2-(2-Benzoylphenyl)-1,2-diphenylethanone | 50805-40-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(2-Benzoylphenyl)-1,2-diphenylethanone
• CAS: 50805-40-8
• 化学式: C₂₇H₂₀O₂
• 分子量: 376.455
• InChiKey: CJWPOIMAESBDNB-UHFFFAOYSA-N

物化性质

• 沸点：
  570.3±38.0 °C(Predicted)
• 密度：
  1.163±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  29
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-(2-Benzoylphenyl)-1,2-diphenylethanone 在 臭氧 、 苯基锂 作用下， 以 乙醚 、 二氯甲烷 、 溶剂黄146 为溶剂， 反应 20.0h， 生成
  参考文献：
  名称：

  Ozonolysis of 1-substituted 2,3-diphenylindenes and o-(1-substituted-2-phenyl-3-methoxy-2-propenyl)benzophenones. Remarkable effects of the method of generation of the carbonyl oxide intermediates on the stereochemistries of both the ozonide and the methanol-derived isochroman products

  摘要：

  DOI：

  10.1021/ja00187a038
• 作为产物：
  描述：

  1,3,4-Triphenyl-2-benzopyran-2-ium perchlorate 在 水 、 sodium carbonate 作用下， 生成 2-(2-Benzoylphenyl)-1,2-diphenylethanone
  参考文献：
  名称：

  Le Roux, Jean-Pierre; Desbene, Paul-Louis; Cherton, Jean-Claude, Journal of Heterocyclic Chemistry, 1981, vol. 18, p. 847 - 849

  摘要：

  DOI：

文献信息

• Ozonolyses of 1,2-diphenyl- and 2-phenylindene
  作者：Toshiya Sugimoto、Koichi Teshima、Norinaga Nakamura、Masatomo Nojima、Shigekazu Kusabayashi、Kevin J. McCullough

  DOI：10.1021/jo00053a026

  日期：1993.1

  Ozonolyses of 1,2-diphenylindene (7), 2-phenylindene (18), and the structurally related acyclic keto olefins 13, 14, 26, and 32 were conducted in MeOH/CH2Cl2 at -70 and 0-degrees-C. The structure of the indenes, 7 and 18, and the reaction temperature, were found to exert an influence on the outcome of the reaction. Ozonolysis of 1,2-diphenylindene (7) at -70-degrees-C proceeded exclusively via the carbonyl oxide intermediate 15 providing the methanol-derived isochroman 9a as the sole isolable product. In contrast, four methanol-derived products, 20-23, were obtained from 2-phenylindene (18) under similar reaction conditions, suggesting that the primary ozonide 25 from 18 undergoes two competing modes of decomposition. Ozonolyses of indenes, 7 and 18, and 0-degrees-C gave mainly the corresponding ozonides, 8 and 19, respectively, while analogous reactions at -70-degrees-C resulted in the predominant formation of the methanol-derived products 9 and 20-23, respectively. The major differences in composition between the ozonolysis product mixtures derived from the acyclic keto olefins 13, 14, 26, and 32 and the appropriate corresponding indenes 7 and 18 suggest that the intermediate carbonyl oxides generated from the former do not make significant contributions to the reaction pathways of the latter.
• LE, ROUX, J. -P.;DESBENE, P. -L.;CHERTON, J. -C., J. HETEROCYCL. CHEM., 1981, 18, N 4, 847-849
  作者：LE, ROUX, J. -P.、DESBENE, P. -L.、CHERTON, J. -C.

  DOI：——

  日期：——
• FUJISAKA, TOMOHIRO;NOJIMA, MASATOMO;KUSABAYASHI, SHIGEKAZU, J. ORG. CHEM., 1985, 50, N 2, 275-277
  作者：FUJISAKA, TOMOHIRO、NOJIMA, MASATOMO、KUSABAYASHI, SHIGEKAZU

  DOI：——

  日期：——
• Le Roux, Jean-Pierre; Desbene, Paul-Louis; Cherton, Jean-Claude, Journal of Heterocyclic Chemistry, 1981, vol. 18, p. 847 - 849
  作者：Le Roux, Jean-Pierre、Desbene, Paul-Louis、Cherton, Jean-Claude

  DOI：——

  日期：——
• Ozonolysis of 1-substituted 2,3-diphenylindenes and o-(1-substituted-2-phenyl-3-methoxy-2-propenyl)benzophenones. Remarkable effects of the method of generation of the carbonyl oxide intermediates on the stereochemistries of both the ozonide and the methanol-derived isochroman products
  作者：Norinaga Nakamura、Tomohiro Fujisaka、Masatomo Nojima、Shigekazu Kusabayashi、Kevin J. McCullough

  DOI：10.1021/ja00187a038

  日期：1989.3