pyrromethene 567A | 163859-22-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: pyrromethene 567A
• 英文别名: 4,4-difluoro-1,3,5,7-tetramethyl-2,6-diethyl-8-pentyl-4-bora-3a,4a-diaza-s-indacene；PM 567A；5,11-Diethyl-2,2-difluoro-4,6,10,12-tetramethyl-8-pentyl-3-aza-1-azonia-2-boranuidatricyclo[7.3.0.03,7]dodeca-1(12),4,6,8,10-pentaene
• CAS: 163859-22-1
• 化学式: C₂₂H₃₃BF₂N₂
• 分子量: 374.325
• InChiKey: GASXPBBNHZUKEI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.41
• 重原子数：
  27
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.59
• 拓扑面积：
  7.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3-[2-(2-乙氧基乙氧基)乙氧基]丙-1-炔 、 pyrromethene 567A 在 乙基溴化镁 作用下， 以 四氢呋喃 为溶剂， 反应 2.0h， 以25.8%的产率得到5,5-bis(3-(2-(2-ethoxyethoxy)ethoxy)prop-1-yn-1-yl)-2,8-diethyl-1,3,7,9-tetramethyl-10-pentyl-5H-5l4-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium
  参考文献：
  名称：

  Nanoparticles via H-aggregation of amphiphilic BODIPY dyes

  摘要：

  We have synthesized wedge-shaped BODIPY dyes with hydrophilic chains and studied their aggregational behavior in THF-containing water by UV vis and photoluminescence spectroscopies, transmission electron microscopy, and dynamic light scattering. One of these dyes showed an aggregate derived from H-dimers and forms a high density nanoparticle in THF-containing water solution. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.04.120
• 作为产物：
  描述：

  2,4-二甲基-3-乙基吡咯 、 己酰氯 在 三氟化硼乙醚 、 三乙胺 作用下， 以 二氯甲烷 为溶剂， 以32.4%的产率得到pyrromethene 567A
  参考文献：
  名称：

  Nanoparticles via H-aggregation of amphiphilic BODIPY dyes

  摘要：

  We have synthesized wedge-shaped BODIPY dyes with hydrophilic chains and studied their aggregational behavior in THF-containing water by UV vis and photoluminescence spectroscopies, transmission electron microscopy, and dynamic light scattering. One of these dyes showed an aggregate derived from H-dimers and forms a high density nanoparticle in THF-containing water solution. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.04.120

文献信息

• Nanoparticles via H-aggregation of amphiphilic BODIPY dyes
  作者：Yuichiro Tokoro、Atsushi Nagai、Yoshiki Chujo

  DOI：10.1016/j.tetlet.2010.04.120

  日期：2010.6

  We have synthesized wedge-shaped BODIPY dyes with hydrophilic chains and studied their aggregational behavior in THF-containing water by UV vis and photoluminescence spectroscopies, transmission electron microscopy, and dynamic light scattering. One of these dyes showed an aggregate derived from H-dimers and forms a high density nanoparticle in THF-containing water solution. (C) 2010 Elsevier Ltd. All rights reserved.