9,9-diethyl-N-(9H-fluoren-2-yl)fluoren-2-amine | 870283-32-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 9,9-diethyl-N-(9H-fluoren-2-yl)fluoren-2-amine
• CAS: 870283-32-2
• 化学式: C₃₀H₂₇N
• 分子量: 401.551
• InChiKey: MIGAYRPUNAUPIN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.7
• 重原子数：
  31
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  9,9-diethyl-N-(9H-fluoren-2-yl)fluoren-2-amine 在 palladium diacetate 、 N-溴代丁二酰亚胺(NBS) 、 三叔丁基膦 、 potassium tert-butylate 、 sodium t-butanolate 作用下， 以 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 38.0h， 生成 tris(7-bromo-9,9-diethylfluoren-2-yl)amine
  参考文献：
  名称：

  New Fluorophores Based on Trifluorenylamine with Very Large Intrinsic Three-Photon Absorption Cross Sections

  摘要：

  [GRAPHICS]A new fluorophore, tri(9,9-diethyl-9H-fluorenyl)amine, was synthesized by the Buchwald-Hartwig reaction of 2-aminofluorene, and based on this molecule three more fluorophores were prepared that exhibit a very large intrinsic three-photon absorption in the near-IR region, which scales as a third power of the bridge length.

  DOI：

  10.1021/ol0513645
• 作为产物：
  描述：

  2-氨基芴 、 2-溴-9,9-二乙基芴 在 1,1'-双(二苯基膦)二茂铁 、 Pt(dba)2 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 21.0h， 以78.4%的产率得到9,9-diethyl-N-(9H-fluoren-2-yl)fluoren-2-amine
  参考文献：
  名称：

  New Fluorophores Based on Trifluorenylamine with Very Large Intrinsic Three-Photon Absorption Cross Sections

  摘要：

  [GRAPHICS]A new fluorophore, tri(9,9-diethyl-9H-fluorenyl)amine, was synthesized by the Buchwald-Hartwig reaction of 2-aminofluorene, and based on this molecule three more fluorophores were prepared that exhibit a very large intrinsic three-photon absorption in the near-IR region, which scales as a third power of the bridge length.

  DOI：

  10.1021/ol0513645

文献信息

• New Fluorophores Based on Trifluorenylamine with Very Large Intrinsic Three-Photon Absorption Cross Sections
  作者：Zhiyong Suo、Mikhail Drobizhev、Charles W. Spangler、Niklas Christensson、Alexander Rebane

  DOI：10.1021/ol0513645

  日期：2005.10.1

  [GRAPHICS]A new fluorophore, tri(9,9-diethyl-9H-fluorenyl)amine, was synthesized by the Buchwald-Hartwig reaction of 2-aminofluorene, and based on this molecule three more fluorophores were prepared that exhibit a very large intrinsic three-photon absorption in the near-IR region, which scales as a third power of the bridge length.