[[3-[Iodide-[bis(triethylphosphine)]platinumethynyl]]-[5-(pyren-1-ylethynyl)phenyl]ethynyl][[[3-[(triethylphosphine)][3-(pyren-1-ylethynyl)phenylethynyl] platinumethynyl]][5-(pyren-1-ylethynyl)]phenyl]ethynylbis(triethylphosphine)platinum | 1430799-52-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: [[3-[Iodide-[bis(triethylphosphine)]platinumethynyl]]-[5-(pyren-1-ylethynyl)phenyl]ethynyl][[[3-[(triethylphosphine)][3-(pyren-1-ylethynyl)phenylethynyl] platinumethynyl]][5-(pyren-1-ylethynyl)]phenyl]ethynylbis(triethylphosphine)platinum
• CAS: 1430799-52-2
• 化学式: C₁₁₈H₁₂₇IP₆Pt₃
• 分子量: 2443.29
• InChiKey: YOCMLVRCQYJUDR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [[[[3-ethynyl-5-(pyren-1-ylethynyl)]phenyl]ethynyl]]-[[[3-[[bis(triethylphosphine)][3-(pyren-1-ylethynyl)-phenylethynyl]platinumethynyl]][5-(pyren-1-ylethynyl)]phenyl]ethynyl]bis(triethylphosphine)platinum 、 [[3-[Iodide-[bis(triethylphosphine)]platinumethynyl]]-[5-(pyren-1-ylethynyl)phenyl]ethynyl][[[3-[(triethylphosphine)][3-(pyren-1-ylethynyl)phenylethynyl] platinumethynyl]][5-(pyren-1-ylethynyl)]phenyl]ethynylbis(triethylphosphine)platinum 在 copper(l) iodide 、 二乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 1.5h， 以51%的产率得到[bis[[3-[[[3-[[bis(triethylphosphine)][3-(pyren-1-ylethynyl)phenylethynyl]platinumethynyl]]-[5-(pyren-1-ylethynyl)]phenyl]ethynyl][bis(triethylphosphine)]platinumethynyl][5-(pyren-1-ylethynyl)]-phenylethynyl]]bis(triethylphosphine)platinum
  参考文献：
  名称：

  Synthesis and characterization of multipyrene-modified platinum acetylide oligomers

  摘要：

  A series of new multipyrene-modified platinum acetylide oligomers were successfully synthesized utilizing the coupling reaction of trans-Pt complexes with C-H bonds in alkynes as the key step. These new conjugated oligomers were characterized by multinuclear NMR (H-1, C-13, and P-31) and mass spectrometry (MALDI-TOF-MS). Preliminary spectroscopic studies of these oligomers were also carried out.

  DOI：

  10.1007/s00706-012-0892-4
• 作为产物：
  描述：

  trans diiodobis(triethylphosphine)platinum(II) 、 [[[[3-ethynyl-5-(pyren-1-ylethynyl)]phenyl]ethynyl]]-[[[3-[[bis(triethylphosphine)][3-(pyren-1-ylethynyl)-phenylethynyl]platinumethynyl]][5-(pyren-1-ylethynyl)]phenyl]ethynyl]bis(triethylphosphine)platinum 在 copper(l) iodide 、 二异丙胺 作用下， 以 四氢呋喃 为溶剂， 反应 2.0h， 以70%的产率得到[[3-[Iodide-[bis(triethylphosphine)]platinumethynyl]]-[5-(pyren-1-ylethynyl)phenyl]ethynyl][[[3-[(triethylphosphine)][3-(pyren-1-ylethynyl)phenylethynyl] platinumethynyl]][5-(pyren-1-ylethynyl)]phenyl]ethynylbis(triethylphosphine)platinum
  参考文献：
  名称：

  Synthesis and characterization of multipyrene-modified platinum acetylide oligomers

  摘要：

  A series of new multipyrene-modified platinum acetylide oligomers were successfully synthesized utilizing the coupling reaction of trans-Pt complexes with C-H bonds in alkynes as the key step. These new conjugated oligomers were characterized by multinuclear NMR (H-1, C-13, and P-31) and mass spectrometry (MALDI-TOF-MS). Preliminary spectroscopic studies of these oligomers were also carried out.

  DOI：

  10.1007/s00706-012-0892-4