3(E),5(E)-octadien-1-ol | 10573-34-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 3(E),5(E)-octadien-1-ol
• 英文别名: trans,trans-Octadien-(3,5)-ol-(1)；octa-3t,5t-dien-1-ol；(3E,5Z)-3,5-Octadien-1-ol；(3E,5E)-octa-3,5-dien-1-ol
• CAS: 10573-34-9
• 化学式: C₈H₁₄O
• 分子量: 126.199
• InChiKey: ZVVFQUSSYQVVJC-VNKDHWASSA-N

物化性质

• 沸点：
  68-72 °C(Press: 4 Torr)
• 密度：
  0.868±0.06 g/cm3(Predicted)
• 保留指数：
  1742

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  9
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3(E),5(E)-octadien-1-ol 在 三氟甲磺酰胺 、 二甲基氯化铝 、 三乙胺 作用下， 以 正己烷 、 二氯甲烷 、 1,2-二氯乙烷 为溶剂， 反应 5.0h， 生成 (4aS*,7S*,8aR*)-7-ethyl-3,4,4a,7,8,8a-hexahydroisochromen-1-one
  参考文献：
  名称：

  Intramolecular Diels−Alder Reactions of Ester-Tethered 1,7,9-Decatrienoates:  Bis[chloro(methyl)aluminum]trifluoromethanesulfonamide as a Catalyst

  摘要：

  The intramolecular Diels-Alder reaction of 1,7,9-decatrienoate derivative with an ester tether is efficiently catalyzed by the bidentate Lewis acid,/bis-aluminated trifluoromethanesulfonamide.

  DOI：

  10.1021/ol026963f
• 作为产物：
  描述：

  3,5-octadiyn-1-ol 在 lithium aluminium tetrahydride 作用下， 以 乙二醇二甲醚 为溶剂， 以90%的产率得到3(E),5(E)-octadien-1-ol
  参考文献：
  名称：

  Iwamoto, Minoru; Tagaki, Yoshikazu; Kogami, Kunio, Agricultural and Biological Chemistry, 1983, vol. 47, # 1, p. 117 - 120

  摘要：

  DOI：

文献信息

• 13-Acetoxy-heptadecadien-(8, 10)-ol-(1), Octadien-(3, 5)-ol-(1)-Isomere und verwandte Verbindungen
  作者：R. Riemschneider、G. Kasang、C. Böhme

  DOI：10.1007/bf01185898

  日期：1965.11
• JPS5424805A
  申请人：——

  公开号：JPS5424805A

  公开（公告）日：1979-02-24
• JPS61111666A
  申请人：——

  公开号：JPS61111666A

  公开（公告）日：1986-05-29
• INHIBITOR FOR TOBACCO AXILLARY BUD GROWTH AND METHOD FOR INHIBITING TOBACCO AXILLARY BUD GROWTH
  申请人：Tanaka Motoki

  公开号：US20130157857A1

  公开（公告）日：2013-06-20

  The present invention relates to an inhibitor for tobacco axillary bud growth, the inhibitor comprising, as an active ingredient, one or more kinds of very-long chain fatty acid synthesis inhibitors such as a chloroacetamide-based herbicide, fentrazamide, cafenstrole or indanofan; an inhibitor for tobacco axillary bud growth, the inhibitor comprising the aforesaid very-long chain fatty acid synthesis inhibitor together with clorthal-dimethyl or an aliphatic alcohol having 6 to 20 carbon atoms; and a method for inhibiting tobacco axillary bud growth which comprises applying the inhibitor for tobacco axillary bud growth. The inhibitor for tobacco axillary bud growth of the present invention shows sustained drug efficacy at a low concentration, induces neither chemical injury nor disease, and can contribute to the improvement in labor productivity.
• TOBACCO AXILLARY BUD INHIBITOR AND TOBACCO AXILLARY BUD-INHIBITING METHOD
  申请人：Tanaka Motoki

  公开号：US20140121112A1

  公开（公告）日：2014-05-01

  The present invention relates to an inhibitor for tobacco axillary bud growth, the inhibitor comprising one or more cell division inhibitors selected from the group consisting of pyridine-based compounds and benzamide-based compounds. This inhibitor for tobacco axillary bud growth has excellent sustainability of effect at low concentration, does not cause chemical damage and disease, and can ensure an improvement in labor productivity. An aliphatic alcohol having 6 to 20 carbon atoms is furthermore combined with the cell division inhibitors selected from pyridine-based compounds and benzamide-based compounds to thereby synergistically enhance the effect of inhibiting the emergence and growth of tobacco axillary buds.