Vinyl-(2-phenyl-thio-ethyl)-ether | 6613-39-4

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: Vinyl-(2-phenyl-thio-ethyl)-ether
• 英文别名: 2-(Phenylthio)ethyl vinyl ether；2-ethenoxyethylsulfanylbenzene
• CAS: 6613-39-4
• 化学式: C₁₀H₁₂OS
• 分子量: 180.271
• InChiKey: LBVVNECDYULMAG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  34.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Vinyl-(2-phenyl-thio-ethyl)-ether 在 potassium fluoride 、 对甲苯磺酸 、 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 氯仿 、 甲苯 为溶剂， 反应 2.08h， 生成 methyl (2RS,4SR)-4-<(5,5-dimethyl-1,3-dioxan-2-yl)methyl>-3,4-dihydro-2-<2-(phenylthio)ethoxy>-2H-pyran-5-carboxylate
  参考文献：
  名称：

  Tietze, Lutz F.; Meier, Heinrich; Nutt, Heinrich, Chemische Berichte, 1989, vol. 122, p. 643 - 650

  摘要：

  DOI：
• 作为产物：
  描述：

  苯硫酚 、 2-氯乙基乙烯基醚 在 sodium hydroxide 、 四丁基溴化铵 作用下， 以81%的产率得到Vinyl-(2-phenyl-thio-ethyl)-ether
  参考文献：
  名称：

  Synthesis of bis(aryloxyethyl) vinyl ethers via phase-transfer-catalyzed nucleophilic displacement on 2-chloroethyl vinyl ether

  摘要：

  DOI：

  10.1021/jo00151a013

文献信息

• Nucleosides. Part LXIII. Acetals as new 2?-O-protecting functions for the synthesis of oligoribonucleotides: Synthesis of uridine building blocks and evaluation of their relative acid stability
  作者：Stefan Matysiak、Hans-Peter Fitznar、Ralf Schnell、Wolfgang Pfleiderer

  DOI：10.1002/hlca.19980810557

  日期：——

  A broad variety of new acyclic vinyl ethers (see 6–41) have been synthesized via the vinyl-interchange reaction of ethyl vinyl ether at room temperature using mercury(II) trifluoroacetate as a highly efficient catalyst. The appropriate vinyl ethers were reacted under acidic conditions with 3′,5′-O-silyl-protected uridine 42 to the corresponding 2′-O-(1-alkoxyethyl) derivatives 43–83 which gave, on

  各种各样的新的无环乙烯基醚（见6 - 41）已被合成通过在室温下的乙基乙烯基醚的乙烯基-交换反应使用汞（II）三氟乙酸盐作为一种高效催化剂。适当的乙烯基醚是在酸性条件下反应，用3'，5'- ø -甲硅烷保护的尿苷42到相应的2'- ø - （1-烷氧基乙基）衍生物43 - 83这给了，对于F的脱甲硅烷基-离子，高产率的尿苷2'- O-缩醛衍生物84 – 124。使用TLC和HPLC技术确定了新合成化合物在酸性和碱性条件下的相对稳定性。受保护的保护基为寡核糖核苷酸合成提供了最佳性能。有趣的是，β-取代的乙基型的非常酸稳定缩醛118 - 121和123可以由β消去过程中提供了一系列潜在的合成值的碱不稳定的乙缩醛的裂解。
• Atavin,A.S. et al., Journal of Organic Chemistry USSR (English Translation), 1967, vol. 3, p. 1368 - 1371
  作者：Atavin,A.S. et al.

  DOI：——

  日期：——
• Resin-containing composition, liquid application method and liquid application apparatus
  申请人：Yamagishi Keiko

  公开号：US20060281853A1

  公开（公告）日：2006-12-14

  Disclosed herein is a resin-containing composition comprising a solvent, a coloring material insoluble in the solvent and a block polymer compound having a repeating structural unit represented by the following general formula (1): wherein X is a polyalkenyl group which may be substituted, A is a linear or branched alkylene group having 1 to 15 carbon atoms, which may be substituted, at least one CH 2 of the alkylene group may be substituted by O, m is an integer of from 0 to 30, the respective A groups may be different from each other when m is plural, Y is at least one of S, O and Se with the proviso that Y contains at least one S and that S, O and Se are each linked via a single bond, and R is a linear or branched alkyl group which may be substituted, an aromatic ring which may be substituted, or a structure in which at most 3 fused rings or aromatic rings, which may be substituted, are bonded via a single bond.
• US7754783B2
  申请人：——

  公开号：US7754783B2

  公开（公告）日：2010-07-13
• Synthesis of bis(aryloxyethyl) vinyl ethers via phase-transfer-catalyzed nucleophilic displacement on 2-chloroethyl vinyl ether
  作者：R. R. Gallucci、R. C. Going

  DOI：10.1021/jo00151a013

  日期：1983.2