4,7-Bis[5-(5-bromothiophen-2-yl)-4-hexylthiophen-2-yl]-2,1,3-benzothiadiazole | 444579-41-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩
• 英文名称: 4,7-Bis[5-(5-bromothiophen-2-yl)-4-hexylthiophen-2-yl]-2,1,3-benzothiadiazole
• CAS: 444579-41-3
• 化学式: C₃₄H₃₄Br₂N₂S₅
• 分子量: 790.795
• InChiKey: MUWRUENNJLJXPK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.2
• 重原子数：
  43
• 可旋转键数：
  14
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  167
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  4,7-Bis[5-(5-bromothiophen-2-yl)-4-hexylthiophen-2-yl]-2,1,3-benzothiadiazole 、 3,4,5-三氟苯硼酸 在 四(三苯基膦)钯 sodium carbonate 作用下， 以 乙醇 、 甲苯 为溶剂， 反应 18.0h， 以61%的产率得到4,7-Bis[4-hexyl-5-[5-(3,4,5-trifluorophenyl)thiophen-2-yl]thiophen-2-yl]-2,1,3-benzothiadiazole
  参考文献：
  名称：

  N-Type Materials And Organic Electronic Devices

  摘要：

  目前提供了公式I的有机化合物，从这些化合物衍生的n型受体材料以及包含这种n型受体材料的器件。(An-DprAnI)

  公开号：

  US20120298976A1
• 作为产物：
  描述：

  4,7-双(5-溴-4-己基噻吩-2-基)苯并[c][1,2,5]噻二唑 在 四(三苯基膦)钯 N-溴代丁二酰亚胺(NBS) 、 溶剂黄146 作用下， 以 乙二醇二甲醚 、 氯仿 、 N,N-二甲基甲酰胺 为溶剂， 反应 4.61h， 生成 4,7-Bis[5-(5-bromothiophen-2-yl)-4-hexylthiophen-2-yl]-2,1,3-benzothiadiazole
  参考文献：
  名称：

  N-Type Materials And Organic Electronic Devices

  摘要：

  目前提供了公式I的有机化合物，从这些化合物衍生的n型受体材料以及包含这种n型受体材料的器件。(An-DprAnI)

  公开号：

  US20120298976A1

文献信息

• [EN] N-TYPE MATERIALS AND ORGANIC ELECTRONIC DEVICES<br/>[FR] MATERIAUX DE TYPE N ET DISPOSITIFS ELECTRONIQUES ORGANIQUES
  申请人：AGENCY SCIENCE TECH & RES

  公开号：WO2011049531A1

  公开（公告）日：2011-04-28

  The invention provides organic compounds of formula I, wherein each A is an independently selected conjugated electron withdrawing aromatic or heteroaromatic group; each D is an independently selected ethenylene group, ethynylene group or a conjugated electron donating aromatic or heteroaromatic group; r is an integer having a value of 2 or greater; each n is independently an integer from 1 to 20; and each p is independently an integer from 1 to 10. N-type acceptor materials derived from such compounds and devices comprising such n-type acceptor materials are also provided.

  该发明提供了公式I的有机化合物，其中每个A是独立选择的共轭电子吸引芳香或杂芳基团；每个D是独立选择的乙烯基团、乙炔基团或共轭电子给体芳香或杂芳基团；r是一个大于等于2的整数；每个n是独立选择的1到20之间的整数；每个p是独立选择的1到10之间的整数。还提供了从这些化合物衍生的N型受体材料和包含这种N型受体材料的器件。
• POLYMER COMPOUND AND POLYMER LIGHT-EMITTING DEVICE USING THE SAME
  申请人：Moriwaki Shota

  公开号：US20110156018A1

  公开（公告）日：2011-06-30

  A polymer compound comprising a repeating unit represented by the formula (I): [wherein X 1 and X 2 are the same or mutually different and represent an oxygen atom, a sulfur atom, —N(R N )— or C(R c1 )═C(R c2 )—, R 1 , R 2 , R 3 , R 4 , R N , R c1 and R c2 are the same or mutually different and represent a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an alkylthio group, an aryl group, an aryloxy group, an arylthio group, an arylalkyl group, an arylalkoxy group, an arylalkylthio group, an arylalkenyl group, an arylalkynyl group, a mono-valent heterocyclic group, a heterocyclic thio group, an amino group, a substituted amino group, a silyl group, a substituted silyl group, an acyl group, an acyloxy group, an imine residue, an amide group, an acid imide group, a carboxyl group, a substituted carboxyl group, a cyano group or a nitro group, and Ar 1 represents a di-valent heterocyclic group.].
• ORGANIC PHOTOELECTRIC CONVERSION ELEMENT
  申请人：Uetani Yasunori

  公开号：US20120100285A1

  公开（公告）日：2012-04-26

  An organic photoelectric conversion element having a high absorbance at 600 nm can be provide by a method for manufacturing an organic photoelectric conversion element having a pair of electrodes at least one of which is transparent or translucent, and an organic layer between the electrodes, the method comprising a step of applying a solution that contains a conjugated polymer compound having a thiophenediyl group as a repeating unit and a sulfur-containing heterocyclic compound on one of the electrodes to form an applied film, and a step of drying the applied film at a temperature of 70° C. or less to form the organic layer.
• US7534503B2
  申请人：——

  公开号：US7534503B2

  公开（公告）日：2009-05-19
• US8723163B2
  申请人：——

  公开号：US8723163B2

  公开（公告）日：2014-05-13