3-O-(2-carbazol-9-ylethyl) 1-O-ethyl propanedioate | 1300039-78-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 3-O-(2-carbazol-9-ylethyl) 1-O-ethyl propanedioate
• CAS: 1300039-78-4
• 化学式: C₁₉H₁₉NO₄
• 分子量: 325.364
• InChiKey: JOUZQWSJFXLZEI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  24
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  57.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3-O-(2-carbazol-9-ylethyl) 1-O-ethyl propanedioate 、 足球烯 在 四溴化碳 、 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 甲苯 为溶剂， 以15%的产率得到
  参考文献：
  名称：

  Electrochemical-Coupling Layer-by-Layer (ECC–LbL) Assembly

  摘要：

  Electrochemical-coupling layer-by-layer (ECC-LbL) assembly is introduced as a novel fabrication methodology for preparing layered thin films. This method allows us to covalently immobilize functional units (e.g., porphyrin, fullerene, and fluorene) into thin films having desired thicknesses and designable sequences for both homo- and heteroassemblies while ensuring efficient layer-to-layer electronic interactions. Films were prepared using a conventional electrochemical setup by a simple and inexpensive process from which various layering sequences can be obtained, and the photovoltaic functions of a prototype p/n heterojunction device were demonstrated.

  DOI：

  10.1021/ja202768k
• 作为产物：
  描述：

  9-咔唑乙醇 、 氯甲酰乙酸乙酯 在 吡啶 作用下， 以 二氯甲烷 为溶剂， 反应 12.0h， 以65%的产率得到3-O-(2-carbazol-9-ylethyl) 1-O-ethyl propanedioate
  参考文献：
  名称：

  Electrochemical-Coupling Layer-by-Layer (ECC–LbL) Assembly

  摘要：

  Electrochemical-coupling layer-by-layer (ECC-LbL) assembly is introduced as a novel fabrication methodology for preparing layered thin films. This method allows us to covalently immobilize functional units (e.g., porphyrin, fullerene, and fluorene) into thin films having desired thicknesses and designable sequences for both homo- and heteroassemblies while ensuring efficient layer-to-layer electronic interactions. Films were prepared using a conventional electrochemical setup by a simple and inexpensive process from which various layering sequences can be obtained, and the photovoltaic functions of a prototype p/n heterojunction device were demonstrated.

  DOI：

  10.1021/ja202768k

文献信息

• Electrochemical-Coupling Layer-by-Layer (ECC–LbL) Assembly
  作者：Mao Li、Shinsuke Ishihara、Misaho Akada、Meiyong Liao、Liwen Sang、Jonathan P. Hill、Venkata Krishnan、Yuguang Ma、Katsuhiko Ariga

  DOI：10.1021/ja202768k

  日期：2011.5.18

  Electrochemical-coupling layer-by-layer (ECC-LbL) assembly is introduced as a novel fabrication methodology for preparing layered thin films. This method allows us to covalently immobilize functional units (e.g., porphyrin, fullerene, and fluorene) into thin films having desired thicknesses and designable sequences for both homo- and heteroassemblies while ensuring efficient layer-to-layer electronic interactions. Films were prepared using a conventional electrochemical setup by a simple and inexpensive process from which various layering sequences can be obtained, and the photovoltaic functions of a prototype p/n heterojunction device were demonstrated.