10-Butoxy-12-oxapentacyclo[11.8.0.02,11.03,8.015,20]henicosa-1(21),2(11),3,5,7,9,13,15,17,19-decaene | 1578258-74-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 萘并呋喃类
• 英文名称: 10-Butoxy-12-oxapentacyclo[11.8.0.02,11.03,8.015,20]henicosa-1(21),2(11),3,5,7,9,13,15,17,19-decaene
• 英文别名: 10-butoxy-12-oxapentacyclo[11.8.0.02,11.03,8.015,20]henicosa-1(21),2(11),3,5,7,9,13,15,17,19-decaene
• CAS: 1578258-74-8
• 化学式: C₂₄H₂₀O₂
• 分子量: 340.422
• InChiKey: TWBVPMDLGBYURG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  26
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  22.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2,3-二羟基萘 在 甲烷磺酸 、 potassium carbonate 作用下， 以 邻二甲苯 、 N,N-二甲基甲酰胺 为溶剂， 反应 39.5h， 生成 10-Butoxy-12-oxapentacyclo[11.8.0.02,11.03,8.015,20]henicosa-1(21),2(11),3,5,7,9,13,15,17,19-decaene
  参考文献：
  名称：

  Synthesis and Properties of Butterfly-Shaped Expanded Naphthofuran Derivatives

  摘要：

  The construction of dinaphtho[2,1-b;2',3'-d]furan-6-ol was developed via a dehydration reaction involving two molecules of 2,3-dihydroxynaphthalene in the presence of a strong acid. Starting from the dinaphthofuran, a variety of butterfly shaped derivatives were synthesized. The optical properties of these compounds were investigated with special attention to the dihedral angle formed by adjacent dinaphthofuran rings and/or the sizes of the fused aromatic rings.

  DOI：

  10.1021/jo500085a

文献信息

• Synthesis and Properties of Butterfly-Shaped Expanded Naphthofuran Derivatives
  作者：Kentaro Nakanishi、Takahiro Sasamori、Kouji Kuramochi、Norihiro Tokitoh、Takeo Kawabata、Kazunori Tsubaki

  DOI：10.1021/jo500085a

  日期：2014.3.21

  The construction of dinaphtho[2,1-b;2',3'-d]furan-6-ol was developed via a dehydration reaction involving two molecules of 2,3-dihydroxynaphthalene in the presence of a strong acid. Starting from the dinaphthofuran, a variety of butterfly shaped derivatives were synthesized. The optical properties of these compounds were investigated with special attention to the dihedral angle formed by adjacent dinaphthofuran rings and/or the sizes of the fused aromatic rings.