13-(thiophen-3-yl)-2,5,8,11-tetraoxatridecane | 458552-56-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: 13-(thiophen-3-yl)-2,5,8,11-tetraoxatridecane
• 英文别名: 3-(3,6,9,12-tetraoxatridecanyl)thiophene；3-[2-[2-[2-(2-Methoxyethoxy)ethoxy]ethoxy]ethyl]thiophene；3-[2-[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]ethyl]thiophene
• CAS: 458552-56-2
• 化学式: C₁₃H₂₂O₄S
• 分子量: 274.381
• InChiKey: WSXPUPJZCSVUQL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  18
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  65.2
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  13-(thiophen-3-yl)-2,5,8,11-tetraoxatridecane 在 sodium hydride 、 4-羟乙基哌嗪乙磺酸 、 三氯氧磷 作用下， 以 四氢呋喃 、 水 、 乙腈 为溶剂， 生成
  参考文献：
  名称：

  [EN] A REUSABLE END-CAPPED BIPYRIDINE COMPOUND USEFUL FOR SELECTIVE DETECTION OF CYANIDE ANIONS AND PROCESS FOR PREPARATION THEREOF
  [FR] COMPOSE DE BIPYRIDINE COIFFE A L'EXTREMITE REUTILISABLE SERVANT A LA DETECTION SELECTIVE D'ANIONS DE CYANURES ET PROCEDE DE PREPARATION ASSOCIE

  摘要：

  本发明描述了一种具有式（A）的端基化双吡啶化合物和具有式（B）的锌配合物的开发。式（1）的测定可以通过监测荧光变化来用于估计和定量锌离子的数量。式（1）的测定可用于成像和检测MCF7细胞系中的Zn2离子。式（2）和（4）的锌配合物可用作氰离子的荧光传感器，使用分析物替换协议。式（2）的测定仅对氰离子选择性，即使存在其他竞争性离子。具有明亮绿色固态发射的式（3）的测定用于制备式（4）。式（4）的橙色荧光粉末用于选择性检测水溶液中的CN离子。

  公开号：

  WO2011033531A1
• 作为产物：
  描述：

  噻吩-3-乙醇 、 对甲苯磺酸三缩乙二醇单甲醚酯 在 potassium tert-butylate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 13-(thiophen-3-yl)-2,5,8,11-tetraoxatridecane
  参考文献：
  名称：

  水溶性，AIE活性聚电解质，用于小鼠神经母细胞瘤Neuro-2A细胞的常规和荧光寿命成像

  摘要：

  合成并表征了骨架中含有四苯基乙烯单元的新型共轭聚电解质。这种聚电解质是水溶性的，并表现出聚集诱导发射（AIE）行为。它具有生物相容性，可直接用于小鼠神经母细胞瘤Neuro-2A细胞的常规和荧光寿命成像，提供有用的细胞形态学信息以及细胞内聚集或运动信息。©2018 Wiley Periodicals，Inc.J.Polym。科学，A部分：Polym。化学 2018，56，672-680

  DOI：

  10.1002/pola.28943

文献信息

• Polymeric vesicles with a hydrophobic interior formed by a thiophene-based all-conjugated amphiphilic diblock copolymer
  作者：Jinseck Kim、In Young Song、Taiho Park

  DOI：10.1039/c1cc10700c

  日期：——

  The diblock copolymer, BP26, assembled into polymeric vesicles with double layers that formed a hydrophobic crystalline interior and a hydrophilic amorphous exterior in methanol, a selective solvent for the PEGT block. The vesicles were demonstrated to encapsulate a hydrophobic guest polyfluorene (PF).

  二嵌段共聚物BP26组装成双层聚合物囊泡，在甲醇（PEGT嵌段的选择性溶剂）中形成疏水性结晶内部和亲水性无定形外部。囊泡被证明可以包裹疏水性客体聚芴（PF）。
• CONDUCTIVE POLYMER FOR SOLID ELECTROLYTIC CAPACITOR
  申请人：Solvay USA Inc.

  公开号：EP2855554A2

  公开（公告）日：2015-04-08
• CONDUCTIVE POLYMER FOR SOLID ELECTROLYTE CAPACITOR
  申请人：Plextronics, Inc.

  公开号：US20140014881A1

  公开（公告）日：2014-01-16

  [Problem] To provide a conductive polymer for solid electrolyte capacitor having outstanding solubility in solvents or dispersibility in solvents and which can produce a capacitor having outstanding capacitor characteristics in high-temperature environments. [Means Used to Resolve the Problem] A conductive polymer (A) for solid electrolyte capacitor containing substituted polythiophene (P) having thiophene repeating units (D) substituted by a least one type of group (s) selected from a group made up of a polyether group (a) indicated in general formula (1); an alkoxy group (b) having 1 to 15 carbon atoms; an alkoxy alkyl group (c) indicated in general formula (2); an alkyl group (d) having 1 to 15 carbon atoms; and a group (e) indicated in general formula (3); as well as thiophene repeating units (E) wherein the hydrogen atoms at position 3 and position 4 on the thiophene ring have been substituted by group (s) and sulfo group (—SO 3 H) (f). —(OR 1 ) k —OR 2 (1) —R 3 —OR 4 (2) —R 5 —(OR 6 ) m —OR 7 (3)
• US9224540B2
  申请人：——

  公开号：US9224540B2

  公开（公告）日：2015-12-29
• [EN] CONDUCTIVE POLYMER FOR SOLID ELECTROLYTIC CAPACITOR<br/>[FR] POLYMÈRE CONDUCTEUR POUR CONDENSATEUR ÉLECTROLYTIQUE SOLIDE
  申请人：PLEXTRONICS INC

  公开号：WO2013181165A2

  公开（公告）日：2013-12-05

  [Problem] To provide a conductive polymer for solid electrolyte capacitor having outstanding solubility in solvents or dispersibility in solvents and which can produce a capacitor having outstanding capacitor characteristics in high-temperature environments. [Means Used to Resolve the Problem] A conductive polymer (A) for solid electrolyte capacitor containing substituted polythiophene (P) having thiophene repeating units (D) substituted by a least one type of group (s) selected from a group made up of a polyether group (a) indicated in general formula (1); an alkoxy group (b) having 1 to 15 carbon atoms; an alkoxy alkyl group (c) indicated in general formula (2); an alkyl group (d) having 1 to 15 carbon atoms; and a group (e) indicated in general formula (3); as well as thiophene repeating units (E) wherein the hydrogen atoms at position 3 and position 4 on the thiophene ring have been substituted by group (s) and sulfo group (-SO3H) (f).