N,N-Dimethyl-N'-[1-phenanthren-9-yl-meth-(E)-ylidene]-ethane-1,2-diamine | 724427-38-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: N,N-Dimethyl-N'-[1-phenanthren-9-yl-meth-(E)-ylidene]-ethane-1,2-diamine
• CAS: 724427-38-7
• 化学式: C₁₉H₂₀N₂
• 分子量: 276.381
• InChiKey: RFBHZCSOKWNUBQ-XSFVSMFZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.97
• 重原子数：
  21.0
• 可旋转键数：
  4.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  15.6
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  dichlorobis(dimethyl sulfoxide)platinum(II) 、 N,N-Dimethyl-N'-[1-phenanthren-9-yl-meth-(E)-ylidene]-ethane-1,2-diamine 以 甲醇 为溶剂， 以97%的产率得到
  参考文献：
  名称：

  Five- and six-membered platinacycles derived from phenantryl and anthracenyl imines

  摘要：

  The reaction of [Pt2Me4(mu-SMe2)(2)] with ligands Me2NCH2CH2NCHAr (2a, Ar = 9-phenantryl; 2b, Ar = 9-anthracenyl) carried out in acetone at room temperature produced the corresponding Compounds [PtMe2{9-(Me2NCH2CH2NCH)C14H9}] (3) in which the imines act as bidentate [N,N'] ligands. Refluxing toluene solutions of compounds 3 gave cyclometallated [C,N,N] compounds [PtMe{9-(Me2NCH2CH2NCH)C14H8}] (4) as a mixture of two isomers containing either a five- or a six-membered metallacycles for 3a and as a single isomer containing a six-membered metallacycle for 3b. The reactions of compounds 4 with acetyl chloride and with methyl iodide produced. respectively, compounds [PtCl{9-(Me2NCH2CH2NCH)C14H8}] (5) and [PtMe2I{9-(Me2NCH2CH2NCH)C14H8}] (6). All compounds were characterised by NMR spectroscopies and analytical data. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.03.020
• 作为产物：
  描述：

  9-甲醛菲 、 N,N-二甲基乙二胺 以 甲苯 为溶剂， 反应 1.0h， 以93%的产率得到N,N-Dimethyl-N'-[1-phenanthren-9-yl-meth-(E)-ylidene]-ethane-1,2-diamine
  参考文献：
  名称：

  Five- and six-membered platinacycles derived from phenantryl and anthracenyl imines

  摘要：

  The reaction of [Pt2Me4(mu-SMe2)(2)] with ligands Me2NCH2CH2NCHAr (2a, Ar = 9-phenantryl; 2b, Ar = 9-anthracenyl) carried out in acetone at room temperature produced the corresponding Compounds [PtMe2{9-(Me2NCH2CH2NCH)C14H9}] (3) in which the imines act as bidentate [N,N'] ligands. Refluxing toluene solutions of compounds 3 gave cyclometallated [C,N,N] compounds [PtMe{9-(Me2NCH2CH2NCH)C14H8}] (4) as a mixture of two isomers containing either a five- or a six-membered metallacycles for 3a and as a single isomer containing a six-membered metallacycle for 3b. The reactions of compounds 4 with acetyl chloride and with methyl iodide produced. respectively, compounds [PtCl{9-(Me2NCH2CH2NCH)C14H8}] (5) and [PtMe2I{9-(Me2NCH2CH2NCH)C14H8}] (6). All compounds were characterised by NMR spectroscopies and analytical data. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.03.020