((2,2-bis(phenoxymethyl)propane-1,3-diyl)bis(oxy))dibenzene | 2209-94-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: ((2,2-bis(phenoxymethyl)propane-1,3-diyl)bis(oxy))dibenzene
• 英文别名: 1,3-Diphenoxy-2,2-bis-phenoxymethyl-propan；1,1'-[[2,2-bis(phenoxymethyl)-1,3-propanediyl]bis(oxy)]bisbenzene；1,3-diphenoxy-2,2-bis-phenoxymethyl-propane；Tetrakis-phenoxymethyl-methan；1,3-Diphenoxy-2,2-bis(phenoxymethyl)propane；[3-phenoxy-2,2-bis(phenoxymethyl)propoxy]benzene
• CAS: 2209-94-1
• 化学式: C₂₉H₂₈O₄
• 分子量: 440.539
• InChiKey: OXMQZJGGOXROFE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  33
• 可旋转键数：
  12
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  ((2,2-bis(phenoxymethyl)propane-1,3-diyl)bis(oxy))dibenzene 在 二硫化碳 、 溴 作用下， 生成 tetrakis[(4-bromophenoxy)methyl]methane
  参考文献：
  名称：

  Backer; Dijken, Recueil des Travaux Chimiques des Pays-Bas, 1936, vol. 55, p. 22,29

  摘要：

  DOI：
• 作为产物：
  描述：

  碘苯 、 季戊四醇 在 氢氧化钾 作用下， 以 二甲基亚砜 为溶剂， 反应 21.0h， 以92%的产率得到((2,2-bis(phenoxymethyl)propane-1,3-diyl)bis(oxy))dibenzene
  参考文献：
  名称：

  CuO纳米粒子催化C，N和C交叉偶联反应：范围和机理

  摘要：

  通过氮，氧和硫亲核试剂与芳基卤化物的交叉偶联反应，已研究了CuO纳米颗粒的C-N，C-O和C-S键形成。酰胺，胺，咪唑，酚，醇和硫醇在中等温度下在碱（例如KOH，Cs 2 CO 3和K 2 CO 3）存在下与芳基碘化物反应。该过程简单，通用，无配体且有效地以高收率提供了交叉偶联的产物。

  DOI：

  10.1021/jo8024253

文献信息

• Organically doped palladium: a highly efficient catalyst for electroreduction of CO₂to methanol
  作者：Heng-Pan Yang、Sen Qin、Huan Wang、Jia-Xing Lu

  DOI：10.1039/c5gc01504a

  日期：——

  A [PYD]@Pd composite was prepared by the entrapment of a pyridine derivative within metallic palladium. Metallic Pd act as heterogengous support and pyridine ring served as active site for electroreduction...

  通过将吡啶衍生物截留在金属钯中来制备[PYD] @Pd复合材料。金属Pd用作杂相载体，吡啶环充当电还原反应的活性位...
• Shostakovskii,M.F. et al., Journal of general chemistry of the USSR, 1965, vol. 35, p. 808 - 810
  作者：Shostakovskii,M.F. et al.

  DOI：——

  日期：——
• CELLULOSE ACYLATE FILM AND METHOD FOR PRODUCING THE SAME
  申请人：HASHIMOTO Kiyokazu

  公开号：US20090018326A1

  公开（公告）日：2009-01-15

  A cellulose acylate film, which contains 1% to 25% by mass of a plasticizer and has a cellulose acylate composition satisfying the inequalities of 0≦X≦2.5 and 2.1≦X+Y≦3.0 (in which X is a substitution degree of acetyl group, and Y is a substitution degree of at least one group selected from propionyl, butyryl, and phthaloyl groups), is transversely stretched under conditions of [preheating temperature>stretching temperature] and [preheating zone length/stretching zone length=0.1 to 10]. After the transverse stretching, the film is heat-fixed under conditions of [stretching temperature>heat-fixing temperature] and [heat-fixing zone length/stretching zone length=0.1 to 10].
• ALCOHOL COMPOUND, CHEMICALLY AMPLIFIED NEGATIVE RESIST COMPOSITION AND RESIST PATTERN FORMING PROCESS
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：US20220197140A1

  公开（公告）日：2022-06-23

  A chemically amplified negative resist composition comprising an alcohol compound of specific structure as a crosslinker has a high sensitivity and dissolution contrast and forms a pattern of good profile with reduced values of LER and CDU.
• CuO Nanoparticles Catalyzed C−N, C−O, and C−S Cross-Coupling Reactions: Scope and Mechanism
  作者：Suribabu Jammi、Sekarpandi Sakthivel、Laxmidhar Rout、Tathagata Mukherjee、Santu Mandal、Raja Mitra、Prasenjit Saha、Tharmalingam Punniyamurthy

  DOI：10.1021/jo8024253

  日期：2009.3.6

  nanoparticles have been studied for C−N, C−O, and C−S bond formations via cross-coupling reactions of nitrogen, oxygen, and sulfur nucleophiles with aryl halides. Amides, amines, imidazoles, phenols, alcohols and thiols undergo reactions with aryl iodides in the presence of a base such as KOH, Cs2CO3, and K2CO3 at moderate temperature. The procedure is simple, general, ligand-free, and efficient to afford the

  通过氮，氧和硫亲核试剂与芳基卤化物的交叉偶联反应，已研究了CuO纳米颗粒的C-N，C-O和C-S键形成。酰胺，胺，咪唑，酚，醇和硫醇在中等温度下在碱（例如KOH，Cs 2 CO 3和K 2 CO 3）存在下与芳基碘化物反应。该过程简单，通用，无配体且有效地以高收率提供了交叉偶联的产物。