1,6-bis-(dimethylamino)pyrene | 10075-93-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: 1,6-bis-(dimethylamino)pyrene
• 英文别名: 1,6-Bis-(dimethylamino)-pyren；1,6-Pyrenediamine, N,N,N',N'-tetramethyl-；1-N,1-N,6-N,6-N-tetramethylpyrene-1,6-diamine
• CAS: 10075-93-1
• 化学式: C₂₀H₂₀N₂
• 分子量: 288.392
• InChiKey: JRBWOWYKCAJMBC-UHFFFAOYSA-N

物化性质

• 沸点：
  426.5±25.0 °C(Predicted)
• 密度：
  1.211±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,6-bis-(dimethylamino)pyrene 、 以 四氢呋喃 、 水 为溶剂， 以52%的产率得到3-(phenylsulfonyl)-BDMAP
  参考文献：
  名称：

  A new and practical method of decarboxylation: photosensitized decarboxylation of N-acyloxyphthalimides via electron-transfer mechanism

  摘要：

  DOI：

  10.1021/ja00234a047
• 作为产物：
  描述：

  1,6-二氨基芘 、 碘甲烷 在 calcium carbonate 作用下， 以 甲醇 、 水 为溶剂， 反应 65.0h， 以30%的产率得到1,6-bis-(dimethylamino)pyrene
  参考文献：
  名称：

  Photoinduced electron-transfer systems consisting of electron-donating pyrenes or anthracenes and benzimidazolines for reductive transformation of carbonyl compounds

  摘要：

  Photoinduced electron-transfer reactions of several ketone substrates were studied to evaluate the utilities of 1,6-bis(dimethyl-amino)pyrene (BDMAP), 1,6-dimethoxypyrene (DMP), 9,10-bis(dimethlylamino)anthracene (BDMAA), and 9,10-dimethoxyanthracene (DMA) as electron-donating sensitizers cooperating with 2-aryl-13-dimethylbenzimidazolines. BDMAP and DMP generally led higher conversion of ketones and better yield of reduction products compared to BDMAA and DMA. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2006.03.061
• 作为试剂：
  描述：

  1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl 2-benzyl-3-phenylpropanoate 、 叔丁基硫醇 在 1,6-bis-(dimethylamino)pyrene 作用下， 以 水 、 异丙醇 为溶剂， 反应 2.0h， 生成 邻苯二甲酸亚胺 、 1,3-联苯基-2-甲基丙烷 、 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  A new and practical method of decarboxylation: photosensitized decarboxylation of N-acyloxyphthalimides via electron-transfer mechanism

  摘要：

  DOI：

  10.1021/ja00234a047

文献信息

• Blue light emitting compound and organic electroluminescent device using the same
  申请人：Je Jong-Tae

  公开号：US20080203905A1

  公开（公告）日：2008-08-28

  A blue light emitting compound and an organic electroluminescent device using the compound are provided. The device exhibits improved color purity of blue emission and excellent life characteristics so as to be used to manufacture a full-color display.

  提供一种发出蓝光的化合物和使用该化合物的有机电致发光装置。该装置表现出改善的蓝色发射色纯度和优异的寿命特性，可用于制造全彩显示器。
• ANTHRACENE DERIVATIVES, LUMINESCENT MATERIALS AND ORGANIC ELECTROLUMINESCENT DEVICES
  申请人：Kawamura Masahiro

  公开号：US20110068683A1

  公开（公告）日：2011-03-24

  Anthracene derivatives each having a structure including an anthracene skeleton, a phenanthrene skeleton selected from among various phenanthrene skeletons different in bonding site which is bonded to the 9-position of the anthracene skeleton and a group selected from among various aryl groups and so on which is bonded to the 10-position of the anthracene skeleton. Organic EL devices made by using the derivatives exhibit high light emission efficiency and a long life.

  这段话的意思是：含有蒽骨架的衍生物，每个衍生物的结构都包括蒽骨架、苯并蒽骨架（从各种不同的苯并蒽骨架中选择，其键合位置与蒽骨架的9位相连）和从各种芳基基团中选择的基团等（其键合位置与蒽骨架的10位相连）。使用这些衍生物制造的有机电致发光器件具有高的发光效率和长寿命。
• OKADA, KEIJI;OKAMOTO, KAZUSHIGE;ODA, MASAJI, J. AMER. CHEM. SOC., 110,(1988) N6, C. 8736-8738
  作者：OKADA, KEIJI、OKAMOTO, KAZUSHIGE、ODA, MASAJI

  DOI：——

  日期：——
• PYRENE COMPOUNDS AND ORGANIC ELECTROLUMINESCENT DEVICES USING THE SAME
  申请人：Je Jong-Tae

  公开号：US20100052526A1

  公开（公告）日：2010-03-04

  A pyrene compound is provided. The pyrene compound is represented by Formula 1: wherein A 1 and A 2 are as defined in the specification. Further provided is an organic electroluminescent device using the pyrene compound. The organic electroluminescent device has high color purity of blue light and shows long life characteristics. Therefore, the organic electroluminescent device is suitable for use in displays and lighting systems.
• PYRENE POLYMER COMPOUND AND LIGHT EMITTING DEVICE USING THE SAME
  申请人：Fukushima Daisuke

  公开号：US20100109517A1

  公开（公告）日：2010-05-06

  A polymer compound comprising a constitutional unit of the formula (1), and a repeating unit of any of the formulae (2) to (4): (wherein, x3, y1, y2, z1 to z3 are 0 or 1. y3 represents an integer of 0 to 2. u represents an integer of 0 to 8. Z represents a pyrene residue, Ar 1 represents an arylene group or di-valent heterocyclic group, and Ar 2 represents an aryl group or mono-valent heterocyclic group.)