5-hydroxy-undecan-2-one | 51032-09-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 5-hydroxy-undecan-2-one
• 英文别名: 5-hydroxyundecan-2-one
• CAS: 51032-09-8
• 化学式: C₁₁H₂₂O₂
• 分子量: 186.294
• InChiKey: FKOBJWXEXLHKIE-UHFFFAOYSA-N

物化性质

• 沸点：
  290.9±23.0 °C(Predicted)
• 密度：
  0.908±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.91
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  5-hydroxy-undecan-2-one 、 三丁基氯化锡 在 正丁基锂 作用下， 以 乙二醇二甲醚 、 乙醚 、 正己烷 为溶剂， 以31%的产率得到2-tributylstannylundec-1-en-5-ol
  参考文献：
  名称：

  Adlington, Robert M.; Baldwin, Jack E.; Gansaeuer, Andreas, Journal of the Chemical Society. Perkin transactions I, 1994, # 13, p. 1697 - 1702

  摘要：

  DOI：
• 作为产物：
  描述：

  2-phenylsulfanyl-undec-2-en-5-ol 在 mercury dichloride 作用下， 以 水 、 乙腈 为溶剂， 生成 5-hydroxy-undecan-2-one
  参考文献：
  名称：

  Biellmann,J.-F.; Schirlin,D., Synthetic Communications, 1978, vol. 8, p. 409 - 412

  摘要：

  DOI：

文献信息

• Lithiated S-(2-methoxyallyl) N,N-dimethyldithiocarbamate, a new, versatile reagent for the introduction of the acetonyl functional group into organic substrates
  作者：Takeshi Nakai、Hiroyuki Shiono、Makoto Okawara

  DOI：10.1016/s0040-4039(00)91227-9

  日期：1975.1
• Vaskan,R.N.; Kovalev,B.G., Journal of Organic Chemistry USSR (English Translation), 1975, vol. 11, p. 1829 - 1831
  作者：Vaskan,R.N.、Kovalev,B.G.

  DOI：——

  日期：——
• Adlington Robert M., Baldwin Jack E., Gansaeuer Andreas, McCoull William,+, J. Chem. Soc. Dalton Trans, (1994) N 13, S 1697-1701
  作者：Adlington Robert M., Baldwin Jack E., Gansaeuer Andreas, McCoull William,+

  DOI：——

  日期：——
• COOLING SENSATION AGENT COMPOSITION AND SENSORY STIMULATION AGENT COMPOSITION
  申请人：Ishida Kenya

  公开号：US20110117147A1

  公开（公告）日：2011-05-19

  The invention relates to a cooling sensation agent composition with a prolonged cool sensation effect comprising at least one compound selected from Formula (1) wherein each of A and B is a hydrogen atom or a hydrocarbon group which may have one or more substituents, in which A and B are not hydrogen atoms simultaneously, and the total number of carbon atoms in A and B is in the range of 6 to 18; and Formulae (2) to (4) wherein R1, R2, and R3 each represent a residue of an alcohol selected from 1-menthol, 1-isopulegol, 3-(1-menthoxy)propan-1,2-diol, 2-(1-menthoxy)ethan-1-ol, 3-(1-menthoxy)propan-1-ol, 2-methyl-3-(1-menthoxy)propan-1,2-diol and para-menthan-3,8-diol), and R4 represents a residue of a branched or straight-chain, cyclic or linear, or saturated or unsaturated alcohol having 6 to 18 carbon atoms that may have one or more aromatic rings that may have a condensed ring and substituent groups such as hydroxyl and ether groups; and R6 represents a hydrocarbon group having 11 to 19 carbon atoms that may be branched and contain one or more unsaturated bonds. The invention also relates to a sensory stimulation agent composition comprising the cooling sensation agent composition; a flavor or fragrance composition, a beverage or food product, a perfume or cosmetic product, a toiletry product, a daily utensil product or grocery, a fiber, a fiber product, a cloth or a medicine comprising the cooling sensation agent composition or the sensory stimulation agent composition; a production method thereof; a cooling processing method of a fiber, fiber product or a cloth, comprising compounding the cooling sensation agent composition or the sensory stimulation agent composition; and new compounds.
• US8632792B2
  申请人：——

  公开号：US8632792B2

  公开（公告）日：2014-01-21