monosodium adipate | 18996-34-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: monosodium adipate
• 英文别名: sodium;hexanedioate;hydron
• CAS: 18996-34-4
• 化学式: C₆H₉O₄*Na
• 分子量: 168.125
• InChiKey: GOGGIOPQLKEIGC-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -4.84
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  80.3
• 氢给体数：
  1
• 氢受体数：
  4

安全信息

• 海关编码：
  2915900090

反应信息

• 作为反应物：
  描述：

  monosodium adipate 、 14-bromodaunorubicin hydrochloride 以 甲醇 为溶剂， 以53%的产率得到6-[2-[(2S,4S)-4-[(2R,4S,5S,6S)-4-amino-5-hydroxy-6-methyloxan-2-yl]oxy-2,5,12-trihydroxy-7-methoxy-6,11-dioxo-3,4-dihydro-1H-tetracen-2-yl]-2-oxoethoxy]-6-oxohexanoic acid
  参考文献：
  名称：

  Povarov, L. S.; Leont'eva, O. V.; Bernacki, R. J., Russian Journal of Bioorganic Chemistry, 1995, vol. 21, # 12, p. 797 - 803

  摘要：

  DOI：
• 作为产物：
  描述：

  、 己二酸 、 sodium acetate 以 溶剂黄146 为溶剂， 生成 monosodium adipate
  参考文献：
  名称：

  METHOD FOR PREPARING A SOLID FORM OF ACETIC ACID AND PRODUCTS THEREOF

  摘要：

  本发明揭示了一种制备固态乙酸的方法。该方法至少包括将固体酸和金属醋酸盐与溶剂混合形成浆料的步骤。经过一定时间后，回收固态乙酸。本发明还包括由上述方法生产的固态乙酸产品。还揭示了包括本发明的固态乙酸产品的配方。此外，还揭示了包括本发明配方的清洁系统。

  公开号：

  US20120208740A1

文献信息

• Processes for producing monoammonium adipate from fermentation broths containing diammonium adipate, monoammonium adipate and/or adipic acid, and conversion of monoammonium adipate to adipic acid
  申请人：BioAmber S.A.S.

  公开号：EP2383250A1

  公开（公告）日：2011-11-02

  A process for making MAA from a clarified DAA-containing fermentation broth includes (a) distilling the broth to form an overhead that includes water and ammonia, and a liquid bottoms that includes MAA, at least some DAA, and at least about 20 wt% water; (b) cooling the bottoms to a temperature sufficient to cause the bottoms to separate into a DAA-containing liquid portion in contact with a MAA-containing solid portion that is substantially free of DAA; (c) separating the solid portion from the liquid portion; and (d) recovering the solid portion.

  从含有澄清DAA的发酵液中制备MAA的过程包括：(a)蒸馏发酵液，形成包括水和氨的顶部，以及包括MAA、至少一些DAA和至少约20 wt%水的液体底部；(b)将底部冷却至足以使底部分离为与含有DAA的液体部分接触的MAA含有的几乎不含DAA的固体部分；(c)将固体部分与液体部分分离；和(d)回收固体部分。
• Process for making carboxyalkylates of branched alcohols
  申请人：Harichian Bijan

  公开号：US20060047168A1

  公开（公告）日：2006-03-02

  Process for carboxy-alkylation, particularly carboxymethylation, of branched alcohols includes the reaction of isoalcohols with potassium-t-butoxide or sodium-t-butoxide and with salt of halogenated alkanoic acid in the presence of the isoalcohol (starting alcohol) as the solvent. Produced are isoalcohol carboxy-alkylates (preferably, carboxymethylates) in excellent yields and purity.

  分支醇的羧甲基化过程，特别是羧甲基化过程，包括在异醇与叔丁醇钾或叔丁醇钠以及卤代烷酸盐的盐的存在下，在异醇（起始醇）作为溶剂的情况下反应。产生的是异醇羧基烷基化物（优选为羧甲基化物），收率和纯度均极高。
• PROCESSES FOR PRODUCING MONOAMMONIUM ADIPATE FROM FERMENTATION BROTHS CONTAINING DIAMMONIUM ADIPATE, MONOAMMONIUM ADIPATE AND/OR ADIPIC ACID, AND CONVERSION OF MONOAMMONIUM ADIPATE TO ADIPIC ACID
  申请人：Fruchey Olan S.

  公开号：US20110266133A1

  公开（公告）日：2011-11-03

  A process for making MAA from a clarified DAA-containing fermentation broth includes (a) distilling the broth to form an overhead that includes water and ammonia, and a liquid bottoms that includes MAA, at least some DAA, and at least about 20 wt % water; (b) cooling the bottoms to a temperature sufficient to cause the bottoms to separate into a DAA-containing liquid portion in contact with a MAA-containing solid portion that is substantially free of DAA; (c) separating the solid portion from the liquid portion; and (d) recovering the solid portion.

  从含有澄清DAA的发酵汁中制备MAA的过程包括(a)蒸馏汁以形成包括水和氨的顶部和包括MAA、至少一些DAA和至少约20重量％水的液体底部; (b)将底部冷却到足以使底部分离成为与MAA含量高且基本上不含DAA的固体部分接触的含有DAA的液体部分; (c)分离固体部分和液体部分; 和(d)回收固体部分。
• Method for preparing a solid form of acetic acid and products thereof
  申请人：Moore Ryan Giffin

  公开号：US08859482B2

  公开（公告）日：2014-10-14

  The present invention discloses a method of preparing a solid form of acetic acid. The method at least includes the steps of combining a solid acid and a metal acetate with a solvent to form a slurry. After a predetermined period of time, a solid form of acetic acid is recovered. The present invention also includes a solid product of acetic acid produced by the above-mentioned method. There is also disclosed a formulation including the solid product of acetic acid according to the present invention. Further, there is disclosed a cleaning system including the formulation according to the present invention.

  本发明揭示了一种制备乙酸固态形式的方法。该方法至少包括将固体酸和金属乙酸盐与溶剂混合形成浆状物的步骤。经过一定时间后，回收乙酸固态形式。本发明还包括由上述方法生产的乙酸固态产品。此外，还披露了包括本发明的乙酸固态产品的配方。进一步，还披露了包括本发明配方的清洁系统。
• Solid form of acetic acid and products thereof
  申请人：Moore Ryan Giffin

  公开号：US09068146B2

  公开（公告）日：2015-06-30

  The present invention discloses a method of preparing a solid form of acetic acid. The method at least includes the steps of combining a solid acid and a metal acetate with a solvent to form a slurry. After a predetermined period of time, a solid form of acetic acid is recovered. The present invention also includes a solid product of acetic acid produced by the above-mentioned method. There is also disclosed a formulation including the solid product of acetic acid according to the present invention. Further, there is disclosed a cleaning system including the formulation according to the present invention.

  本发明揭示了一种制备醋酸固体形式的方法。该方法至少包括将固体酸和金属醋酸盐与溶剂混合形成浆糊的步骤。经过一定时间后，回收醋酸固体形式。本发明还包括上述方法生产的醋酸固体产品。还公开了包括本发明的醋酸固体产品的配方。此外，还公开了包括本发明配方的清洁系统。