9-[[3,5-Bis[(10-hexylanthracen-9-yl)methoxy]phenoxy]methyl]-10-(chloromethyl)anthracene | 885481-32-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 9-[[3,5-Bis[(10-hexylanthracen-9-yl)methoxy]phenoxy]methyl]-10-(chloromethyl)anthracene
• 英文别名: 9-[[3,5-bis[(10-hexylanthracen-9-yl)methoxy]phenoxy]methyl]-10-(chloromethyl)anthracene
• CAS: 885481-32-3
• 化学式: C₆₄H₆₁ClO₃
• 分子量: 913.64
• InChiKey: NSMMKUPABBGVOM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  20.1
• 重原子数：
  68
• 可旋转键数：
  20
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  9-[[3,5-Bis[(10-hexylanthracen-9-yl)methoxy]phenoxy]methyl]-10-(chloromethyl)anthracene 、 (3,5-Dihydroxyphenyl)methyl benzoate 在 18-冠醚-6 、 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 4.0h， 以75%的产率得到[3,5-Bis[[10-[[3,5-bis[(10-hexylanthracen-9-yl)methoxy]phenoxy]methyl]anthracen-9-yl]methoxy]phenyl]methyl benzoate
  参考文献：
  名称：

  Construction of divergent anthracene arrays within dendritic frameworks

  摘要：

  This publication presents simple methodologies for construction of divergent anthracene arrays either within structural interior or at peripheral positions of dendritic frameworks. The synthetic approaches employed multiple coupling reactions between two types of 10-functionalized 9-anthryl chlorides and two types of polyphenolic linkers, resulting in four types of dendritic architectures. Successful implementation of the syntheses was confirmed by a range of spectroscopies along with elemental analyses and size exclusion chromatography studies. The resulting dendritic molecules showed a range Of Solubilities in chloroform fairly affected by the dendritic backbone structures. Fluorescence spectroscopic experiments of the multichromophoric dendritic systems indicated pronounced energy delocalization functionalities via an energy migration within the branched molecular frameworks as expressed in reduced fluorescence quantum yields and complex emission decay profiles. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2006.01.024
• 作为产物：
  描述：

  5-hydroxy-1,3-phenylene dibenzoate 在 lithium chloride 4-二甲氨基吡啶 、 18-冠醚-6 、 sodium methylate 、 potassium carbonate 、 甲基磺酰氯 、 正丁胺 、 三乙胺 作用下， 以 四氢呋喃 、 甲醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 50.0h， 生成 9-[[3,5-Bis[(10-hexylanthracen-9-yl)methoxy]phenoxy]methyl]-10-(chloromethyl)anthracene
  参考文献：
  名称：

  Construction of divergent anthracene arrays within dendritic frameworks

  摘要：

  This publication presents simple methodologies for construction of divergent anthracene arrays either within structural interior or at peripheral positions of dendritic frameworks. The synthetic approaches employed multiple coupling reactions between two types of 10-functionalized 9-anthryl chlorides and two types of polyphenolic linkers, resulting in four types of dendritic architectures. Successful implementation of the syntheses was confirmed by a range of spectroscopies along with elemental analyses and size exclusion chromatography studies. The resulting dendritic molecules showed a range Of Solubilities in chloroform fairly affected by the dendritic backbone structures. Fluorescence spectroscopic experiments of the multichromophoric dendritic systems indicated pronounced energy delocalization functionalities via an energy migration within the branched molecular frameworks as expressed in reduced fluorescence quantum yields and complex emission decay profiles. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2006.01.024

文献信息

• Construction of divergent anthracene arrays within dendritic frameworks
  作者：Masaki Takahashi、Hironao Morimoto、Yousuke Suzuki、Mitsuji Yamashita、Hideki Kawai、Yoshihisa Sei、Kentaro Yamaguchi

  DOI：10.1016/j.tet.2006.01.024

  日期：2006.3

  This publication presents simple methodologies for construction of divergent anthracene arrays either within structural interior or at peripheral positions of dendritic frameworks. The synthetic approaches employed multiple coupling reactions between two types of 10-functionalized 9-anthryl chlorides and two types of polyphenolic linkers, resulting in four types of dendritic architectures. Successful implementation of the syntheses was confirmed by a range of spectroscopies along with elemental analyses and size exclusion chromatography studies. The resulting dendritic molecules showed a range Of Solubilities in chloroform fairly affected by the dendritic backbone structures. Fluorescence spectroscopic experiments of the multichromophoric dendritic systems indicated pronounced energy delocalization functionalities via an energy migration within the branched molecular frameworks as expressed in reduced fluorescence quantum yields and complex emission decay profiles. (c) 2006 Elsevier Ltd. All rights reserved.