITX那样在存储过程中显示出不稳定的发黄行为。
• [EN] ORGANIC MOLECULE, IN PARTICULAR FOR USE IN OPTOELECTRONIC DEVICES<br/>[FR] MOLÉCULE ORGANIQUE, EN PARTICULIER DESTINÉE À ÊTRE UTILISÉE DANS DES DISPOSITIFS OPTOÉLECTRONIQUES
  申请人：CYNORA GMBH

  公开号：WO2018229053A1

  公开（公告）日：2018-12-20

  The invention relates to an organic compound, in particular for the application in organic optoelectronic devices. According to the invention, the organic compound has - a first chemical moiety with a structure of formula (I) and - two second chemical moieties, each with a structure of formula (II), wherein the first chemical moiety is linked to each of the two second chemical moieties via a single bond; wherein LT is N or C-R1; LV is N or C-R1; LW is N or C-W; and exactly one ring atom selected from the group consisting of LT, LV and LW is N, exactly one substituent selected from the group consisting of RT, RV and RW is CN, exactly one substituent selected from the group consisting of LW, Y and X represents the binding site of a single bond linking the first chemical moiety and one of the two second chemical moieties, and exactly one substituent selected from the group consisting of RW, RY and RX represents the binding site of a single bond linking the first chemical moiety and one of the two second chemical moieties.

  本发明涉及一种有机化合物，特别适用于有机光电器件中的应用。根据本发明，所述有机化合物具有以下特征：- 第一化学基团的结构式为(I)，- 两个第二化学基团，每个化学基团的结构式为(II)，其中第一化学基团通过单键与两个第二化学基团相连；其中LT为N或C-R1；LV为N或C-R1；LW为N或C-W；并且从LT，LV和LW组成的群组中精确选择一个环原子为N，从RT，RV和RW组成的群组中精确选择一个取代基为CN，从LW，Y和X组成的群组中精确选择一个取代基表示第一化学基团和两个第二化学基团之间单键的结合位点，从RW，RY和RX组成的群组中精确选择一个取代基表示第一化学基团和两个第二化学基团之间单键的结合位点。
• [EN] ORGANIC MOLECULES FOR USE IN OPTOELECTRONIC DEVICES<br/>[FR] MOLÉCULES ORGANIQUES DESTINÉES À ÊTRE UTILISÉES DANS DES DISPOSITIFS OPTOÉLECTRONIQUES
  申请人：CYNORA GMBH

  公开号：WO2019115446A1

  公开（公告）日：2019-06-20

  The invention relates to an organic compound for the use in optoelectronic devices. According to the invention, the organic molecule has - one first chemical moiety with a structure of formula I, and - three second chemical moieties, each with a structure of formula II, wherein the first chemical moiety is linked to each of the three second chemical moieties via a single bond; wherein # represents the binding site of a single bond linking the second chemical moiety to the first chemical moiety; Z is at each occurrence independently from another selected from the group consisting of a direct bond, CR3R4, C=CR3R4, C=O, C=NR3, NR3, O, SiR3R4, S, S(O) and S(O)2; LT is N or C-T; Lv is N or C-V; Lw is N or C-W; T, V, W is the binding site of a single bond linking the first chemical moiety to one of the three second chemical moieties or is R2; X, Y is the binding site of a single bond linking the first chemical moiety to one of the three second chemical moieties or is R1; Rc is the binding site of a single bond linking the first chemical moiety to one of the three second chemical moieties; and Rw is selected from the group consisting of CN and CF3.

  本发明涉及一种用于光电子器件的有机化合物。根据本发明，该有机分子具有 - 一个具有公式I结构的第一化学基团，以及 - 三个具有公式II结构的第二化学基团，其中第一化学基团通过单键与每个第二化学基团相连；其中#表示将第二化学基团与第一化学基团连接的单键的结合位点；Z在每个出现处独立于另一个从由直接键，CR3R4，C=CR3R4，C=O，C=NR3，NR3，O，SiR3R4，S，S（O）和S（O）2组成的群体中选择；LT为N或C-T；Lv为N或C-V；Lw为N或C-W；T、V、W为将第一化学基团与三个第二化学基团中的一个相连的单键的结合位点，或为R2；X、Y为将第一化学基团与三个第二化学基团中的一个相连的单键的结合位点，或为R1；Rc为将第一化学基团与三个第二化学基团中的一个相连的单键的结合位点；Rw选自CN和CF3的群体。
• [EN] ORGANIC MOLECULES, IN PARTICULAR FOR USE IN OPTOELECTRONIC DEVICES<br/>[FR] MOLÉCULES ORGANIQUES, PARTICULIÈREMENT DESTINÉES À ÊTRE UTILISÉES DANS DES DISPOSITIFS OPTOÉLECTRONIQUES
  申请人：CYNORA GMBH

  公开号：WO2019038376A1

  公开（公告）日：2019-02-28

  The invention relates to an organic compound, in particular for the use in organic optoelectronic devices. According to the invention, the organic compound has a structure of formula I, wherein - V, W and Y are, independently from each other,selected from the group consisting of CN and R2; - Z is independently from another selected from the group consisting of:a direct bond, CR3R4, C=CR3R4, C=O, C=NR3, NR3, O, SiR3R4, S, S(O) and S(O)2; - exactly one substituent selected from the group consisting of V, Wand Y is CN.

  该发明涉及一种有机化合物，特别用于有机光电子器件中的使用。根据该发明，该有机化合物具有结构式I的结构，其中- V、W和Y分别从-CN和R2组成的组中选择；- Z独立于另一个从直接键，CR3R4，C=CR3R4，C=O，C=NR3，NR3，O，SiR3R4，S，S(O)和S(O)2组成的组中选择；- V、W和Y中的一个取代基是CN。