Cyclobuten-1.2-dicarbonsaeure-diallylester | 38818-34-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Cyclobuten-1.2-dicarbonsaeure-diallylester
• 英文别名: Bis(prop-2-enyl) cyclobutene-1,2-dicarboxylate；bis(prop-2-enyl) cyclobutene-1,2-dicarboxylate
• CAS: 38818-34-7
• 化学式: C₁₂H₁₄O₄
• 分子量: 222.241
• InChiKey: SGOJOMKXONZXHX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  16
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Cyclobuten-1.2-dicarbonsaeure-diallylester 390.0 ℃ 、9.33 Pa 条件下， 生成 2.3-Dicarballyloxybutadien-1.3
  参考文献：
  名称：

  [4 + 2] -1,2-二氰基环丁烯和环塞纳热合环2,3-二氰基丁二烯-1,3 † ‡的环加成

  摘要：

  提出了从1,2-二氰基环丁烷（1）（一种可商购的丙烯腈环二聚体）开始的容易的合成路线，以得到1,2-二氰基环丁烯（3），环丁烯-1,2-二羧酸（56）及其衍生物。

  DOI：

  10.1002/hlca.19730560839
• 作为产物：
  描述：

  环丁烷-1,2-二甲腈 在 氯化亚砜 、 硫酸 、 三乙胺 作用下， 以 1,4-二氧六环 为溶剂， 生成 Cyclobuten-1.2-dicarbonsaeure-diallylester
  参考文献：
  名称：

  [4 + 2] -1,2-二氰基环丁烯和环塞纳热合环2,3-二氰基丁二烯-1,3 † ‡的环加成

  摘要：

  提出了从1,2-二氰基环丁烷（1）（一种可商购的丙烯腈环二聚体）开始的容易的合成路线，以得到1,2-二氰基环丁烯（3），环丁烯-1,2-二羧酸（56）及其衍生物。

  DOI：

  10.1002/hlca.19730560839

文献信息

• COMPOSITION FOR LINING
  申请人：Osaka Soda Co., Ltd.

  公开号：EP3326784A1

  公开（公告）日：2018-05-30

  The present invention aims to provide a lining composition which overcomes the problems such as environmental problems (e.g. marine pollution) and VOC problem and which has a good cure rate. We have found that this can be achieved by a composition containing a vinyl ester resin as a prepolymer component and an aliphatic or alicyclic polyfunctional allyl ester compound as a crosslinking agent.

  本发明旨在提供一种内衬组合物，它能克服环境问题（如海洋污染）和挥发性有机化合物 问题，并具有良好的固化率。我们发现，可以通过一种含有乙烯基酯树脂作为预聚物成分和脂肪族或脂环族多官能烯丙基酯化合物作为交联剂的组合物来实现这一目标。
• PHOTOCURABLE RESIN COMPOSITION AND CURED PRODUCT OF SAME
  申请人：Osaka Soda Co., Ltd.

  公开号：EP3438135A1

  公开（公告）日：2019-02-06

  The objection of the present invention is to provide a photocurable resin composition having deep curability. The photocurable resin composition comprises an allyl polymer (a) produced by polymerization of an allyl compound represented by the following formula (1), a photocurable compound (b), and a photopolymerization initiator (c). In the formula, n represents an integer of 2 to 4; Z is selected from a binding site, an n-valent aliphatic chain hydrocarbon group optionally having a hydroxyl group, an n-valent alicyclic hydrocarbon group optionally having an alkyl group, and an n-valent aromatic hydrocarbon group optionally having an alkyl group; n is 2 and two -COOCH2CH=CH2 moieties are directly bonded to each other when Z is a binding site.         Z⁅COOCH2CH=CH2]n     (1)

  本发明的目的是提供一种具有深度固化性的光固化树脂组合物。光固化树脂组合物包括由下式（1）代表的烯丙基化合物聚合生成的烯丙基聚合物（a）、光固化化合物（b）和光聚合引发剂（c）。式中，n 代表 2 至 4 的整数；Z 选自结合位点、任选具有羟基的 n 价脂族链烃基团、任选具有烷基的 n 价脂环烃基团和任选具有烷基的 n 价芳香烃基团；n 为 2，当 Z 为结合位点时，两个 -COO CH=CH2 分子彼此直接键合。 Z⁅COO CH= ]n (1)
• PHOTOCURABLE RESIN COMPOSITION, INK, AND PAINT
  申请人：Osaka Soda Co., Ltd.

  公开号：EP3674329A1

  公开（公告）日：2020-07-01

  The present invention aims to provide a photocurable resin composition that can constitute a composition having excellent adhesion to plastic substrates. The present invention relates to a photocurable resin composition containing: an allyl polymer (A) produced by polymerizing an allyl compound represented by the following formula (1):         Z-[-COOCH2CH=CH2]n     (1) wherein n is an integer of 2 to 4 and Z is an n-valent alicyclic hydrocarbon group that may have an alkyl group; and a silane coupling agent (B).

  本发明旨在提供一种光固化树脂组合物，该组合物可构成对塑料基材具有极佳附着力 的组合物。本发明涉及一种光固化树脂组合物，其中含有：通过聚合下式（1）所代表的烯丙基化合物而制得的烯丙基聚合物（A）： Z-[-COOCH2CH=CH2]n (1) 其中 n 为 2 至 4 的整数，Z 为可带有烷基的正价脂环烃基团；以及硅烷偶联剂 (B)。
• THERMOSETTING RESIN COMPOSITION
  申请人：Osaka Soda Co., Ltd.

  公开号：EP3778680A1

  公开（公告）日：2021-02-17

  The present invention aims to provide a thermosetting resin composition that causes no environmental issues such as generation of VOCs and has curability (especially, curability at low temperature) as good as that in the case using a diallyl phthalate monomer as a crosslinking agent. The present invention reveals that the following thermosetting resin composition has excellent curability at low temperature. The thermosetting resin composition contains an unsaturated polyester resin; an alicyclic polyfunctional allyl ester represented by the following formula (1) [in the formula, n is an integer of 2 to 4 and Z is an n-valent alicyclic hydrocarbon group]; and an initiator having a one-minute half-life temperature in a range of 100°C to 250°C and a molecular weight of 100 to 400 and selected from the group consisting of peroxyketals, peroxyesters, dialkyl peroxides, and peroxy carbonates. [Chem. 1]         Z(̵COOCH2 CH=CH2)n ···     (1)

  本发明旨在提供一种热固性树脂组合物，该组合物不会产生挥发性有机化合物等环境问题，其固化性（尤其是低温固化性）与使用邻苯二甲酸二烯丙酯单体作为交联剂的情况下的固化性相同。本发明揭示了以下热固性树脂组合物具有优异的低温固化性。该热固性树脂组合物含有不饱和聚酯树脂；由下式（1）代表的脂环族多官能烯丙基酯[式中，n 为 2 至 4 的整数，Z 为正价脂环族烃基]；以及一种引发剂，该引发剂的一分钟半衰期温度在 100°C 至 250°C 之间，分子量在 100 至 400 之间，选自过氧酮、过氧酯、二烷基过氧化物和过氧碳酸盐组成的组。 [化学 1］ Z(̵COO CH=CH2)n --- (1)
• Photocurable resin composition and cured product of same
  申请人：OSAKA SODA CO., LTD.

  公开号：US10604600B2

  公开（公告）日：2020-03-31

  The objection of the present invention is to provide a photocurable resin composition having deep curability. The photocurable resin composition comprises an allyl polymer (a) produced by polymerization of an allyl compound represented by the following formula (1), a photocurable compound (b), and a photopolymerization initiator (c). In the formula, n represents an integer of 2 to 4; Z is selected from a binding site, an n-valent aliphatic chain hydrocarbon group optionally having a hydroxyl group, an n-valent alicyclic hydrocarbon group optionally having an alkyl group, and an n-valent aromatic hydrocarbon group optionally having an alkyl group; n is 2 and two —COOCH2CH═CH2 moieties are directly bonded to each other when Z is a binding site. ZCOOCH2CH═CH2)n  (1)

  本发明的目的是提供一种具有深度固化性的光固化树脂组合物。光固化树脂组合物包括由下式（1）代表的烯丙基化合物聚合生成的烯丙基聚合物（a）、光固化化合物（b）和光聚合引发剂（c）。式中，n 代表 2 至 4 的整数；Z 选自结合位点、任选具有羟基的 n 价脂族链烃基团、任选具有烷基的 n 价脂环烃基团和任选具有烷基的 n 价芳香烃基团；n 为 2，当 Z 为结合位点时，两个 -COO CH═CH2 分子彼此直接键合。 ZCOO CH═ )n (1)