7-isopropyl-1-methyl-9-nitro-[3]phenanthrylamine | 651714-33-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 7-isopropyl-1-methyl-9-nitro-[3]phenanthrylamine
• 英文别名: 9-Nitro-3-amino-1-methyl-7-isopropyl-phenanthren
• CAS: 651714-33-9
• 化学式: C₁₈H₁₈N₂O₂
• 分子量: 294.353
• InChiKey: IRYADOLMUFIFOG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.92
• 重原子数：
  22.0
• 可旋转键数：
  2.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  69.16
• 氢给体数：
  1.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  7-isopropyl-1-methyl-9-nitro-[3]phenanthrylamine 生成 3-chloro-7-isopropyl-1-methyl-9-nitro-phenanthrene
  参考文献：
  名称：

  Karrman, Svensk Kemisk Tidskrift, 1947, vol. 59, p. 57,59

  摘要：

  DOI：
• 作为产物：
  描述：

  4-chloro-7-isopropyl-1-methyl-9-nitro-[3]phenanthrylamine 在 盐酸 、 溶剂黄146 、 copper(l) chloride 作用下， 生成 7-isopropyl-1-methyl-9-nitro-[3]phenanthrylamine
  参考文献：
  名称：

  Silhlbom, Acta Chemica Scandinavica (1947), 1953, vol. 7, p. 790,796

  摘要：

  DOI：

文献信息

• Karrman; Sihlbom, Svensk Kemisk Tidskrift, 1946, vol. 58, p. 189,190, 194
  作者：Karrman、Sihlbom

  DOI：——

  日期：——
• Groundwater Exploitation and Its Impact on the Environment in the North China Plain
  作者：Liu Changming、Yu Jingjie、Eloise Kendy

  DOI：10.1080/02508060108686913

  日期：2001.6

  The North China Plain (NCP) is one of China's most important social, economic, and agricultural regions. Currently, the Plain has 17,950 thousand ha of cultivated land, 71.1 percent of which is irrigated, consuming more than 70 percent of the total water supply. Increasing water demands associated with rapid urban and industrial development and expansion of irrigated land have led to overexploitation of both surface and the ratio of groundwater resources, particularly north of the Yellow River. In 1993, the ratio of groundwater exploitation to recharge in many parts of the NCP exceeded 1.0; in some areas, the ratio exceeded 1.5. Consequently, about 1.06 million ha of water-short irrigated areas in the NCP also have poor water quality. Persistent groundwater overexploitation in the northern parts of the NCP has resulted in water-level declines in both shallow and deep aquifers. According to data from 600 shallow groundwater observation wells in the Hebei Plain, the average depth to water increased from 7.23 m in 1983 to 11.52 m in 1993, indicating an average water-table decline of 0.425 m/year. Water table declines are not uniformly distributed throughout the area. Depletion rates are generally greatest beneath cities and intensively groundwater-irrigated areas. Water-table declines have also varied over time. With the continued decline of groundwater levels, large depression cones have formed both in unconfined and confined aquifers beneath the Hebei Plain. Groundwater depletion in the NCP has severely impacted the environment. Large tracts of land that overlie cones of depression have subsided, seawater has intruded into previously freshwater aquifers in coastal plains, and groundwater quality has deteriorated due to salinization, seawater intrusion, and untreated urban and industrial wastewater discharge. In order to balance groundwater exploitation with recharge, the major remedial measures suggested are to strengthen groundwater management, to raise water use efficiency, to adjust the water-consumed structure, and to increase water supply.