5,23-Dimethylhexacyclo[12.12.0.02,7.08,13.015,20.021,26]hexacosa-1(14),2(7),3,5,8,10,12,15,17,19,21(26),22,24-tridecaene | 1274702-44-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 5,23-Dimethylhexacyclo[12.12.0.02,7.08,13.015,20.021,26]hexacosa-1(14),2(7),3,5,8,10,12,15,17,19,21(26),22,24-tridecaene
• 英文别名: 5,23-dimethylhexacyclo[12.12.0.02,7.08,13.015,20.021,26]hexacosa-1(14),2(7),3,5,8,10,12,15,17,19,21(26),22,24-tridecaene
• CAS: 1274702-44-1
• 化学式: C₂₈H₂₀
• 分子量: 356.467
• InChiKey: IKDLUSNJXCTTOK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  28
• 可旋转键数：
  0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  [1,1-二苯基-2,2-二(4-甲基苯基]乙烯 在 甲烷磺酸 、 2,3-二氯-5,6-二氰基-1,4-苯醌 作用下， 以 二氯甲烷 为溶剂， 反应 1.5h， 生成 5,23-Dimethylhexacyclo[12.12.0.02,7.08,13.015,20.021,26]hexacosa-1(14),2(7),3,5,8,10,12,15,17,19,21(26),22,24-tridecaene
  参考文献：
  名称：

  Sequential Oxidative Transformation of Tetraarylethylenes to 9,10-Diarylphenanthrenes and Dibenzo[g,p]chrysenes using DDQ as an Oxidant

  摘要：

  Tetraarylethylenes can be sequentially transformed into 9,10-diarylphenanthrenes and dibenzo[g,p]chrysenes using 1 and 2 equiv of DDQ, respectively, in CH(2)Cl(2) containing methanesulfonic acid, in excellent yields. Efficient access to substituted dibenzochrysenes from tetraarylethylenes establishes the versatility of this procedure over the existing multistep syntheses of dibenzochrysenes. Moreover, the ready regeneration of DIM from easily recovered reduced DDQ-H(2) continues to advance the use of DDQ/H(+) for the oxidative C-C bond forming reactions.

  DOI：

  10.1021/ol200069c

文献信息

• Sequential Oxidative Transformation of Tetraarylethylenes to 9,10-Diarylphenanthrenes and Dibenzo[<i>g</i>,<i>p</i>]chrysenes using DDQ as an Oxidant
  作者：Tushar S. Navale、Khushabu Thakur、Rajendra Rathore

  DOI：10.1021/ol200069c

  日期：2011.4.1

  Tetraarylethylenes can be sequentially transformed into 9,10-diarylphenanthrenes and dibenzo[g,p]chrysenes using 1 and 2 equiv of DDQ, respectively, in CH(2)Cl(2) containing methanesulfonic acid, in excellent yields. Efficient access to substituted dibenzochrysenes from tetraarylethylenes establishes the versatility of this procedure over the existing multistep syntheses of dibenzochrysenes. Moreover, the ready regeneration of DIM from easily recovered reduced DDQ-H(2) continues to advance the use of DDQ/H(+) for the oxidative C-C bond forming reactions.