2-iodoethyl acrylate | 44653-97-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-iodoethyl acrylate
• 英文别名: 2-iodoethyl prop-2-enoate
• CAS: 44653-97-6
• 化学式: C₅H₇IO₂
• 分子量: 226.014
• InChiKey: LLBXAYYHEGEQCL-UHFFFAOYSA-N

物化性质

• 沸点：
  210.5±23.0 °C(Predicted)
• 密度：
  1.759±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  8
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,1-bis(3-cyclohexyl-4-hydroxycyclohexyl)cyclohexane 、 2-iodoethyl acrylate 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 反应 10.0h， 以38%的产率得到
  参考文献：
  名称：

  ビニル誘導体、およびこれの使用

  摘要：

  提供新型的乙烯基诱导体以及含有该化合物的组成物。提供一种含碳膜形成组成物，该组成物具有耐高温性能并能形成均一的膜，以及使用该组成物制备含碳膜的方法。此外，还提供了使用上述组成物和方法制备器件的方法。解决方案为提供新型的乙烯基诱导体及其使用，以及含有该化合物的组成物、含碳膜的制备方法和半导体的制备方法。图2。

  公开号：

  JP2018140972A
• 作为产物：
  描述：

  丙烯酸氯乙酯 在 sodium iodide 作用下， 以 丙酮 为溶剂， 反应 22.0h， 以79%的产率得到2-iodoethyl acrylate
  参考文献：
  名称：

  Intramolecular photochemical reactions of 4-(.omega.-alkenyloxy)-6-methyl-2-pyrones having an alkoxycarbonyl group at the olefinic carbon chain

  摘要：

  Photochemical reactions of 4-(omega-alkenyloxy)-6-methyl-2-pyrones 4-8 were investigated. Photosensitized reactions of 2-pyrones 4-6 gave intramolecular [2 + 2] cycloadducts 14-16 as oxatricyclic lactones, site-, regio- and stereospecifically, but 7 and 8 gave no products. On the other hand, direct irradiations of 4 and 5 afforded cyclobutenecarboxylic acids 19 and 20, respectively. The intramolecular cycloaddition mechanism was also explained from the excited state of 2-pyrone calculated by means of the MNDO-CI method.

  DOI：

  10.1021/jo00025a035

文献信息

• Cu-catalyzed carboboration of acetylene with Michael acceptors
  作者：Tairan Cheng、Boxiang Liu、Rui Wu、Shifa Zhu

  DOI：10.1039/d2sc02306g

  日期：——

  A copper-catalyzed three-component carboboration of acetylene with B2Pin2 and Michael acceptors is reported. In this reaction, a cheap and abundant C2 chemical feedstock, acetylene, was used as a starting material to afford cis-alkenyl boronates bearing a homoallylic carbonyl group. The reaction was robust and could be reliably performed on the molar scale. Furthermore, the resulting cis-alkenyl boronates

  报道了铜催化乙炔与 B 2 Pin 2和 Michael 受体的三组分碳硼化反应。在该反应中，使用廉价且丰富的C2化学原料乙炔作为起始原料，得到带有同烯丙基羰基的顺式烯基硼酸酯。该反应很稳健，并且可以在摩尔规模上可靠地进行。此外，所得顺式烯基硼酸酯可以轻松转化为多种功能化分子。
• Extraordinary aspects of bromo-functionalized multi-walled carbon nanotubes as initiator for polymerization of ionic liquid monomers
  作者：Yu-Hsun Chang、Pei-Yi Lin、Ming-Sung Wu、King-Fu Lin

  DOI：10.1016/j.polymer.2012.03.020

  日期：2012.4

  Two ionic liquid monomers, 1-(2-acryloyloxy-ethyl)-3-methyl-imidazol-1-ium iodide (AMImI) and 1-(2-acryloyloxy-ethyl)-3-methyl-benzoimidazol-1-ium iodide (AMBImI), were synthesized and polymerized through atom transfer radical polymerization (ATRP). Poly(AMImI)-grafted multi-walled carbon nanotubes (denoted as MWCNT-poly(AMImI)) could also be fabricated through "grafting from" method of ATRP using bromo-functionalized MWCNT (denoted as MWCNT-Br) as initiator but MWCNT-poly(AMBImI) could not. Based on the thermogravimetric analysis and high resolution transmission electron microscopy, AMBImI monomer has encapsulated the MWCNT-Br probably through the pi-pi: and cation-pi interactions invalidating the initiation capability of MWCNT-Br. Besides, by mixing AMBImI with MWCNT-Br directly at room temperature, the MWCNT-Br was coated with a thin layer of AMBImI, whereas MWCNT-Br could not physisorb AMImI. Both MWCNT-poly(AMImI) and AMBImI-encapsulated MWCNT were dispersed well in 1-methyl-3-propylimidazolium iodide ionic liquid. (C) 2012 Elsevier Ltd. All rights reserved.