undeca-4E,6Z-dien-1-ol | 261163-75-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: undeca-4E,6Z-dien-1-ol
• 英文别名: (4E,6Z)-undeca-4,6-dien-1-ol
• CAS: 261163-75-1
• 化学式: C₁₁H₂₀O
• 分子量: 168.279
• InChiKey: YFKOGZCPDXKVHD-IGTJQSIKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  12
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  undeca-4E,6Z-dien-1-ol 在 9-borabicyclo[3.3.1]nonane dimer 、 Pyr*CrO₃*HCl 、 sodium hexamethyldisilazane 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 20.0h， 生成 (5E,7Z)-5,7-dodecadiene-1-ol
  参考文献：
  名称：

  Insect pheromones and their analogs LIX. A new method for the synthesis of components of the sex pheromones of insects of the genusMalacosoma

  摘要：

  A new method has been developed for the synthesis of the main components of the sex pheromones of insects of the Malacasoma genus that is based on the selective transformation of the product of the partial ozonolysis of cyclohexa-1,4-diene - methyl 6-oxohex-4E-enoate.

  DOI：

  10.1007/bf02234863
• 作为产物：
  描述：

  (E)-methyl 5-formylpent-4-enoate 在 lithium aluminium tetrahydride 、 sodium hexamethyldisilazane 作用下， 以 四氢呋喃 、 乙醚 为溶剂， 反应 16.5h， 生成 undeca-4E,6Z-dien-1-ol
  参考文献：
  名称：

  Insect pheromones and their analogs LIX. A new method for the synthesis of components of the sex pheromones of insects of the genusMalacosoma

  摘要：

  A new method has been developed for the synthesis of the main components of the sex pheromones of insects of the Malacasoma genus that is based on the selective transformation of the product of the partial ozonolysis of cyclohexa-1,4-diene - methyl 6-oxohex-4E-enoate.

  DOI：

  10.1007/bf02234863

文献信息

• Insect pheromones and their analogs LIX. A new method for the synthesis of components of the sex pheromones of insects of the genusMalacosoma
  作者：O. S. Kukovinets、V. G. Kasradze、E. V. Salimova、V. N. Odinokov、F. Z. Galin、P. I. Fedorov

  DOI：10.1007/bf02234863

  日期：1999.5

  A new method has been developed for the synthesis of the main components of the sex pheromones of insects of the Malacasoma genus that is based on the selective transformation of the product of the partial ozonolysis of cyclohexa-1,4-diene - methyl 6-oxohex-4E-enoate.