Bis(chlor-tert-butyl)-peroxid | 42334-69-0

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 英文名称: Bis(chlor-tert-butyl)-peroxid
• 英文别名: bis-(2-chloro-1,1-dimethyl-ethyl) peroxide；1-Chloro-2-(1-chloro-2-methylpropan-2-yl)peroxy-2-methylpropane；1-chloro-2-(1-chloro-2-methylpropan-2-yl)peroxy-2-methylpropane
• CAS: 42334-69-0
• 化学式: C₈H₁₆Cl₂O₂
• 分子量: 215.12
• InChiKey: ULEPAGUSKAPXAG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-氯-2-甲基-2-丙醇 、 Chlor-tert-butylhydroperoxid 生成 Bis(chlor-tert-butyl)-peroxid
  参考文献：
  名称：

  Thermal decomposition of tertiary alkyl peroxides. Substituent effects in peroxide bond homolysis and .beta. scission of alkoxy radicals

  摘要：

  DOI：

  10.1021/jo00964a001

文献信息

• HIGH REFRACTIVE INDEX COMPOSITION
  申请人：Battelle Memorial Institute

  公开号：EP2563826A2

  公开（公告）日：2013-03-06
• US8883935B2
  申请人：——

  公开号：US8883935B2

  公开（公告）日：2014-11-11
• [EN] HIGH REFRACTIVE INDEX COMPOSITION<br/>[FR] COMPOSITION À INDICE DE RÉFRACTION ÉLEVÉ
  申请人：BATTELLE MEMORIAL INSTITUTE

  公开号：WO2011139856A2

  公开（公告）日：2011-11-10

  A high refractive index composition comprising a reaction product of one or more first organic compounds capable of undergoing polymerization and one or more second compounds with high refractive index, and the method of making and using the composition. A composition comprising an organic compound obtained by coupling two reactive groups (a) and (b), wherein a. the reactive group (a) is Y-(CH2)n-M(0-R)3, wherein R is CH3, C2H5, C3H8, C4H10; and Y is -NH2, -COOH, -NCO, or epoxy; and wherein M is selected from the group consisting of Ti, Zr, V, Mg, Al, Mn, Sb, Ba, Ca, Ce, Si, and Sn; and b. the reactive group (b) is selected from the group consisting of carbazole, fluorene, imidazole with one or more functional groups selected from -OH, -NH2, -COOH, -NCO, -epoxy, -vinyl, -acrylic, -acyl, - alkyl, -halide, -amino, -ketone, -allyl, -allylic, - thiol, -isocyanate, and a mixture thereof; and the method of making and using the composition.
• Thermal decomposition of tertiary alkyl peroxides. Substituent effects in peroxide bond homolysis and .beta. scission of alkoxy radicals
  作者：W. H. Richardson、M. B. Yelvington、A. H. Andrist、E. W. Ertley、R. S. Smith、T. D. Johnson

  DOI：10.1021/jo00964a001

  日期：1973.12