| 934996-00-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 934996-00-6
• 化学式: C₂₂H₃₁NOSi
• 分子量: 353.58
• InChiKey: NHHYFZKPNGNZSB-BQYQJAHWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.81
• 重原子数：
  25.0
• 可旋转键数：
  7.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.41
• 拓扑面积：
  22.12
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  、 4-氯甲基苯乙烯 以 乙腈 为溶剂， 反应 24.0h， 以62%的产率得到4-((E)-2-{4-[(triisopropylsilyl)oxy]phenyl}ethenyl)-1-(4-vinylbenzyl)pyridinium chloride
  参考文献：
  名称：

  Color Change of N-Isopropylacrylamide Copolymer Bearing Reichardts Dye as Optical Sensor for Lower Critical Solution Temperature and for Host−Guest Interaction with β-Cyclodextrin

  摘要：

  With a simple reaction pathway, a polymerizable solvatochromic dye monomer was synthesized. Copolymerization of this dye monomer with NiPAAM leads to formation of a solvatochromic copolymer with lower critical solution temperature (LCST) behavior. This resulting copolymer visualizes via a red-orange color change (a) the LCST phase transition and (b) the host-guest interaction of cyclodextrin with this copolymer simply by the naked eye. Actually, these effects are completely reversible.

  DOI：

  10.1021/ja068959v
• 作为产物：
  描述：

  4-甲基吡啶 在 咪唑 、 乙酸酐 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 48.0h， 生成
  参考文献：
  名称：

  Color Change of N-Isopropylacrylamide Copolymer Bearing Reichardts Dye as Optical Sensor for Lower Critical Solution Temperature and for Host−Guest Interaction with β-Cyclodextrin

  摘要：

  With a simple reaction pathway, a polymerizable solvatochromic dye monomer was synthesized. Copolymerization of this dye monomer with NiPAAM leads to formation of a solvatochromic copolymer with lower critical solution temperature (LCST) behavior. This resulting copolymer visualizes via a red-orange color change (a) the LCST phase transition and (b) the host-guest interaction of cyclodextrin with this copolymer simply by the naked eye. Actually, these effects are completely reversible.

  DOI：

  10.1021/ja068959v