(octaphenyltetraazaporphyrinato)magnesium(II)

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: (octaphenyltetraazaporphyrinato)magnesium(II)
• 英文别名: (2,3,7,8,12,13,17,18-octaphenyl-5,10,15,20-tetraazaporphyrinato)magnesium(II)；magnesium(II) octaphenyltetraazaporphyrinate；Mg(II)-octaphenyltetraazaporphyrinate；[(Ph₈PA)Mg]；magnesium octaphenyltetraazaporphyrinate；magnesium octaphenyltetraazaporphine；MgTAPPh8；Magnesium;4,5,9,10,14,15,19,20-octakis-phenyl-2,7,12,17,21,23-hexaza-22,24-diazanidapentacyclo[16.2.1.13,6.18,11.113,16]tetracosa-1,3,5,7,9,11(23),12,14,16,18(21),19-undecaene
• 化学式: C₆₄H₄₀MgN₈
• 分子量: 945.38
• InChiKey: SLEOHDOUWZKIDE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.45
• 重原子数：
  73
• 可旋转键数：
  8
• 环数：
  13.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  76.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  (octaphenyltetraazaporphyrinato)magnesium(II) 在 氯磺酸 作用下， 生成
  参考文献：
  名称：

  Lanthanide complexes with alkylsulfamoyl-substituted octaphenyltetraazaporphyrins

  摘要：

  The reaction of alkylsulfamoyl-substituted octaphenyltetraazaporphyrin with tris(acetylacetonato)lutetium(III) tris(acetylacetonato)ytterbium(III) gave the corresponding coordination compounds which were characterized by elemental compositions and IR and electronic absorption spectra.

  DOI：

  10.1134/s1070363212070171
• 作为产物：
  描述：

  dicyanostilbene 在 magnesium 作用下， 生成 (octaphenyltetraazaporphyrinato)magnesium(II)
  参考文献：
  名称：

  Lanthanide complexes with alkylsulfamoyl-substituted octaphenyltetraazaporphyrins

  摘要：

  The reaction of alkylsulfamoyl-substituted octaphenyltetraazaporphyrin with tris(acetylacetonato)lutetium(III) tris(acetylacetonato)ytterbium(III) gave the corresponding coordination compounds which were characterized by elemental compositions and IR and electronic absorption spectra.

  DOI：

  10.1134/s1070363212070171

文献信息

• Metal-exchange reaction of <font>Mg</font>-octaphenyltetraazaporphyrin with <font>Co</font>(<font>II</font>)
  作者：Svetlana V. Zvezdina、Natalya V. Chizhova、Nugzar Zh. Mamardashvili

  DOI：10.1142/s1088424613501095

  日期：2014.1

  The metal-exchange reaction of Mg ( II )-octaphenyltetraazaporphyrin with CoCl ₂ leading to formation of Co ( II )-octaphenyltetraazaporphyrin was studied by the method of UV-vis spectroscopy. The kinetic parameters of the metal-exchange reaction were determined.

  利用紫外可见光谱法研究了 Mg ( II )-octaphenyltetraazaporphyrin 与 CoCl 2 发生金属交换反应生成 Co ( II )-octaphenyltetraazaporphyrin 的过程。确定了金属交换反应的动力学参数。
• Metal exchange reaction of magnesium octaphenyltetraazaporphyrin with copper, cobalt, and zinc chlorides in DMSO and DMF
  作者：S. V. Zvezdina、N. V. Chizhova、N. Zh. Mamardashvili

  DOI：10.1134/s1070363214100211

  日期：2014.10

  Metal exchange reaction of (octaphenyltetraazaporphyrinato)magnesium(II) with copper, cobalt, and zinc chlorides in dimethyl sulfoxide and dimethylformamide has been studied by spectrophotometry. Kinetic and thermodynamic parameters of the process have been determined, and a probable reaction mechanism has been proposed. Zinc(II), copper(II), cobalt(II), and cobalt(III) complexes of octaphenyltetraazaporphyrin

  通过分光光度法研究了（八苯基四氮杂卟啉酮）镁（II）与铜，钴和氯化锌在二甲基亚砜和二甲基甲酰胺中的金属交换反应。确定了该过程的动力学和热力学参数，并提出了可能的反应机理。八苯基四氮杂卟啉的锌（II），铜（II），钴（II）和钴（III）配合物已被分离和表征。
• Transmetalation of (octaphenyltetraazaporphyrinato)magnesium(II) with manganese(II) chloride in dimethylformamide
  作者：S. V. Zvezdina、N. V. Chizhova、N. Zh. Mamardashvili

  DOI：10.1134/s1070363214070251

  日期：2014.7

  The reaction of (octaphenyltetraazaporphyrinato)magnesium(II) with manganese(II) chloride in dimethylformamide gave (chloro)(octaphenyltetraazaporphyrinato)manganese(III). Reactions of the latter with nitrogen-containing bases were studied. The kinetic parameters of the transmetalation of (octaphenyltetraazaporphyrinato) magnesium(II) with MnCl2 in dimethylformamide at 323, 333, and 343 K were determined

  （八苯基四氮杂卟啉酮）镁（II）与氯化锰（II）在二甲基甲酰胺中的反应得到（氯）（八苯基四氮杂卟啉酮）锰（III）。研究了后者与含氮碱的反应。确定了在二甲基甲酰胺中分别于323、333和343 K下用MnCl 2对（八苯基四氮杂卟啉酮）镁（II）进行金属转移的动力学参数，并提出了可能的反应机理。
• Synthesis and spectral properties of 1,2,5-thiadiazolo-, 1,2,5-selenadiazolo-, and benzo-fused β-phenyl-substituted porphyrazines
  作者：P. A. Stuzhin、I. V. Pimkov、A. Ul’-Khak、S. S. Ivanova、I. A. Popkova、D. I. Volkovich、V. A. Kuz’mitskii、M. -P. Donzello

  DOI：10.1134/s1070428007120202

  日期：2007.12

  Cross cyclotetramerization of trans-2,3-diphenylbutanedinitrile with 1,2,5-thia(selena)diazole-3,4-dicarbonitriles or phthalodinitrile in the presence of magnesium butoxide gave mixtures of Mg(II) porphyrazine complexes which were treated with trifluoroacetic acid to isolate unsymmetrical hexaphenyl-substituted 1,2,5-thia(selena)diazolo- and benzo-fused porphyrazines together with diphenyltribenzoporphyrazine. Their H-1 NMR and electronic absorption spectra (in the UV and visible regions) were recorded. The effect of benzene and heteroring fusion on the electronic and steric structure and spectral properties of porphyrazine derivatives was studied in terms of the molecular orbital perturbation theory and semiempirical quantum-chemical calculations (AM1, PM3, ZINDO/S, CNDO/S).
• Chizhova; Berezin, Russian Journal of Inorganic Chemistry, 2003, vol. 48, # 9, p. 1359 - 1363
  作者：Chizhova、Berezin

  DOI：——

  日期：——