3-烯丙氧基丙基甲基丙烯酸酯 | 77757-02-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 3-烯丙氧基丙基甲基丙烯酸酯
• 英文名称: 3-allyloxypropyl methacrylate
• 英文别名: Allyloxypropyl methacrylate；3-prop-2-enoxypropyl 2-methylprop-2-enoate
• CAS: 77757-02-9
• 化学式: C₁₀H₁₆O₃
• mdl: MFCD00080399
• 分子量: 184.235
• InChiKey: VTPQJFCQKHYNAE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 海关编码：
  2916140000

反应信息

• 作为反应物：
  描述：

  3-烯丙氧基丙基甲基丙烯酸酯 在 dihydrogen hexachloroplatinate 三氯硅烷 作用下， 以 四氢呋喃 、 异丙醇 、 甲苯 为溶剂， 生成 [3-(3-methacryloxypropoxy)propyl]trichlorosilane
  参考文献：
  名称：

  EP1439181

  摘要：

  公开号：
• 作为产物：
  描述：

  1-烯丙基氧基丙-1-醇 、 甲基丙烯酰氯 在 三乙胺 作用下， 反应 2.5h， 生成 3-烯丙氧基丙基甲基丙烯酸酯
  参考文献：
  名称：

  EP1439181

  摘要：

  公开号：

文献信息

• Acetylacetoxyalkyl-allyl ethers
  申请人：Hoechst Aktiengesellschaft

  公开号：US04418207A1

  公开（公告）日：1983-11-29

  Unsaturated acetoacetic acid esters are suitable as comonomers in the polymerization of unsaturated compounds in an aqueous medium. Particularly suitable are acetylacetoxyalkyl-allyl ethers which may be synthesized in an easy manner and correspond to the formulae ##STR1## Said allyl ether derivatives are especially prepared by reacting an allyl alcohol with an epoxide and reacting the resulting hydroxyalkyl-allyl ether with diketene. Both reaction steps are carried out at a temperature of from 0.degree. to 100.degree. C., preferably in the presence of a catalyst. The allyl ether derivatives may be copolymerized especially with vinyl compounds, such as vinyl esters, acrylic acid esters, olefins, vinyl halides and vinyl aromatic hydrocarbons.

  不饱和的乙酰乙酸酯是适合在水介质中聚合不饱和化合物的共聚单体。特别适合的是乙酰乙酸烯丙酯醚，可以容易地合成并对应于公式##STR1## 所述烯丙醚衍生物是通过将烯丙醇与环氧化物反应，并将所得的羟基烷基烯丙醚与二酮反应而特别制备的。两个反应步骤都在0℃至100℃的温度下进行，最好在催化剂的存在下进行。烯丙醚衍生物可以与乙烯化合物（例如乙烯酸酯，丙烯酸酯，烯烃，乙烯卤化物和乙烯芳香族碳氢化合物）共聚。
• MONOMER COMPOSITION, POLYMER OBTAINED THEREFROM, AND OCULAR LENS
  申请人：Johnson & Johnson Vision Care, Inc.

  公开号：EP1354898A1

  公开（公告）日：2003-10-22

  This invention has the objective of providing monomer compositions with which polymers of a superior balance of various physical properties such as high oxygen permeability, high water content and a low modulus of elasticity can be obtained. It has the further objective of providing polymers and ophthalmic lenses comprised of said monomers. It is a monomer composition in which three types of monomers specified by the values of Q = (mass of Si atoms in 1 molecule of monomer) / (molecular weight of the monomer) and of Z = (number of ether oxygens in 1 molecule of monomer) + (number of hydroxyl groups in 1 molecule of monomer) are combined in suitable weight ratios.

  本发明的目的是提供一种单体组合物，利用这种单体组合物可以获得各种物理性能 （如高透氧性、高含水量和低弹性模量）平衡极佳的聚合物。其进一步目标是提供由上述单体组成的聚合物和眼科镜片。 它是一种单体组合物，其中三种类型的单体按适当的重量比组合，其值分别为 Q=（1 个单体分子中 Si 原子的质量）/（单体分子量）和 Z=（1 个单体分子中醚氧原子的数量）+（1 个单体分子中羟基的数量）。
• MONOMER, POLYMER, AND OCULAR LENS COMPRISING THE SAME
  申请人：Johnson & Johnson Vision Care, Inc.

  公开号：EP1439181A1

  公开（公告）日：2004-07-21

  Monomers for polymers having high oxygen permeability, high water content and a low modulus of elasticity are provided, and polymers and ophthalmic lenses comprised of said monomers are provided. They are monomers represented by formula (1) or (2) below:         X-O-(CH2CH2CH2O)m-(CH2)n-A     (1)    wherein, X is a polymerizable group having carbon-carbon unsaturated bonds; A is a siloxanyl group; R is H or a methyl group; m is an integer of 1 to 10; m' is an integer of 2 to 10; and n is an integer of 2 to 10.

  本发明提供了用于具有高氧气渗透性、高含水量和低弹性模量的聚合物的单体，并提供了由所述单体组成的聚合物和眼科镜片。它们是由下式（1）或（2）表示的单体： X-O-( O)m-(CH2)n-A (1) 其中，X 是具有碳-碳不饱和键的可聚合基团；A 是硅氧烷基团；R 是 H 或甲基；m 是 1-10 的整数；m'是 2-10 的整数；n 是 2-10 的整数。
• PHOTOCURABLE ACRYLIC RESIN, ADHESIVE COMPOSITION COMPRISING SAME, AND ADHESIVE FILM FORMED BY USING SAME
  申请人：LG CHEM, LTD.

  公开号：EP3733721A1

  公开（公告）日：2020-11-04

  The present invention relates to a photocurable acrylic resin which is a polymer of a monomer mixture including a crosslinkable monomer represented by [Formula 1]; a (meth)acrylic monomer including a photoinitiating functional group; and an alkyl (meth)acrylate-based monomer, and has a weight average molecular weight of 100,000 to 500,000, and a branch-type polymer structure, and an adhesive composition and an adhesive film including the same.

  本发明涉及一种光固化丙烯酸树脂，它是单体混合物的聚合物，其中包括由[式 1]表示的可交联单体；包括光引发官能团的（甲基）丙烯酸单体；以及（甲基）丙烯酸烷基单体，其重量平均分子量为 100,000 至 500,000，并具有分支型聚合物结构，以及包括其在内的粘合剂组合物和粘合膜。
• ADHESIVE COMPOSITION AND PROTECTIVE FILM USING SAME
  申请人：LG CHEM, LTD.

  公开号：EP3733807A1

  公开（公告）日：2020-11-04

  The present invention relates to an adhesive composition and a protective film including an adhesive layer formed by using the same, wherein the adhesive composition includes an acrylic copolymer formed by polymerizing a monomer mixture, the monomer mixture including a monomer represented by [Formula 1], a (meth)acrylic monomer including a carboxy group, a (meth)acrylic monomer including a cross-linkable functional group, and an alkyl(meth)acrylate-based monomer, wherein the acrylic copolymer has a polymerization conversion rate of 99 wt% or higher.

  本发明涉及一种粘合剂组合物以及使用该组合物形成的包括粘合剂层的保护膜，其中粘合剂组合物包括通过聚合单体混合物形成的丙烯酸共聚物，该单体混合物包括由[式 1]表示的单体、包括羧基的（甲基）丙烯酸单体、包括可交联官能团的（甲基）丙烯酸单体以及烷基（甲基）丙烯酸酯基单体，其中丙烯酸共聚物的聚合转化率为 99 wt%或更高。