[Tb(1-phenyl-3-methyl-4-cyclopentylcarbonyl-pyrazol-5-one(1-))3(H2O)] | 669704-65-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: [Tb(1-phenyl-3-methyl-4-cyclopentylcarbonyl-pyrazol-5-one(1-))3(H2O)]
• CAS: 669704-65-8
• 化学式: C₄₈H₅₃N₆O₇Tb
• 分子量: 984.91
• InChiKey: FKTYHTPEHBZFEB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [Tb(1-phenyl-3-methyl-4-cyclopentylcarbonyl-pyrazol-5-one(-1H))3(H2O)(EtOH)] 以 neat (no solvent) 为溶剂， 生成 [Tb(1-phenyl-3-methyl-4-cyclopentylcarbonyl-pyrazol-5-one(1-))3(H2O)]
  参考文献：
  名称：

  The role of reaction medium on the coordination environment of terbium in complexes with 4-acylpyrazol-5-ones

  摘要：

  [Tb(Q)(3)(H2O)] and [Tb(Q)(3)(H2O)(EtOH)] derivatives of novel 1-phenyl-3-methyl-4-R-pyrazol-5-one (HQ = HQ(CP): R = cyclopentylcarbonyl, HQ(ETCP): R = cyclopentylpropionyl) have been prepared and shown to be seven- and eight-coordinate, respectively, by IR, X-ray and elemental analyses. The role of the reaction medium on the coordination number of Tb is discussed. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2003.08.028