4-丁基-1-环己烯-1-羧酸 | 70928-93-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 4-丁基-1-环己烯-1-羧酸
• 英文名称: 4-butyl-1-cylohexene-1-carboxylic acid
• 英文别名: 4-Butylcyclohexene-1-carboxylic acid
• CAS: 70928-93-7
• 化学式: C₁₁H₁₈O₂
• 分子量: 182.263
• InChiKey: ANCPXFBWTKRDEY-UHFFFAOYSA-N

物化性质

• 熔点：
  82-117 °C (polymorph)
• 沸点：
  296.8±19.0 °C(Predicted)
• 密度：
  1.009±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-丁基-1-环己烯-1-羧酸 、 4-正丁氧基苯酚 在 吡啶 、 氯化亚砜 作用下， 生成 4-Butoxyphenyl 4-butylcyclohex-1-ene-1-carboxylate
  参考文献：
  名称：

  Bezborodov, V. S.; Konovalov, V. A.; Lapanik, V. I., Journal of Organic Chemistry USSR (English Translation), 1988, vol. 24, # 3, p. 551 - 554

  摘要：

  DOI：
• 作为产物：
  描述：

  对丁基环已烷甲酸 生成 4-丁基-1-环己烯-1-羧酸
  参考文献：
  名称：

  DE2847639

  摘要：

  公开号：

文献信息

• Reactive polymer-supporting porous film for battery separator and use thereof
  申请人：Ichikawa Tomoaki

  公开号：US20090098464A1

  公开（公告）日：2009-04-16

  The invention provides a reactive polymer-supporting porous film for use as a battery separator which comprises a porous substrate film and a partially crosslinked reactive polymer supported on the porous substrate film, the partially crosslinked reactive polymer being obtained by the reaction of a crosslinkable polymer having at least one reactive group selected from the group consisting of 3-oxetanyl group and epoxy group in the molecule with a monocarboxylic acid. The invention further provides a method of manufacturing a battery which comprises layering electrodes on the reactive polymer-supporting porous film to obtain an electrode/reactive polymer-supporting porous film layered body; placing the electrode/reactive polymer-supporting porous film layered body in a battery container; introducing an electrolytic solution containing a cationic polymerization catalyst into the battery container so that at least a portion of the reactive polymer is swollen or dissolved in the electrolytic solution at least in the vicinity of the interface of the porous film and the electrodes and cationically polymerized so that the electrodes are bonded to the porous film.

  本发明提供了一种反应性聚合物支撑多孔膜，用作电池隔膜，包括多孔基底膜和部分交联的反应性聚合物，所述部分交联的反应性聚合物是通过将至少具有3-氧杂环基团和环氧基团之一的反应性基团的交联聚合物与单羧酸反应而获得的。本发明还提供了一种制造电池的方法，包括将电极层覆盖在反应性聚合物支撑的多孔膜上，以获得电极/反应性聚合物支撑的多孔膜层状体；将电极/反应性聚合物支撑的多孔膜层状体放置在电池容器中；将含有阳离子聚合催化剂的电解液引入电池容器中，使反应性聚合物至少在多孔膜和电极的界面附近在电解液中肿胀或溶解，并通过阳离子聚合使电极与多孔膜结合。
• Crystalline polypropylene resin composition and amide compounds
  申请人：NEW JAPAN CHEMICAL CO.,LTD.

  公开号：EP0557721A2

  公开（公告）日：1993-09-01

  Disclosed are a crystalline polypropylene resin composition comprising a crystalline polyproplylene resin and a β-nucleating agent, and a method of increasing the proportion of β-form crystals in a crystalline polypropylene resin molding comprising molding the composition, the β-nucleating agent being a diamide compound.

  本发明公开了一种结晶聚丙烯树脂组合物，该组合物由结晶聚丙烯树脂和 β 成核剂组成；还公开了一种增加结晶聚丙烯树脂模塑中 β 形晶体比例的方法，该方法包括模塑该组合物，β 成核剂为二酰胺化合物。
• Porous stretched article of polypropylene-based resin and process for its preparation
  申请人：NEW JAPAN CHEMICAL CO.,LTD.

  公开号：EP0632095A2

  公开（公告）日：1995-01-04

  Disclosed are a process for producing a porous stretched article of β-crystalline polypropylene-based resin, the process comprising the steps of crystallizing a melt of a polypropylene-based resin composition at a temperature of 15 to 140°C to form a solidified product containing β-form crystals and stretching the resulting solidified product at a temprature which is higher than 20 °C but lower than the melting point of the β-form crystals in said solidified product, the polypropylene-based resin composition comprising a polypropylene-based resin and 0.0001 to 5 parts by weight, per 100 parts by weight of the polypropylene-based resin, of at least one specific amide compound; and a porous stretched article produced by the process.

  本发明公开了一种用β-结晶聚丙烯基树脂生产多孔拉伸制品的工艺，该工艺包括以下步骤：在15至140℃的温度下使聚丙烯基树脂组合物的熔体结晶，形成含有β-结晶的固化物，并在高于20℃但低于所述固化物中β-结晶的熔点的温度下拉伸所得固化物，所述聚丙烯基树脂组合物包括聚丙烯基树脂和0.0001至5份（按每100份聚丙烯基树脂的重量计）的至少一种特定酰胺化合物；以及由该工艺生产的多孔拉伸制品。
• PROPYLENE-ETHYLENE COPOLYMER COMPOSITIONS AND PROCESS FOR THE PRODUCTION THEREOF
  申请人：CHISSO CORPORATION

  公开号：EP0790262A1

  公开（公告）日：1997-08-20

  A propylene-ethylene copolymer composition is obtained which has a good moldability and is excellent in the balance of rigidity, toughness, and impact-strength. A propylene-ethylene copolymer composition having a melt flow rate of 10 to 300 g/10 minutes and obtained by producing 60 to 95 % by weight, based on the weight of whole polymer, of a propylene polymer having a melt flow rate (ASTM D-1238) in the range of 100 to 1,000 g/10 minutes and having a ratio (Cf) of integrated values of the propylene polymer dissolved in o-dichlorobenzene at a temperature of lower than 112°C, and a temperature of 112°C or higher, respectively, which is an index of the stereoregurality in molecules and molecular weight distribution, when the amounts of the propylene polymer dissolved therein at each of the temperatures were determined by raising the temperature of the o-dichlorobenzene continuously or stepwise, of 0.5 or less, by carrying out polymerization of propylene in the presence of a highly stereoregular catalyst and hydrogen in a polymerization step (I), and then producing 5 to 40 % by weight, based on the weight of whole polymer, of an ethylene-propylene copolymer by feeding ethylene and propylene to the propylene polymer produced in the polymerization step (I) to react so that the content of ethylene becomes 30 to 80 % by weight, in a polymerization step (II); and a propylene-ethylene copolymer composition comprising the composition mentioned above and a α-crystal and/or β-crystal nucleator added therewith.

  一种丙烯-乙烯共聚物组合物具有良好的成型性，并且在刚性、韧性和冲击强度的平衡方面表现优异。 一种熔体流动速率为 10 至 300 克/10 分钟的丙烯-乙烯共聚物组合物，通过以下方法获得 以整个聚合物的重量为基准，生产 60% 至 95% 重量百分比的丙烯聚合物，其熔体流动速率（ASTM D-1238）在 100 至 1,000 克/10 分钟范围内，在温度低于 112°C、和 112°C 或更高温度下溶解在邻二氯苯中的丙烯聚合物的综合值之比 (Cf)，这分别是分子立体性和分子量分布的指标，当通过连续或逐步提高邻二氯苯的温度 0.5 或更低，在聚合步骤 (I) 中，在高度立体配位催化剂和氢的存在下进行丙烯聚合，然后 在聚合步骤(II)中，通过向聚合步骤(I)中生成的丙烯聚合物中加入乙烯和丙烯进行反应，使乙烯的含量达到 30% 至 80%（以整个聚合物的重量计），生成 5% 至 40%（以重量计）的乙烯-丙烯共聚物；以及丙烯-乙烯共聚物组合物，该组合物包括上述组合物和加入其中的 α 结晶和/或 β 结晶成核剂。
• PREFOAMED PARTICLES OF POLYPROPYLENE RESIN AND PROCESS FOR PRODUCING THE SAME
  申请人：KANEGAFUCHI KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0790275A1

  公开（公告）日：1997-08-20

  Heat temperature at the expansion molding of a finished expanded article is decreased by lowering the melting peak temperature of the pre-expanded particles of a polypropylene resin. Comprising the polypropylene resin and a β-crystalline-nucleating agent, the percentage of the β-form in the whole crystalline region is 5 to 100 parts by weight.

  通过降低聚丙烯树脂预膨化颗粒的熔融峰值温度，可降低成品膨化物膨化成型时的热温度。由聚丙烯树脂和β-结晶成核剂组成，β-形式在整个结晶区域中的百分比为 5 至 100 重量份。